Engineering Peptide-Based Molecular Baits for Targeted Fishing and Protein Profiling of Exosomes as a Liquid Biopsy for Gastrointestinal Adenocarcinoma DOI
Kun Xu, Yanting Hao, Han Gao

и другие.

Analytical Chemistry, Год журнала: 2024, Номер 97(1), С. 741 - 748

Опубликована: Дек. 30, 2024

High-performance isolation of exosomes as a promising liquid biopsy target is great importance for both fundamental research and clinical applications. This is, however, challenged by the prevalent heterogeneity highly complex nature biosamples. Here, we introduce use CD81-targeting peptide building block tailoring molecular baits exosome payload analysis in biofluids. To explore full potential multivalent interactions, peptide-functionalized affinity interfaces were covalently engineered with varied assembling topology, flexibility, local density recognition motif. Capable best fitting surface conformation CD81 on curved membranes, dual-layered capture interface (Exo-PepTrap2) tandem bivalent decoration outperforms monolayered branched architectures. Enabled multivalency-enhanced reaction antifouling ability, Exo-PepTrap2 achieved high yield purity targeted fishing cell culture media urine samples. By integration mass spectrometry-based proteomic profiling, differentially expressed proteins efficiently identified harvested biomarkers gastrointestinal adenocarcinoma. CD81-targeted platform provides new viewpoint multivalency-based versatile tool to information precise medicine.

Язык: Английский

A Targeted and Responsive Nanoprodrug Delivery System for Synergistic Glioma Chemotherapy DOI

Weiling Zhuo,

Wanyu Wang, Wenjie Zhou

и другие.

Small, Год журнала: 2024, Номер 20(30)

Опубликована: Март 3, 2024

Abstract Doxorubicin (DOX) is widely used as a chemotherapeutic agent for both hematologic and solid tumors reasonable candidate glioma treatment. However, its effectiveness hindered by significant toxicity drug resistance. Moreover, the presence of blood–brain barrier (BBB) brings crucial challenge to therapy. In response, GSH‐responsive actively targeted nanoprodrug delivery system (cRGD/PSDOX‐Cur@NPs) are developed. this system, disulfide bond‐bridged DOX prodrug (PEG‐SS‐DOX) designed release specifically in high glutathione (GSH) tumor environment, markedly reducing cardiotoxicity associated with DOX. To further address resistance, curcumin, serving P‐glycoprotein (P‐gp) inhibitor, effectively increased cellular concentration. Consequently, cRGD/PSDOX‐Cur@NPs exhibited synergistic anti‐tumor effects vitro. Furthermore, vivo experiments validated superior BBB penetration brain‐targeting abilities cRGD/PSDOX‐Cur@NPs, showcasing remarkable potential treating subcutaneous orthotopic gliomas. This research underscores that presents novel approach inhibiting while addressing resistance systemic toxicity.

Язык: Английский

Процитировано

8

How to optimize the immune checkpoint blockade therapy for cancers? DOI Creative Commons
Hui Guo, Yuchuan Hou, Chunxi Wang

и другие.

ONCOLOGIE, Год журнала: 2024, Номер 26(3), С. 343 - 348

Опубликована: Март 16, 2024

Abstract The realm of cancer therapy has been profoundly altered with the emergence immune checkpoint blockade (ICB) therapy, providing improved survival prospects for many patients some cancers. However, challenge achieving efficient or sustained therapeutic benefits underscores critical imperative to optimize ICB strategies. This review elucidates pivotal role predictive biomarkers in optimizing precision deciphering intricate dynamics associated response heterogeneity. Furthermore, it critically examines application nanotechnology-driven drug delivery as a promising avenue amplify efficacy, facilitating controlled and targeted release. Recognizing comprehensive dynamic interplay among tumor cells, stromal cells catalyzed transformative advances reverse translational research. approach enables researchers gain insights into underlying mechanisms responses, resistance mechanisms. convergence biomarkers, revolutionary nanotechnology, research emerges an indispensable focal point, propelling frontiers oncology within complex landscape therapy.

