Chemical Engineering Communications,
Journal Year:
2024,
Volume and Issue:
unknown, P. 1 - 31
Published: Dec. 30, 2024
Research
focus
has
turned
to
sustainable
and
ecologically
friendly
energy
sources
due
the
growing
dependence
on
nonrenewable
fuels.
The
lignocellulosic
biomass's
(LCB)
intrinsic
recalcitrance
makes
bioprocess's
downstream
processing
difficult.
Over
past
20
years,
pretreatment
procedures
have
drawn
a
lot
of
attention
since
they
are
acknowledged
as
essential
operations
for
effective
biomass
refining.
In
order
achieve
more
practices,
deep
eutectic
solvents
(DESs)
proven
be
useful
LCB
valorization.
DESs
thermochemically
stable,
recyclable,
non-flammable,
contain
very
little
vapor
pressure.
present
article,
an
extensive
summarization
types,
characteristics,
functions
in
efficient
conversion
sugarcane
bagasse
is
reviewed.
addition
outlining
principles
DES
composition,
overview
provided
factors
influencing
ChCl-DES-assisted
extraction
compositional
components
from
bagasse.
Furthermore,
in-depth
insight
into
mechanism
behind
ChCl-based-DES
reactions
will
provide
highlights
future
studies.
most
recent
advancements
years
2018–2023
DES-based
valorization
various
products
then
thoroughly
covered.
Finally,
paper
concluded
with
discussion
technical
issues
potential
directions
research
works.
Advances in Colloid and Interface Science,
Journal Year:
2024,
Volume and Issue:
331, P. 103244 - 103244
Published: June 26, 2024
Ionic
liquids
(ILs)
play
a
crucial
role
in
the
design
of
novel
materials.
The
ionic
nature
ILs
provides
numerous
advantages
drug
delivery,
acting
as
green
solvent
or
active
ingredient
to
enhance
solubility,
permeability,
and
binding
efficiency
drugs.
They
could
also
function
structuring
agent
development
nano/micro
particles
for
including
micelles,
vesicles,
gels,
emulsion,
more.
This
review
summarize
IL-based
gel
structures
with
their
advanced
delivery
applications.
first
part
focuses
on
formulation
applications
delivery.
second
offers
comprehensive
overview
recent
gel.
It
aims
offer
new
perspectives
attract
more
attention
open
up
avenues
biomedical
gels.
Macromolecular Rapid Communications,
Journal Year:
2024,
Volume and Issue:
45(21)
Published: July 15, 2024
Abstract
Over
the
past
two
decades,
deep
eutectic
solvents
(DESs)
have
captured
significant
attention
as
an
emergent
class
of
that
unique
properties
and
applications
in
differing
fields
chemistry.
One
area
where
DES
systems
find
utility
is
design
polymeric
gels,
often
referred
to
“eutectogels,”
which
can
be
prepared
either
using
a
replace
traditional
solvent,
or
monomers
form
part
themselves.
Due
extensive
network
intramolecular
interactions
(e.g.,
hydrogen
bonding)
ionic
species
exist
systems,
eutectogels
possess
appealing
material
properties—high
adhesive
strength,
tuneable
viscosity,
rapid
polymerization
kinetics,
good
conductivity,
well
high
strength
flexibility.
In
addition,
non‐covalent
crosslinking
approaches
are
possible
due
inherent
these
materials.
This
review
considers
several
key
eutectogels,
including
organic
electronics,
wearable
sensor
technologies,
3D
printing
resins,
adhesives,
range
various
biomedical
applications.
The
design,
synthesis,
discussed,
addition
advantages
this
synthetic
approach
comparison
gel
design.
Perspectives
on
future
directions
field
also
highlighted.
JACS Au,
Journal Year:
2024,
Volume and Issue:
4(10), P. 3744 - 3758
Published: Oct. 3, 2024
Eutectogels,
a
rising
category
of
soft
materials,
have
recently
garnered
significant
attention
owing
to
their
remarkable
potential
in
various
domains.
This
innovative
class
materials
consists
eutectic
solvent
immobilized
three-dimensional
network
structure.
The
use
eco-friendly
and
cost-effective
solvents
further
emphasizes
the
appeal
these
multiple
applications.
Eutectogels
exhibit
key
characteristics
most
solvents,
including
environmental
friendliness,
facile
preparation,
low
vapor
pressure,
good
ionic
conductivity.
Moreover,
they
can
be
tailored
display
functionalities
such
as
self-healing
capability,
adhesiveness,
antibacterial
properties,
which
are
facilitated
by
incorporating
specific
combinations
mixture
constituents.
perspective
article
delves
into
current
landscape
challenges
associated
with
eutectogels,
particularly
focusing
on
applications
CO
ACS Sustainable Chemistry & Engineering,
Journal Year:
2024,
Volume and Issue:
12(30), P. 11260 - 11273
Published: July 16, 2024
We
present
the
application
of
an
extreme
gradient
boosting
model
(eutXG)
to
predict
melting
point
(MP)
deep
eutectic
solvents
(DES).
The
is
based
on
XGBoost,
a
decision
tree
ensemble
designed
be
highly
scalable
that
enables
superior
training
speed
and
prediction
accuracy.
selected
model─trained
with
molecular
fingerprints,
molar
ratios,
chemical
descriptors─enabled
MPs
DES
average
accuracy
97.6%,
which
represents
difference
just
±2.4%
respect
values
reported
in
literature.
Using
SHapley
Additive
exPlanations
(SHAP),
further
insights
into
relative
importance
different
inputs
used
train
machine
learning
were
identified.
Moreover,
generalization
ability
eutXG
was
critically
assessed
by
comparing
predicted
vs
experimentally
determined
MP
series
novel
halogen
bonding,
developed
mixing
tetraalkylammonium
triiodide
salts
(NPe4I3
or
NHex4I3)
organoiodines,
such
as
1,2-diiodotetrafluorobenzene
(o-F4DIB),
1,3-diiodotetrafluorobenzene
(m-F4DIB),
2,5-diiodothiophene
(2,5-DIT),
demonstrating
its
actual
only
2
K.
Our
results
not
reinforce
having
(at
least
some)
representative
data
for
step
increase
model's
predictions
but
also
demonstrate
accelerate
development
applications
this
entirely
new
class
hydrophobic
DES,
potentially
impacting
wide
range
fields
from
pharmaceuticals
agrochemicals.
This
review
explores
the
application
of
machine
learning
in
predicting
and
optimizing
key
physicochemical
properties
deep
eutectic
solvents,
including
CO2
solubility,
density,
electrical
conductivity,
heat
capacity,
melting
temperature,
surface
tension,
viscosity.
By
leveraging
learning,
researchers
aim
to
enhance
understanding
customization
a
critical
step
expanding
their
use
across
various
industrial
research
domains.
The
integration
represents
significant
advancement
tailoring
solvents
for
specific
applications,
marking
progress
toward
development
greener
more
efficient
processes.
As
continues
unlock
full
potential
it
is
expected
play
an
increasingly
pivotal
role
revolutionizing
sustainable
chemistry
driving
innovations
environmental
technology.
