Recent Advances and Perspectives in Synthetic Applications of Silylboronates as Silyl Radical Precursors DOI Creative Commons
Zhihua Cai,

Qing-Qing Bu,

Xi-Yu Wang

и другие.

Chemical Science, Год журнала: 2024, Номер unknown

Опубликована: Дек. 26, 2024

This review summarizes the recent advances in synthetic applications of silylboronates as silyl radical precursors, discusses advantages and limitations each method, illustrates chances still open for further exploration.

Язык: Английский

Palladium-catalyzed cascade cyclization of α,β-unsaturated N-tosylhydrazones with iodoarenes : access to 2H-chromenes and 2H-quinolines DOI

Yiyi Zheng,

Xi-Wei Zhu,

Yi-Yun Pan

и другие.

Organic & Biomolecular Chemistry, Год журнала: 2024, Номер 22(46), С. 9121 - 9124

Опубликована: Янв. 1, 2024

A palladium-catalyzed cascade reaction of α,β-unsaturated N -tosylhydrazones with iodoarene derivatives containing a nucleophilic group is described.

Язык: Английский

Процитировано

0
Nickel-catalyzed stereospecific reductive cross-coupling of vinyl chlorosilanes with axially chiral biaryl electrophiles DOI
Tiantian Yin,

Shiyuan Sui,

Shuqi Li

и другие.

Chemical Communications, Год журнала: 2024, Номер 60(96), С. 14204 - 14207

Опубликована: Янв. 1, 2024

Nickel-catalyzed stereospecific reductive cross-coupling of vinyl chlorosilanes with chiral biaryl electrophiles for the synthesis axially organosilanes.

Язык: Английский

Процитировано

0
Samarium Diiodide/Samarium-Mediated Deoxygenative Hydrosilylation of Ketones DOI

Ruxing Li,

Yilin Ma, Peixin Zhang

и другие.

The Journal of Organic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 21, 2024

The first deoxygenative hydrosilylation of ketones promoted by samarium diiodide and has been reported. In this approach, secondary alkyl silanes are synthesized from unactivated chlorosilanes in one step. carbonyl group is activated SmI2-mediated single-electron transfer process, which follows a elimination O=Sm. Broad substrate scope excellent functional tolerance demonstrated.

Язык: Английский

Процитировано

0
Asymmetric Migratory Tsuji–Wacker Oxidation Enables the Enantioselective Synthesis of Hetero- and Isosteric Diarylmethanes DOI Creative Commons
Emily Frank, Sooyoung Park, Elias Harrer

и другие.

Journal of the American Chemical Society, Год журнала: 2024, Номер 146(50), С. 34383 - 34393

Опубликована: Дек. 7, 2024

Diarylmethanes play, in part, a pivotal role the design of highly potent, chiral, nonracemic drugs whose bioactivity is typically affected by substitution pattern their arene units. In this context, certain arenes such as

Язык: Английский

Процитировано

0
Recent Advances and Perspectives in Synthetic Applications of Silylboronates as Silyl Radical Precursors DOI Creative Commons
Zhihua Cai,

Qing-Qing Bu,

Xi-Yu Wang

и другие.

Chemical Science, Год журнала: 2024, Номер unknown

Опубликована: Дек. 26, 2024

This review summarizes the recent advances in synthetic applications of silylboronates as silyl radical precursors, discusses advantages and limitations each method, illustrates chances still open for further exploration.

Язык: Английский

Процитировано

0