Язык: Английский

Процитировано

4

Iterative Design of a Prodrug Nanocarrier for Cell Cycle Arrest, Immune Modulation, and Enhanced T Cell Infiltration for Colon Cancer Therapy DOI
Zhenhan Feng, Mengmeng Qin,

Jinhong Jiang

и другие.

Nano Letters, Год журнала: 2025, Номер unknown

Опубликована: Фев. 10, 2025

Recent advancements in cancer therapy have highlighted the dual role of cyclin-dependent kinase 4/6 inhibitors (CDK4/6i) both cell cycle regulation and immune activation. However, applying CDK4/6i to immunologically unfavorable tumors is challenging due complex tumor microenvironment (TME), characterized by inadequate T recruitment exclusion mechanisms that hinder an effective antitumor immunity. In this work, we iteratively designed prodrug liposomal nanocarriers integrate multiple functions: inhibition through encapsulation CDK4/6i, activation via concurrent delivery oral gavage-inducing chemotherapy agent, overcoming incorporation a cholesterol prodrug. This iterative nanocarrier design effectively improves pharmacokinetic profile overcomes immunosuppressive TME, achieves superior efficacy, synergizes with checkpoint provide lasting effects various colon animal models.

Язык: Английский

Процитировано

0

Piezo‐Electrons Induced Endoplasmic Reticulum Protein Misfolding to Enhance Immune Checkpoint Blockage Cancer Therapy DOI
Zhuo Li, Meng Yuan, Jinhui Zhang

и другие.

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Апрель 14, 2025

Abstract The endoplasmic reticulum (ER) is a crucial organelle in eukaryotic cells that regulates protein synthesis, folding, and transport, playing vital role maintaining homeostasis functions. Tumor evade the immune surveillance killing of body by synthesizing checkpoint proteins ER, thereby inhibiting T cell‐mediated antitumor responses enhancing tumor tolerance, leading to poor efficacy cancer immunotherapy. Herein, an ultrasound‐triggered piezo‐nanomedicine designed with targeting function (BTO v ‐T ER ) achieve novel blockade therapy. Under ultrasound irradiation, BTO releases piezo‐electrons reducing properties disrupt redox cell reticulum, inducing misfolding apoptosis, which activates response. Meanwhile, due abnormal folding expression proteins, such as Programmed death ligand 1 (PD‐L1) downregulated, reactivating promoting strategy interfering processing various within via piezo‐catalysis provides approach for

Язык: Английский

Процитировано

0

Saponin Gallate-Loaded Gd-Doped Zinc–Gallium Layered Double Hydroxides (Zn/Ga@Gd-LDH) Nanocarrier for Attenuating NF-κB-Mediated Inflammation DOI

Momna Aslam,

Batool Fatima,

Rafia Batool

и другие.

ACS Applied Materials & Interfaces, Год журнала: 2025, Номер unknown

Опубликована: Апрель 24, 2025

This work describes a drug delivery system (DDS) based on the therapeutic anti-inflammatory efficacy of saponin gallate (SG), combination gallic acid and saponin, chemically conjugated via an ester linkage. formulation was loaded onto biocompatible gadolinium-doped zinc-gallium-layered double hydroxide (Zn/Ga@Gd-LDH) nanocarrier. FT-IR, XRD, SEM, HPLC were used to characterize synthesized materials. UV-visible spectroscopy employed investigate release from SG-Zn/Ga@Gd-LDH at optimized temperature (45 °C) pH (5). The kinetic behavior nanoparticles suggested that first-order model most appropriate for profile. regression value (R2) 0.96614 indicated optimal controlled effectiveness minimal adverse effects over 54 h. in vitro vivo models confirmed drug-loaded nanocarriers exhibited antioxidant, anti-inflammatory, anticancer properties. Western blotting analysis abrogates properties by halting phosphorylation pro-inflammatory proteins p-p65 decreasing CRP levels involved NF-κB pathway. effect reducing secretion proinflammatory cytokines. treatment against acute CCl4-induced liver injury showed potential histological parameters' study. Radiolabeling with 99mTc carried out determine its biodistribution. chromatographic results promising radiolabeling up 90% percentages. SPECT-CT imaging ex gamma counting Wistar rats revealed different clearance rates nanoparticles, aiding evaluation nanosystem. designed also demonstrated antioxidant due SG compound having IC50 127.45 μg/mL free radical scavenging activity. Ga@Gd-LDH tumor-suppressing ability 79.89 ± 3.91% viable cells breast cancer MCF-7 cells. developed could thus be conducive strategy inflammatory diseases.

