(Deep) eutectic solvents for the separation of platinum group metals and rare earth elements: characteristics, extraction mechanisms and state of the art

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 159497 - 159497

Опубликована: Янв. 1, 2025

Язык: Английский

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Critical metal extraction from spent battery cathodes and anticipated developments using next generation green solvents for achieving a net-zero future

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 160324 - 160324

Опубликована: Фев. 1, 2025

Язык: Английский

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DESignSolvents: an open platform for the search and prediction of the physicochemical properties of deep eutectic solvents

Green Chemistry, Год журнала: 2024, Номер 26(7), С. 3958 - 3967

Опубликована: Янв. 1, 2024

A web-resource, DESignSolvents, to provide users worldwide with the database of DES properties and corresponding prediction models.

Язык: Английский

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Review of ionic liquid and ionogel-based biomaterials for advanced drug delivery

Advances in Colloid and Interface Science, Год журнала: 2024, Номер 331, С. 103244 - 103244

Опубликована: Июнь 26, 2024

Ionic liquids (ILs) play a crucial role in the design of novel materials. The ionic nature ILs provides numerous advantages drug delivery, acting as green solvent or active ingredient to enhance solubility, permeability, and binding efficiency drugs. They could also function structuring agent development nano/micro particles for including micelles, vesicles, gels, emulsion, more. This review summarize IL-based gel structures with their advanced delivery applications. first part focuses on formulation applications delivery. second offers comprehensive overview recent gel. It aims offer new perspectives attract more attention open up avenues biomedical gels.

Язык: Английский

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Applications of Functional Polymeric Eutectogels

Macromolecular Rapid Communications, Год журнала: 2024, Номер 45(21)

Опубликована: Июль 15, 2024

Abstract Over the past two decades, deep eutectic solvents (DESs) have captured significant attention as an emergent class of that unique properties and applications in differing fields chemistry. One area where DES systems find utility is design polymeric gels, often referred to “eutectogels,” which can be prepared either using a replace traditional solvent, or monomers form part themselves. Due extensive network intramolecular interactions (e.g., hydrogen bonding) ionic species exist systems, eutectogels possess appealing material properties—high adhesive strength, tuneable viscosity, rapid polymerization kinetics, good conductivity, well high strength flexibility. In addition, non‐covalent crosslinking approaches are possible due inherent these materials. This review considers several key eutectogels, including organic electronics, wearable sensor technologies, 3D printing resins, adhesives, range various biomedical applications. The design, synthesis, discussed, addition advantages this synthetic approach comparison gel design. Perspectives on future directions field also highlighted.

Язык: Английский

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Dynamic Properties and Diverse Applications of Deep Eutectic Solvents

Journal of Ionic Liquids, Год журнала: 2025, Номер 5(1), С. 100135 - 100135

Опубликована: Янв. 29, 2025

Язык: Английский

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Solvent Screening for Separation Processes Using Machine Learning and High-Throughput Technologies

Chem & Bio Engineering, Год журнала: 2025, Номер 2(4), С. 210 - 228

Опубликована: Март 5, 2025

As the chemical industry shifts toward sustainable practices, there is a growing initiative to replace conventional fossil-derived solvents with environmentally friendly alternatives such as ionic liquids (ILs) and deep eutectic (DESs). Artificial intelligence (AI) plays key role in discovery design of novel development green processes. This review explores latest advancements AI-assisted solvent screening specific focus on machine learning (ML) models for physicochemical property prediction separation process design. Additionally, this paper highlights recent progress automated high-throughput (HT) platforms screening. Finally, discusses challenges prospects ML-driven HT strategies optimization. To end, provides insights advance future

Язык: Английский

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eutXG: A Machine-Learning Model to Understand and Predict the Melting Point of Novel X-Bonded Deep Eutectic Solvents

ACS Sustainable Chemistry & Engineering, Год журнала: 2024, Номер 12(30), С. 11260 - 11273

Опубликована: Июль 16, 2024

We present the application of an extreme gradient boosting model (eutXG) to predict melting point (MP) deep eutectic solvents (DES). The is based on XGBoost, a decision tree ensemble designed be highly scalable that enables superior training speed and prediction accuracy. selected model─trained with molecular fingerprints, molar ratios, chemical descriptors─enabled MPs DES average accuracy 97.6%, which represents difference just ±2.4% respect values reported in literature. Using SHapley Additive exPlanations (SHAP), further insights into relative importance different inputs used train machine learning were identified. Moreover, generalization ability eutXG was critically assessed by comparing predicted vs experimentally determined MP series novel halogen bonding, developed mixing tetraalkylammonium triiodide salts (NPe4I3 or NHex4I3) organoiodines, such as 1,2-diiodotetrafluorobenzene (o-F4DIB), 1,3-diiodotetrafluorobenzene (m-F4DIB), 2,5-diiodothiophene (2,5-DIT), demonstrating its actual only 2 K. Our results not reinforce having (at least some) representative data for step increase model's predictions but also demonstrate accelerate development applications this entirely new class hydrophobic DES, potentially impacting wide range fields from pharmaceuticals agrochemicals.

Язык: Английский

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Eutectogels: The Multifaceted Soft Ionic Materials of Tomorrow

JACS Au, Год журнала: 2024, Номер 4(10), С. 3744 - 3758

Опубликована: Окт. 3, 2024

Eutectogels, a rising category of soft materials, have recently garnered significant attention owing to their remarkable potential in various domains. This innovative class materials consists eutectic solvent immobilized three-dimensional network structure. The use eco-friendly and cost-effective solvents further emphasizes the appeal these multiple applications. Eutectogels exhibit key characteristics most solvents, including environmental friendliness, facile preparation, low vapor pressure, good ionic conductivity. Moreover, they can be tailored display functionalities such as self-healing capability, adhesiveness, antibacterial properties, which are facilitated by incorporating specific combinations mixture constituents. perspective article delves into current landscape challenges associated with eutectogels, particularly focusing on applications CO

Язык: Английский

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Recent advances and new trends in the use of deep eutectic solvents in organic synthesis and other applications

Journal of Molecular Liquids, Год журнала: 2025, Номер unknown, С. 127510 - 127510

Опубликована: Апрель 1, 2025

Язык: Английский

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