Advanced Materials,
Год журнала:
2021,
Номер
33(30)
Опубликована: Май 28, 2021
Soft
materials
that
respond
to
wireless
external
stimuli
are
referred
as
"smart"
due
their
promising
potential
in
real-world
actuation
and
sensing
applications
robotics,
microfluidics,
bioengineering.
Recent
years
have
witnessed
a
burst
of
these
stimuli-responsive
preliminary
applications.
However,
further
advancement
demands
more
versatility,
configurability,
adaptability
deliver
promised
benefits.
Here,
dual-stimuli-responsive
soft
bimorph
material
with
three
configurations
enable
complex
programmable
3D
shape-morphing
is
presented.
The
consists
liquid
crystal
elastomers
(LCEs)
magnetic-responsive
(MREs)
via
facile
fabrication
orthogonally
integrates
respective
stimuli-responsiveness
without
detrimentally
altering
properties.
offers
an
unprecedented
wide
design
space
abundant
degree-of-freedoms
(DoFs)
the
LCE's
director
field,
MRE's
magnetization
profile,
diverse
geometric
configurations.
It
responds
controlled
magnetic
field
environmental
temperature.
Its
dual-responsiveness
allows
independent
control
different
DoFs
for
behaviors
anisotropic
A
set
situ
reconfigurable
environment-aware
untethered
miniature
12-legged
robot
capable
locomotion
self-gripping
demonstrated.
Such
can
provide
solutions
development
future
robotic
other
functional
devices.
Chemical Reviews,
Год журнала:
2022,
Номер
122(5), С. 5317 - 5364
Опубликована: Фев. 1, 2022
In
conventional
classification,
soft
robots
feature
mechanical
compliance
as
the
main
distinguishing
factor
from
traditional
made
of
rigid
materials.
Recent
advances
in
functional
materials
have
facilitated
emergence
a
new
class
capable
tether-free
actuation
response
to
external
stimuli
such
heat,
light,
solvent,
or
electric
magnetic
field.
Among
various
types
stimuli-responsive
materials,
shown
remarkable
progress
their
design
and
fabrication,
leading
development
with
unique
advantages
potential
for
many
important
applications.
However,
field
is
still
its
infancy
requires
further
advancements
terms
principles,
fabrication
methods,
control
mechanisms,
sensing
modalities.
Successful
future
would
require
comprehensive
understanding
fundamental
principle
actuation,
well
physical
properties
behavior
this
review,
we
discuss
recent
modeling
simulation,
robots.
We
then
give
set
guidelines
optimal
performance
Lastly,
summarize
biomedical
applications
provide
our
perspectives
on
next-generation
Materials Science and Engineering R Reports,
Год журнала:
2021,
Номер
145, С. 100596 - 100596
Опубликована: Апрель 2, 2021
Additive
manufacturing
(AM),
also
known
as
three-dimensional
(3D)
printing,
has
boomed
over
the
last
30
years,
and
its
use
accelerated
during
5
years.
AM
is
a
materials-oriented
technology,
printing
resolution
versus
scalability/speed
trade-off
exists
among
various
types
of
materials,
including
polymers,
metals,
ceramics,
glasses,
composite
materials.
Four-dimensional
(4D)
together
with
versatile
transformation
systems,
drives
researchers
to
achieve
utilize
high
dimensional
AM.
Multiple
perspectives
structural
materials
have
been
raised
illustrated
in
this
review,
multi-material
(MMa-AM),
multi-modulus
(MMo-AM),
multi-scale
(MSc-AM),
multi-system
(MSy-AM),
multi-dimensional
(MD-AM),
multi-function
(MF-AM).
The
rapid
tremendous
development
methods
offers
great
potential
for
applications,
such
aerospace
field,
biomedical
electronic
devices,
nuclear
industry,
flexible
wearable
soft
sensors,
actuators,
robotics,
jewelry
art
decorations,
land
transportation,
underwater
porous
structures.
Molecular Pharmaceutics,
Год журнала:
2019,
Номер
unknown
Опубликована: Дек. 26, 2019
As
an
emerging
drug
carrier,
hydrogels
have
been
widely
used
for
tumor
delivery.
A
hydrogel
carrier
can
cause
less
severe
side
effects
than
systemic
chemotherapy
and
achieve
sustained
delivery
of
a
at
sites.
In
addition,
excellent
biocompatibility
biodegradability
lower
toxicity
nanoparticle
carriers.
Smart
respond
to
stimuli
in
the
environment
(e.g.,
heat,
pH,
light,
ultrasound),
enabling
situ
gelation
controlled
release,
which
greatly
enhance
convenience
efficiency
Here,
we
summarize
different
sizes
cancer
treatment
their
related
routes,
discuss
design
strategies
stimuli-responsive
hydrogels,
review
research
concerning
smart
reported
past
few
years.
Multifunctional Materials,
Год журнала:
2020,
Номер
3(4), С. 042003 - 042003
Опубликована: Ноя. 17, 2020
Abstract
Magnetically
responsive
soft
materials
are
composites
where
magnetic
fillers
embedded
into
polymeric
matrices.
These
active
have
attracted
extensive
research
and
industrial
interest
due
to
their
ability
realize
fast
programmable
shape
changes
through
remote
untethered
control
under
the
application
of
fields.
