Nature Communications,
Journal Year:
2024,
Volume and Issue:
15(1)
Published: Aug. 26, 2024
Controlling
the
precise
growth
of
atoms
is
necessary
to
achieve
manipulation
atomic
composition
and
position,
regulation
electronic
structure,
an
understanding
reactions
at
level.
Herein,
we
report
a
facile
method
for
ordered
anchoring
zero-valent
platinum
manganese
with
single-atom
thickness
on
graphdiyne
under
mild
conditions.
Due
strong
incomplete
charge
transfer
between
metal
atoms,
formation
clusters
nanoparticles
can
be
inhibited.
The
size,
structure
bimetallic
nanoplates
are
precisely
controlled
by
natural
structure-limiting
effect
graphdiyne.
Experimental
characterization
clearly
demonstrates
such
fine
control
process.
Electrochemical
measurements
show
that
active
site
platinum-manganese
interface
guarantees
high
catalytic
activity
selectivity
(~100%)
alkene-to-diol
conversion.
This
work
lays
solid
foundation
obtaining
high-performance
nanomaterials
engineering
site.
reports
growing
highly
Pt
Mn
single
layers
fully
activates
loaded
results
in
electrocatalytic
conversion
Chemical Society Reviews,
Journal Year:
2024,
Volume and Issue:
53(6), P. 3096 - 3133
Published: Jan. 1, 2024
The
latest
advancements
in
two-dimensional
organic–inorganic
van
der
Waals
heterojunctions,
including
their
classification,
construction,
and
device
applications,
elucidating
structure–property
relationship
based
on
interface
engineering.
Science China Materials,
Journal Year:
2024,
Volume and Issue:
67(3), P. 729 - 751
Published: Feb. 4, 2024
Graphynes
(GYs),
as
a
novel
carbon
allotrope,
are
composed
of
sp-
and
sp2-hybridized
atoms.
Among
them,
graphdiyne
(GDY)
is
the
most
widely
studied
has
received
great
attention.
Its
unique
sp-hybridization,
uniform
pores,
highly
conjugated
structures,
especially
GDY
with
high
crystallinity,
bring
excellent
electronic,
optic,
mechanical
characteristics,
making
them
extensively
used
in
electronic
devices,
energy
storage
conversion,
catalysis,
gas
separation,
seawater
desalination,
so
on.
However,
materials
still
face
challenges,
including
synthesis
crystalline
rapid
non-destructive
characterization
methods.
In
this
review,
we
primarily
summarize
design,
synthesis,
structural
high-crystallinity
GDY.
Various
applications
also
described,
which
may
new
opportunities
for
single-crystalline
materials.
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
36(30)
Published: May 10, 2024
Abstract
Artificial
heterostructures
with
structural
advancements
and
customizable
electronic
interfaces
are
fundamental
for
achieving
high‐performance
lithium‐ion
batteries
(LIBs).
Here,
a
design
idea
covalently
bonded
lateral/vertical
black
phosphorus
(BP)‐graphdiyne
oxide
(GDYO)
heterostructure
achieved
through
facile
ball‐milling
approach,
is
designed.
Lateral
heterogeneity
realized
by
the
sp
2
‐hybridized
mode
P‐C
bonds,
which
connect
atoms
at
edges
of
BP
carbon
terminal
acetylene
in
GDYO.
The
vertical
connection
heterojunction
GDYO
connected
P‐O‐C
bond.
Experimental
theoretical
studies
demonstrate
that
BP‐GDYO
incorporates
interfacial
engineering
features,
including
built‐in
electric
fields,
chemical
bond
interactions,
maximized
nanospace
confinement
effects.
Therefore,
exhibits
improved
electrochemical
kinetics
enhanced
stability.
Moreover,
ex‐
in‐situ
studies,
lithiation
mechanism
BP‐GDYO,
highlighting
introduction
inhibits
shuttle/dissolution
effect
intermediates,
hinders
volume
expansion,
provides
more
reactive
sites,
ultimately
promotes
reversible
lithium
storage,
clarified.
anode
storage
performance
high‐rate
capacity
long‐cycle
stability
(602.6
mAh
g
−1
after
1
000
cycles
2.0
A
).
proposed
universal
represents
conceptual
advance
building
LIBs
electrode.
InfoMat,
Journal Year:
2024,
Volume and Issue:
6(7)
Published: June 4, 2024
Abstract
Flexible
electronics
has
emerged
as
a
continuously
growing
field
of
study.
Two‐dimensional
(2D)
materials
often
act
conductors
and
electrodes
in
electronic
devices,
holding
significant
promise
the
design
high‐performance,
flexible
electronics.
Numerous
studies
have
focused
on
harnessing
potential
these
for
development
such
devices.
However,
to
date,
incorporation
2D
rarely
been
summarized
or
reviewed.
Consequently,
there
is
an
urgent
need
develop
comprehensive
reviews
rapid
updates
this
evolving
landscape.
This
review
covers
progress
complex
material
architectures
based
materials,
including
interfaces,
heterostructures,
2D/polymer
composites.
Additionally,
it
explores
wearable
energy
storage
conversion,
display
touch
technologies,
biomedical
applications,
together
with
integrated
solutions.
Although
pursuit
high‐performance
high‐sensitivity
instruments
remains
primary
objective,
also
warrants
consideration.
By
combining
multiple
functionalities
into
singular
device,
augmented
by
machine
learning
algorithms,
we
can
potentially
surpass
performance
existing
technologies.
Finally,
briefly
discuss
future
trajectory
burgeoning
field.
discusses
recent
advancements
sensors
made
from
their
applications
architecture
device
design.
Nature Communications,
Journal Year:
2024,
Volume and Issue:
15(1)
Published: Aug. 26, 2024
Controlling
the
precise
growth
of
atoms
is
necessary
to
achieve
manipulation
atomic
composition
and
position,
regulation
electronic
structure,
an
understanding
reactions
at
level.
Herein,
we
report
a
facile
method
for
ordered
anchoring
zero-valent
platinum
manganese
with
single-atom
thickness
on
graphdiyne
under
mild
conditions.
Due
strong
incomplete
charge
transfer
between
metal
atoms,
formation
clusters
nanoparticles
can
be
inhibited.
The
size,
structure
bimetallic
nanoplates
are
precisely
controlled
by
natural
structure-limiting
effect
graphdiyne.
Experimental
characterization
clearly
demonstrates
such
fine
control
process.
Electrochemical
measurements
show
that
active
site
platinum-manganese
interface
guarantees
high
catalytic
activity
selectivity
(~100%)
alkene-to-diol
conversion.
This
work
lays
solid
foundation
obtaining
high-performance
nanomaterials
engineering
site.
reports
growing
highly
Pt
Mn
single
layers
fully
activates
loaded
results
in
electrocatalytic
conversion
