Advanced Functional Materials,
Год журнала:
2023,
Номер
33(39)
Опубликована: Март 9, 2023
Abstract
Stimuli‐responsive
hydrogels
have
attracted
much
attention
owing
to
the
versatility
of
their
programmed
response
in
offering
intelligent
solutions
for
biomimicry
applications,
such
as
soft
robotics,
tissue
engineering,
and
drug
delivery.
To
achieve
complexity
biomimetic
structures,
two
photon
polymerization
(2PP)
has
provided
a
means
fabricating
intricate
3D
structures
from
stimuli‐responsive
hydrogels.
Rapid
swelling
hydrogel
microstructures
are
advantageous
osmotically
driven
stimuli‐response,
where
actuation
speed,
that
is
reliant
on
diffusion
analytes
or
bioanalytes,
can
be
optimized.
Herein,
flexibility
2PP
exploited
showcase
novel
sugar‐responsive,
phenylboronic
acid‐based
photoresist.
This
offers
remarkable
solution
achieving
fast
systems
been
often
hindered
by
volume‐dependent
times
receptor
sites.
A
photoresist
compatible
with
presented
fabricate
accelerated
times.
Moreover,
programmable
(i.e.,
bending
opening)
fabricated
using
same
within
one‐step
fabrication
process.
By
combining
an
easily
adaptable
photoresist,
accessible
method
showcased
sophisticated
chemo‐responsive
actuators.
Chemical Reviews,
Год журнала:
2021,
Номер
121(8), С. 4999 - 5041
Опубликована: Март 31, 2021
Manipulation
and
navigation
of
micro
nanoswimmers
in
different
fluid
environments
can
be
achieved
by
chemicals,
external
fields,
or
even
motile
cells.
Many
researchers
have
selected
magnetic
fields
as
the
active
actuation
source
based
on
advantageous
features
this
strategy
such
remote
spatiotemporal
control,
fuel-free,
high
degree
reconfigurability,
programmability,
recyclability,
versatility.
This
review
introduces
fundamental
concepts
advantages
micro/nanorobots
(termed
here
"MagRobots")
well
basic
knowledge
materials,
setups
for
manipulation,
field
configurations,
symmetry-breaking
strategies
effective
movement.
These
are
discussed
to
describe
interactions
between
fields.
Actuation
mechanisms
flagella-inspired
MagRobots
(i.e.,
corkscrew-like
motion
traveling-wave
locomotion/ciliary
stroke
motion)
surface
walkers
surface-assisted
motion),
applications
other
propulsion
approaches,
stimulation
beyond
provided
followed
fabrication
techniques
(quasi-)spherical,
helical,
flexible,
wire-like,
biohybrid
MagRobots.
Applications
targeted
drug/gene
delivery,
cell
minimally
invasive
surgery,
biopsy,
biofilm
disruption/eradication,
imaging-guided
delivery/therapy/surgery,
pollution
removal
environmental
remediation,
(bio)sensing
also
reviewed.
Finally,
current
challenges
future
perspectives
development
magnetically
powered
miniaturized
motors
discussed.
Advanced Materials,
Год журнала:
2020,
Номер
33(4)
Опубликована: Дек. 4, 2020
Abstract
Micro‐/nanorobots
(m‐bots)
have
attracted
significant
interest
due
to
their
suitability
for
applications
in
biomedical
engineering
and
environmental
remediation.
Particularly,
vivo
diagnosis
intervention
been
the
focus
of
extensive
research
recent
years
with
various
clinical
imaging
techniques
being
applied
localization
tracking.
The
successful
integration
well‐designed
m‐bots
surface
functionalization,
remote
actuation
systems,
becomes
crucial
step
toward
applications,
especially
uses.
This
review
thus
addresses
four
different
aspects
m‐bots:
design/fabrication,
actuation,
localization.
diagnosis,
sensing,
microsurgery,
targeted
drug/cell
delivery,
thrombus
ablation,
wound
healing
are
reviewed
from
these
viewpoints.
developed
m‐bot
systems
comprehensively
compared
evaluated
based
on
characteristics.
current
challenges
directions
future
this
field
summarized.
Advanced Functional Materials,
Год журнала:
2023,
Номер
33(39)
Опубликована: Март 22, 2023
Abstract
The
rapid
development
of
additive
manufacturing
has
fueled
a
revolution
in
various
research
fields
and
industrial
applications.
Among
the
myriad
advanced
3D
printing
techniques,
two‐photon
polymerization
lithography
(TPL)
uniquely
offers
significant
advantage
nanoscale
print
resolution,
been
widely
employed
diverse
fields,
for
example,
life
sciences,
materials
mechanics,
microfluidics.
More
recently,
by
virtue
optical
transparency
most
resins
used,
TPL
is
finding
new
applications
optics
photonics,
with
nanometer
to
millimeter
feature
dimensions.
It
enables
minimization
elements
systems,
exploration
light‐matter
interactions
degrees
freedom,
never
possible
before.
To
review
recent
progress
related
research,
it
starts
fundamentals
material
formulation,
then
discusses
novel
fabrication
methods,
wide
range
These
notably
include
diffractive,
topological,
quantum,
color
optics.
With
panoramic
view
development,
concluded
insights
perspectives
future
potential
Nano-Micro Letters,
Год журнала:
2022,
Номер
14(1)
Опубликована: Апрель 8, 2022
Versatile
liquid
manipulating
surfaces
combining
patternable
and
controllable
wettability
have
recently
motivated
considerable
attention
owing
to
their
significant
advantages
in
droplet-solid
impacting
behaviors,
microdroplet
self-removal,
liquid-liquid
interface
reaction
applications.