They
would
many
high-impact
potential
applications
in
robotics/devices,
metamaterials,
biomedical
devices.
With
a
broad
range
functional
fillers,
matrices,
advanced
fabrication
techniques,
material
properties
can
be
programmed
for
integrated
functions,
including
morphing,
dynamic
deformation-based
locomotion,
object
manipulation
assembly,
heat
generation,
as
well
reconfigurable
electronics.
In
this
review,
an
overview
state-of-the-art
developments
future
perspectives
multifunctional
magnetically
is
presented.
Hydrogels
with
tailor-made
swelling-shrinkable
properties
have
aroused
considerable
interest
in
numerous
biomedical
domains.
For
example,
as
swelling
is
a
key
issue
for
blood
and
wound
extrudates
absorption,
the
transference
of
nutrients
metabolites,
well
drug
diffusion
release,
hydrogels
high
capacity
been
widely
applicated
full-thickness
skin
healing
tissue
regeneration,
delivery.
Nevertheless,
fields
adhesives
internal
soft-tissue
healing,
bioelectronics,
non-swelling
play
very
important
functions
owing
to
their
stable
macroscopic
dimension
physical
performance
physiological
environment.
Moreover,
negative
behavior
(i.e.,
shrinkage)
can
be
exploited
drive
noninvasive
closure,
achieve
resolution
enhancement
hydrogel
scaffolds.
In
addition,
it
help
push
out
entrapped
drugs,
thus
promote
release.
However,
there
still
has
not
general
review
constructions
applications
from
viewpoint
properties.
Therefore,
this
summarizes
tactics
employed
so
far
tailoring
applications.
And
relatively
comprehensive
understanding
current
progress
future
challenge
different
features
provided
potential
clinical
translations.
Advanced Functional Materials,
Год журнала:
2020,
Номер
30(50)
Опубликована: Сен. 15, 2020
Abstract
Small‐scale
magnetic
soft‐bodied
robots
based
on
biocompatible
and
biodegradable
materials
are
essential
for
their
potential
high‐impact
minimally
invasive
medical
applications
inside
the
human
body.
Therefore,
a
strategy
fully
untethered
soft
millirobots
with
encoded
3D
anisotropy
static
or
dynamic
shape
programming
is
presented.
Such
robot
body
comprised
of
porcine
extracellular
matrix‐derived
collagen‐based
hydrogel
network
embedded
superparamagnetic
iron
oxide
nanoparticles
(SPIONs).
magnetization
achieved
by
directionally
self‐assembled
SPION
chains
using
an
external
permanent
magnet.
As
proof‐of‐concept
demonstration,
milli‐gripper
that
can
undergo
flexible
reversible
deformations
glycerol
biologically
relevant
liquid
media
The
gripper
perform
cargo
grabbing,
transportation
rolling,
release
controlling
field
inputs.
These
milli‐grippers
be
completely
degraded
matrix
metalloproteinase‐2
enzyme
in
physiologically
concentrations.
Furthermore,
biocompatibility
tests
umbilical
cord
vein
endothelial
cells
degradation
products
grippers
demonstrate
no
acute
toxicity.
approach
offers
facile
fabrication
designing
nanocomposite
programmable
toward
future
applications.
Advanced Functional Materials,
Год журнала:
2021,
Номер
31(34)
Опубликована: Июнь 17, 2021
Abstract
The
research
of
functional
magnetic
materials
has
become
a
hot
topic
in
the
past
few
years
due
to
their
fast,
long‐range,
and
precise
response
diverse
environments.
Functional
devices
using
different
structure
designs
have
been
developed
demonstrated
good
advantages
enable
various
applications.
However,
required
for
functions
also
increase
fabrication
difficulties
while
developing
such
devices.
3D
printing
technology
presents
powerful
promising
manufacturing
approach
rapidly
fabricate
complex
geometries
multiple
scales.
Here,
strategies
underlying
mechanisms
several
primary
applications
are
systematically
reviewed,
including,
anisotropy
property
enhancement,
robots,
components
electronics,
magneto‐thermal
Finally,
current
challenges
future
perspectives
engineering
printed
discussed.
Materials & Design,
Год журнала:
2021,
Номер
211, С. 110172 - 110172
Опубликована: Окт. 14, 2021
Magnetoactive
soft
materials
(MSMs)
are
polymeric
composites
filled
with
magnetic
particles
that
an
emerging
class
of
smart
and
multifunctional
immense
potentials
to
be
used
in
various
applications
including
but
not
limited
artificial
muscles,
robotics,
controlled
drug
delivery,
minimally
invasive
surgery,
metamaterials.
Advantages
MSMs
include
remote
contactless
actuation
multiple
modes,
high
strain
rate,
self-sensing,
fast
response
etc.
Having
broad
functional
behaviours
offered
by
the
fillers
embedded
within
non-magnetic
matrices,
undoubtedly
one
most
promising
where
shape-morphing,
dynamic
locomotion,
reconfigurable
structures
highly
required.
This
review
article
provides
a
comprehensive
picture
focusing
on
materials,
manufacturing
processes,
programming
techniques,
behaviours,
experimental
characterisations,
device-related
achievements
current
state-of-the-art
discusses
future
perspectives.
Overall,
this
only
overview
MSMs'
research
development
also
functions
as
systematic
guideline
towards
multifunctional,
sophisticated
magnetoactive
devices.