Science China Materials,
Год журнала:
2024,
Номер
67(3), С. 729 - 751
Опубликована: Фев. 4, 2024
Graphynes
(GYs),
as
a
novel
carbon
allotrope,
are
composed
of
sp-
and
sp2-hybridized
atoms.
Among
them,
graphdiyne
(GDY)
is
the
most
widely
studied
has
received
great
attention.
Its
unique
sp-hybridization,
uniform
pores,
highly
conjugated
structures,
especially
GDY
with
high
crystallinity,
bring
excellent
electronic,
optic,
mechanical
characteristics,
making
them
extensively
used
in
electronic
devices,
energy
storage
conversion,
catalysis,
gas
separation,
seawater
desalination,
so
on.
However,
materials
still
face
challenges,
including
synthesis
crystalline
rapid
non-destructive
characterization
methods.
In
this
review,
we
primarily
summarize
design,
synthesis,
structural
high-crystallinity
GDY.
Various
applications
also
described,
which
may
new
opportunities
for
single-crystalline
materials.
Nature Communications,
Год журнала:
2024,
Номер
15(1)
Опубликована: Авг. 26, 2024
Controlling
the
precise
growth
of
atoms
is
necessary
to
achieve
manipulation
atomic
composition
and
position,
regulation
electronic
structure,
an
understanding
reactions
at
level.
Herein,
we
report
a
facile
method
for
ordered
anchoring
zero-valent
platinum
manganese
with
single-atom
thickness
on
graphdiyne
under
mild
conditions.
Due
strong
incomplete
charge
transfer
between
metal
atoms,
formation
clusters
nanoparticles
can
be
inhibited.
The
size,
structure
bimetallic
nanoplates
are
precisely
controlled
by
natural
structure-limiting
effect
graphdiyne.
Experimental
characterization
clearly
demonstrates
such
fine
control
process.
Electrochemical
measurements
show
that
active
site
platinum-manganese
interface
guarantees
high
catalytic
activity
selectivity
(~100%)
alkene-to-diol
conversion.
This
work
lays
solid
foundation
obtaining
high-performance
nanomaterials
engineering
site.
reports
growing
highly
Pt
Mn
single
layers
fully
activates
loaded
results
in
electrocatalytic
conversion
Angewandte Chemie International Edition,
Год журнала:
2024,
Номер
63(9)
Опубликована: Янв. 9, 2024
Abstract
The
manufacture
of
nitric
acid
(HNO
3
)
consumes
large
amounts
energy
and
causes
serious
environmental
pollution.
Electrochemical
synthesis
is
regarded
as
a
key
way
to
eliminate
carbon
emissions
from
the
chemicals
industry.
selective
electrosynthesis
HNO
nitrogen
was
achieved
by
controllable
assembly
cobalt
metal
on
graphdiyne
surface
using
powerful
tool
electrochemistry
at
ambient
conditions.
As
an
advanced
material,
(GDY)
has
conjugated
structure
its
rich
in
sp‐C
triple
bond
skeleton,
which
can
achieve
strong
interaction
with
atoms,
resulting
incomplete
charge
transfer
between
atoms.
experimental
theoretical
calculation
results
show
that
highly
oxidized
(HOCo/GDY)
selectively
efficiently
activate
convert
into
intermediate
*NO,
promotes
efficient
overall
conversion
performance
acid.
Thus,
highest
yield
(192.0
μg
h
−1
mg
Faradaic
efficiency
(21.5
%)
were
low
potentials.
Advanced Materials,
Год журнала:
2024,
Номер
36(30)
Опубликована: Май 10, 2024
Abstract
Artificial
heterostructures
with
structural
advancements
and
customizable
electronic
interfaces
are
fundamental
for
achieving
high‐performance
lithium‐ion
batteries
(LIBs).
Here,
a
design
idea
covalently
bonded
lateral/vertical
black
phosphorus
(BP)‐graphdiyne
oxide
(GDYO)
heterostructure
achieved
through
facile
ball‐milling
approach,
is
designed.
Lateral
heterogeneity
realized
by
the
sp
2
‐hybridized
mode
P‐C
bonds,
which
connect
atoms
at
edges
of
BP
carbon
terminal
acetylene
in
GDYO.
The
vertical
connection
heterojunction
GDYO
connected
P‐O‐C
bond.
Experimental
theoretical
studies
demonstrate
that
BP‐GDYO
incorporates
interfacial
engineering
features,
including
built‐in
electric
fields,
chemical
bond
interactions,
maximized
nanospace
confinement
effects.
Therefore,
exhibits
improved
electrochemical
kinetics
enhanced
stability.
Moreover,
ex‐
in‐situ
studies,
lithiation
mechanism
BP‐GDYO,
highlighting
introduction
inhibits
shuttle/dissolution
effect
intermediates,
hinders
volume
expansion,
provides
more
reactive
sites,
ultimately
promotes
reversible
lithium
storage,
clarified.
anode
storage
performance
high‐rate
capacity
long‐cycle
stability
(602.6
mAh
g
−1
after
1
000
cycles
2.0
A
).
proposed
universal
represents
conceptual
advance
building
LIBs
electrode.
Abstract
Flexible
electronics
has
emerged
as
a
continuously
growing
field
of
study.
Two‐dimensional
(2D)
materials
often
act
conductors
and
electrodes
in
electronic
devices,
holding
significant
promise
the
design
high‐performance,
flexible
electronics.
Numerous
studies
have
focused
on
harnessing
potential
these
for
development
such
devices.
However,
to
date,
incorporation
2D
rarely
been
summarized
or
reviewed.
Consequently,
there
is
an
urgent
need
develop
comprehensive
reviews
rapid
updates
this
evolving
landscape.
This
review
covers
progress
complex
material
architectures
based
materials,
including
interfaces,
heterostructures,
2D/polymer
composites.
Additionally,
it
explores
wearable
energy
storage
conversion,
display
touch
technologies,
biomedical
applications,
together
with
integrated
solutions.
Although
pursuit
high‐performance
high‐sensitivity
instruments
remains
primary
objective,
also
warrants
consideration.
By
combining
multiple
functionalities
into
singular
device,
augmented
by
machine
learning
algorithms,
we
can
potentially
surpass
performance
existing
technologies.
Finally,
briefly
discuss
future
trajectory
burgeoning
field.
discusses
recent
advancements
sensors
made
from
their
applications
architecture
device
design.
Science China Materials,
Год журнала:
2024,
Номер
67(3), С. 729 - 751
Опубликована: Фев. 4, 2024
Graphynes
(GYs),
as
a
novel
carbon
allotrope,
are
composed
of
sp-
and
sp2-hybridized
atoms.
Among
them,
graphdiyne
(GDY)
is
the
most
widely
studied
has
received
great
attention.
Its
unique
sp-hybridization,
uniform
pores,
highly
conjugated
structures,
especially
GDY
with
high
crystallinity,
bring
excellent
electronic,
optic,
mechanical
characteristics,
making
them
extensively
used
in
electronic
devices,
energy
storage
conversion,
catalysis,
gas
separation,
seawater
desalination,
so
on.
However,
materials
still
face
challenges,
including
synthesis
crystalline
rapid
non-destructive
characterization
methods.
In
this
review,
we
primarily
summarize
design,
synthesis,
structural
high-crystallinity
GDY.
Various
applications
also
described,
which
may
new
opportunities
for
single-crystalline
materials.