However,
developing
a
facile
efficient
method
fabricate
these
versatile
remains
an
enormous
challenge.
In
this
paper,
strategy
for
the
fabrication
of
with
on
Polyimide
(PI)
film
based
femtosecond
laser
thermal
accumulation
engineering
is
proposed.
Because
its
micro-/nanostructures
chemical
composition
through
adjusting
local
accumulation,
PI
can
be
tuned
from
superhydrophilicity
(~
3.6°)
superhydrophobicity
151.6°).
Furthermore,
three
diverse
heterogeneous
were
constructed
various
applications
successfully
realized,
including
water
transport,
droplet
arrays,
wells.
This
work
may
provide
achieving
efficiently
multifunctional
steering
surfaces.
Nature Communications,
Год журнала:
2022,
Номер
13(1)
Опубликована: Сен. 26, 2022
Abstract
Inspired
by
insect
compound
eyes
(CEs)
that
feature
unique
optical
schemes
for
imaging,
there
has
recently
been
growing
interest
in
developing
optoelectronic
CE
cameras
with
comparable
size
and
functions.
However,
considering
the
mismatch
between
complex
3D
configuration
of
CEs
planar
nature
available
imaging
sensors,
it
is
currently
challenging
to
reach
this
end.
Here,
we
report
a
paradigm
miniature
integrated
camera
manufacturing
polymer
19~160
logarithmic
profile
ommatidia
via
femtosecond
laser
two-photon
polymerization.
In
contrast
μ-CEs
spherical
suffer
from
defocusing
problems,
as-obtained
permit
direct
integration
commercial
CMOS
detector,
because
depth-of-field
focus
range
all
are
significantly
increased.
The
μ-CE
enables
large
field-of-view
(90°),
spatial
position
identification
sensitive
trajectory
monitoring
moving
targets.
Moreover,
can
be
microfluidic
chip
serves
as
an
on-chip
real-time
microorganisms
monitoring.
insect-scale
provides
practical
route
integrating
well-developed
sensors
micro-optics
elements,
holding
great
promise
cutting-edge
applications
endoscopy
robot
vision.
Progress in Polymer Science,
Год журнала:
2023,
Номер
140, С. 101665 - 101665
Опубликована: Фев. 26, 2023
Nature
endows
numerous
organisms
with
the
ability
to
realize
their
basic
physiological
activities
through
stimulus-responsive
actuation.
Inspired
by
these
interesting
biological
structures,
various
biomimetic
hydrogel
actuators
excellent
controllability,
fast
response,
and
toughness
have
been
developed.
Here,
principles
of
enabling
behavior
in
polymer
materials
are
first
reviewed
for
example
subsequently
recent
progress
implementing
stimuli-response
bioinspired
being
discussed.
Particular
emphasis
is
on
mechanisms
underlying
mechanical
toughening
its
role
applications.
The
goal
highlight
progress,
find
common
threads,
discuss
fundamental
differences
determine
current
challenges
future
directions
this
field.
Advanced Functional Materials,
Год журнала:
2023,
Номер
33(39)
Опубликована: Фев. 22, 2023
Abstract
Two‐Photon
Lithography,
thanks
to
its
very
high
sub‐diffraction
resolution,
has
become
the
lithographic
technique
par
excellence
in
applications
requiring
small
feature
sizes
and
complex
3D
pattering.
Despite
this,
fabrication
times
required
for
extended
structures
remain
much
longer
than
those
of
other
competing
techniques
(UV
mask
lithography,
nanoimprinting,
etc.).
Its
low
throughput
prevents
wide
adoption
industrial
applications.
To
increase
it,
over
years
different
solutions
have
been
proposed,
although
their
usage
is
difficult
generalize
may
be
limited
depending
on
specific
application.
A
promising
strategy
further
opening
a
concrete
window
industry,
lies
combination
with
holography
approaches:
this
way
it
possible
generate
dozens
foci
from
single
laser
beam,
thus
parallelizing
periodic
structures,
or
engineer
intensity
distribution
writing
plane
way,
obtaining
microstructures
exposure.
Here,
fundamental
concepts
behind
high‐speed
Lithography
are
discussed,
literary
production
recent
that
exploits
such
reviewed,
contextualized
according
topic
covered.
Advanced Functional Materials,
Год журнала:
2023,
Номер
33(34)
Опубликована: Май 5, 2023
Abstract
Hydrogel
actuators,
capable
of
generating
reversible
deformation
in
response
to
external
stimulus,
are
widely
considered
as
new
emerging
intelligent
materials
for
applications
soft
robots,
smart
sensors,
artificial
muscles,
and
so
on.
Peptide
self‐assembly
is
applied
the
construction
hydrogel
due
their
excellent
stimulus
response.
However,
actuators
based
on
peptide
rarely
reported
explored.
In
this
study,
a
pH‐responsive
(MA‐FIID)
designed
introduced
into
poly(
N
‐isopropyl
acrylamide)
backbone
(PNIPAM)
construct
bilayer
heterogeneous
assembly
disassembly
molecules
under
different
pH
conditions.
These
peptide‐containing
can
perform
controllable
bending,
bucking,
complex
stimulation.
Meanwhile,
Hofmeister
effect
PNIPAM
hydrogels
endows
these
with
enhanced
mechanical
strength,
ionic
(CaCl
2
),
shape‐memory
property.
This
work
broadens
application
supramolecular
hydrogels,
also
provides
inspirations
materials.