Язык: Английский

Процитировано

0

Comparison of Protocols to Test Peptide Stability in Blood Plasma and Cell Culture Supernatants DOI Creative Commons

Anne T. Köhler,

Eva‐Maria Jülke,

Jan Stichel

и другие.

ACS Pharmacology & Translational Science, Год журнала: 2024, Номер 7(11), С. 3618 - 3625

Опубликована: Окт. 14, 2024

Due to their high specificity, peptides are promising candidates in drug development, but fast degradation often limits biological activity. Thus, a short half-life is one of the major challenges development new peptide therapeutics. Moreover, enzymatic cleavage can be reason for misleading results assays. Peptide stability assays typically consist incubation, precipitation, and detection steps. However, current methods differ greatly regarding these three steps, thus limiting compatibility. Here, we systematically evaluate different parameters First, quantified compared analyte loss during precipitation plasma proteins. Especially, broadly used by strong acids was found unsuitable, while mixtures organic solvents preserved more further analysis. Next, four fluorescently labeled model analyzed blood two cell culture supernatants. Strong variation dynamics patterns found. Finally, evaluated role fluorescent labeling on with isotopic labels, underlining individual advantages both methods. Altogether, data provide important analyzing comparing stability.

Язык: Английский

Процитировано

2

Nanomotors activating both cGAS-STING pathway and immune checkpoint blockade for tumor therapy and bioimaging DOI

Dan Jing,

Ji Zhang, Ziyi Li

и другие.

Talanta, Год журнала: 2024, Номер 284, С. 127258 - 127258

Опубликована: Ноя. 20, 2024

Язык: Английский

Процитировано

2

Engineering Peptide-Based Molecular Baits for Targeted Fishing and Protein Profiling of Exosomes as a Liquid Biopsy for Gastrointestinal Adenocarcinoma DOI
Kun Xu, Yanting Hao, Han Gao

и другие.

Analytical Chemistry, Год журнала: 2024, Номер 97(1), С. 741 - 748

Опубликована: Дек. 30, 2024

High-performance isolation of exosomes as a promising liquid biopsy target is great importance for both fundamental research and clinical applications. This is, however, challenged by the prevalent heterogeneity highly complex nature biosamples. Here, we introduce use CD81-targeting peptide building block tailoring molecular baits exosome payload analysis in biofluids. To explore full potential multivalent interactions, peptide-functionalized affinity interfaces were covalently engineered with varied assembling topology, flexibility, local density recognition motif. Capable best fitting surface conformation CD81 on curved membranes, dual-layered capture interface (Exo-PepTrap2) tandem bivalent decoration outperforms monolayered branched architectures. Enabled multivalency-enhanced reaction antifouling ability, Exo-PepTrap2 achieved high yield purity targeted fishing cell culture media urine samples. By integration mass spectrometry-based proteomic profiling, differentially expressed proteins efficiently identified harvested biomarkers gastrointestinal adenocarcinoma. CD81-targeted platform provides new viewpoint multivalency-based versatile tool to information precise medicine.

Язык: Английский

Процитировано

1