Green Synthesis of a New Schiff Base Linker and Its Use to Prepare Coordination Polymers DOI Creative Commons
M. Hayes, Aizhamal Subanbekova, Yassin H. Andaloussi

и другие.

Crystal Growth & Design, Год журнала: 2024, Номер 25(2), С. 444 - 451

Опубликована: Дек. 25, 2024

Solid-state synthesis is an approach to organic that desirable because it can offer minimal or no solvent waste, high yields, and relatively low energy footprints. Herein, we report the solid-state of a novel Schiff base, 4-{(E)-[(4-methylpyridin-3-yl)imino]methyl}benzoic acid (4-PIBZ), synthesized through reaction amine aldehyde. 4-PIBZ was prepared via solvent-drop (water) grinding (SDG) on multigram scale with 97% yield characterized using FTIR, 1H NMR, SCXRD. The pyridyl carboxylate moiety present in make suitable for use as linker ligand indeed found coordinate Cu(II), Zn(II), Cd(II) cations, enabling serve assembly coordination polymers. thereby formed 1D (spiro chain) 2D (square lattice, sql, topology) polymers solvent-induced (layering slurry) methods. resulting were though X-ray diffraction (SCXRD, PXRD) TGA, further demonstrating utility green methods preparation some classes new ligands turn be used

Язык: Английский

Adsorption separation of propylene/propane by pressure induced flexible porous MOF DOI
Huiping Chen, Meiling Li, Dongxu Gu

и другие.

Microporous and Mesoporous Materials, Год журнала: 2025, Номер unknown, С. 113644 - 113644

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0
Chemistry and crystal engineering DOI Creative Commons
Susan A. Bourne

IUCrJ, Год журнала: 2024, Номер 11(4), С. 434 - 435

Опубликована: Июнь 28, 2024

Recent studies published in the Chemistry and crystal engineering section of IUCrJ emphasize developments both methodology techniques as well diverse range classes compounds being studied problems tackled.

Язык: Английский

Процитировано

0
Green Synthesis of a New Schiff Base Linker and Its Use to Prepare Coordination Polymers DOI Creative Commons
M. Hayes, Aizhamal Subanbekova, Yassin H. Andaloussi

и другие.

Crystal Growth & Design, Год журнала: 2024, Номер 25(2), С. 444 - 451

Опубликована: Дек. 25, 2024

Solid-state synthesis is an approach to organic that desirable because it can offer minimal or no solvent waste, high yields, and relatively low energy footprints. Herein, we report the solid-state of a novel Schiff base, 4-{(E)-[(4-methylpyridin-3-yl)imino]methyl}benzoic acid (4-PIBZ), synthesized through reaction amine aldehyde. 4-PIBZ was prepared via solvent-drop (water) grinding (SDG) on multigram scale with 97% yield characterized using FTIR, 1H NMR, SCXRD. The pyridyl carboxylate moiety present in make suitable for use as linker ligand indeed found coordinate Cu(II), Zn(II), Cd(II) cations, enabling serve assembly coordination polymers. thereby formed 1D (spiro chain) 2D (square lattice, sql, topology) polymers solvent-induced (layering slurry) methods. resulting were though X-ray diffraction (SCXRD, PXRD) TGA, further demonstrating utility green methods preparation some classes new ligands turn be used

Язык: Английский

Процитировано

0