Green Synthesis of a New Schiff Base Linker and Its Use to Prepare Coordination Polymers DOI Creative Commons
M. Hayes, Aizhamal Subanbekova, Yassin H. Andaloussi

et al.

Crystal Growth & Design, Journal Year: 2024, Volume and Issue: 25(2), P. 444 - 451

Published: Dec. 25, 2024

Solid-state synthesis is an approach to organic that desirable because it can offer minimal or no solvent waste, high yields, and relatively low energy footprints. Herein, we report the solid-state of a novel Schiff base, 4-{(E)-[(4-methylpyridin-3-yl)imino]methyl}benzoic acid (4-PIBZ), synthesized through reaction amine aldehyde. 4-PIBZ was prepared via solvent-drop (water) grinding (SDG) on multigram scale with 97% yield characterized using FTIR, 1H NMR, SCXRD. The pyridyl carboxylate moiety present in make suitable for use as linker ligand indeed found coordinate Cu(II), Zn(II), Cd(II) cations, enabling serve assembly coordination polymers. thereby formed 1D (spiro chain) 2D (square lattice, sql, topology) polymers solvent-induced (layering slurry) methods. resulting were though X-ray diffraction (SCXRD, PXRD) TGA, further demonstrating utility green methods preparation some classes new ligands turn be used

Language: Английский

Adsorption separation of propylene/propane by pressure induced flexible porous MOF DOI
Huiping Chen, Meiling Li, Dongxu Gu

et al.

Microporous and Mesoporous Materials, Journal Year: 2025, Volume and Issue: unknown, P. 113644 - 113644

Published: April 1, 2025

Language: Английский

Citations

0
Chemistry and crystal engineering DOI Creative Commons
Susan A. Bourne

IUCrJ, Journal Year: 2024, Volume and Issue: 11(4), P. 434 - 435

Published: June 28, 2024

Recent studies published in the Chemistry and crystal engineering section of IUCrJ emphasize developments both methodology techniques as well diverse range classes compounds being studied problems tackled.

Language: Английский

Citations

0
Green Synthesis of a New Schiff Base Linker and Its Use to Prepare Coordination Polymers DOI Creative Commons
M. Hayes, Aizhamal Subanbekova, Yassin H. Andaloussi

et al.

Crystal Growth & Design, Journal Year: 2024, Volume and Issue: 25(2), P. 444 - 451

Published: Dec. 25, 2024

Solid-state synthesis is an approach to organic that desirable because it can offer minimal or no solvent waste, high yields, and relatively low energy footprints. Herein, we report the solid-state of a novel Schiff base, 4-{(E)-[(4-methylpyridin-3-yl)imino]methyl}benzoic acid (4-PIBZ), synthesized through reaction amine aldehyde. 4-PIBZ was prepared via solvent-drop (water) grinding (SDG) on multigram scale with 97% yield characterized using FTIR, 1H NMR, SCXRD. The pyridyl carboxylate moiety present in make suitable for use as linker ligand indeed found coordinate Cu(II), Zn(II), Cd(II) cations, enabling serve assembly coordination polymers. thereby formed 1D (spiro chain) 2D (square lattice, sql, topology) polymers solvent-induced (layering slurry) methods. resulting were though X-ray diffraction (SCXRD, PXRD) TGA, further demonstrating utility green methods preparation some classes new ligands turn be used

Language: Английский

Citations

0