Recent Advances and Perspectives in Synthetic Applications of Silylboronates as Silyl Radical Precursors DOI Creative Commons
Zhihua Cai,

Qing-Qing Bu,

Xi-Yu Wang

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 26, 2024

This review summarizes the recent advances in synthetic applications of silylboronates as silyl radical precursors, discusses advantages and limitations each method, illustrates chances still open for further exploration.

Language: Английский

Palladium-catalyzed cascade cyclization of α,β-unsaturated N-tosylhydrazones with iodoarenes : access to 2H-chromenes and 2H-quinolines DOI

Yiyi Zheng,

Xi-Wei Zhu,

Yi-Yun Pan

et al.

Organic & Biomolecular Chemistry, Journal Year: 2024, Volume and Issue: 22(46), P. 9121 - 9124

Published: Jan. 1, 2024

A palladium-catalyzed cascade reaction of α,β-unsaturated N -tosylhydrazones with iodoarene derivatives containing a nucleophilic group is described.

Language: Английский

Citations

0
Nickel-catalyzed stereospecific reductive cross-coupling of vinyl chlorosilanes with axially chiral biaryl electrophiles DOI
Tiantian Yin,

Shiyuan Sui,

Shuqi Li

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(96), P. 14204 - 14207

Published: Jan. 1, 2024

Nickel-catalyzed stereospecific reductive cross-coupling of vinyl chlorosilanes with chiral biaryl electrophiles for the synthesis axially organosilanes.

Language: Английский

Citations

0
Samarium Diiodide/Samarium-Mediated Deoxygenative Hydrosilylation of Ketones DOI

Ruxing Li,

Yilin Ma, Peixin Zhang

et al.

The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 21, 2024

The first deoxygenative hydrosilylation of ketones promoted by samarium diiodide and has been reported. In this approach, secondary alkyl silanes are synthesized from unactivated chlorosilanes in one step. carbonyl group is activated SmI2-mediated single-electron transfer process, which follows a elimination O=Sm. Broad substrate scope excellent functional tolerance demonstrated.

Language: Английский

Citations

0
Asymmetric Migratory Tsuji–Wacker Oxidation Enables the Enantioselective Synthesis of Hetero- and Isosteric Diarylmethanes DOI Creative Commons
Emily Frank, Sooyoung Park, Elias Harrer

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(50), P. 34383 - 34393

Published: Dec. 7, 2024

Diarylmethanes play, in part, a pivotal role the design of highly potent, chiral, nonracemic drugs whose bioactivity is typically affected by substitution pattern their arene units. In this context, certain arenes such as

Language: Английский

Citations

0
Recent Advances and Perspectives in Synthetic Applications of Silylboronates as Silyl Radical Precursors DOI Creative Commons
Zhihua Cai,

Qing-Qing Bu,

Xi-Yu Wang

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 26, 2024

This review summarizes the recent advances in synthetic applications of silylboronates as silyl radical precursors, discusses advantages and limitations each method, illustrates chances still open for further exploration.

Language: Английский

Citations

0