Chemical Society Reviews, Год журнала: 2025, Номер unknown
Опубликована: Янв. 1, 2025
This review summarizes recent advancements in the synthetic strategies of ionic porous materials, and highlights synergistic interplay task-specific interactions with pore structure key applications, including gas separation catalysis.
Язык: Английский
Materials Science and Engineering R Reports, Год журнала: 2024, Номер 157, С. 100771 - 100771
Опубликована: Янв. 30, 2024
Язык: Английский
Процитировано
41
Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(28)
Опубликована: Май 7, 2024
Alkali metals (e.g. Li, Na, and K) multivalent Zn, Mg, Ca, Al) have become star anodes for developing high-energy-density rechargeable batteries due to their high theoretical capacity excellent conductivity. However, the inevitable dendrites unstable interfaces of metal pose challenges safety stability batteries. To address these issues, covalent organic frameworks (COFs), as emerging materials, been widely investigated regular porous structure, flexible molecular design, specific surface area. In this minireview, we summarize research progress COFs in stabilizing anodes. First, present origins delve into advantages based on physical/chemical properties alkali metals. Then, special attention has paid application host design anodes, artificial solid electrolyte interfaces, additives, solid-state electrolytes, separator modifications. Finally, a new perspective is provided from pore modulation, synthesis COFs.
Язык: Английский
Процитировано
38
Small Structures, Год журнала: 2024, Номер 5(5)
Опубликована: Фев. 5, 2024
In current research, achieving carbon neutrality has become a primary focus through the utilization of various conversion technologies that transform dioxide (CO 2 ) into valuable chemicals or fuels. Covalent organic frameworks (COFs), as emerging crystalline polymers, offer distinct advantages in CO compared to other materials. These include controllable nanoscale pores, predefined functional units, editable framework structures, and rich conjugated systems. The unique characteristics COFs make them highly promising electrocatalysts for conversion. This review provides comprehensive overview pioneering works recent research on COF‐based materials electrochemical reduction reaction. offers analysis design principles reactive sites, skeleton pore functionalities, 3D frameworks, morphologies, composite COFs, aiming enhance electrocatalysis. Finally, this presents some recommendations material design, reaction mechanisms, theoretical computations understanding mechanisms further facilitate high‐performance electrocatalysts.
Язык: Английский
Процитировано
31
Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(22)
Опубликована: Апрель 2, 2024
The ion extraction and electro/photo catalysis are promising methods to address environmental energy issues. Covalent organic frameworks (COFs) a class of template construct absorbents catalysts because their stable frameworks, high surface areas, controllable pore environments, well-defined catalytic sites. Among them, ionic COFs as unique crystalline porous materials, with charges in the or along walls, have shown different properties resulting performance these applications those from charge-neutral COFs. In this review, current research progress based on for conversion, including cationic/anionic materials is reviewed terms synthesis strategy, modification methods, mechanisms adsorption catalysis, well applications. Finally, we demonstrated challenges future development design strategies
Язык: Английский
Процитировано
31
ACS Nano, Год журнала: 2024, Номер 18(33), С. 21804 - 21835
Опубликована: Авг. 8, 2024
Covalent organic frameworks (COFs) are crystalline networks with extended backbones cross-linked by covalent bonds. Due to the semiconductive properties and variable metal coordinating sites, along rapid development in linkage chemistry, utilization of COFs photocatalytic CO2RR has attracted many scientists' interests. In this Review, we summarize latest research progress on for CO2 reduction. first part, present COF linkages that have been used CO2RR, discuss four mechanisms including as intrinsic photocatalysts, photosensitive motifs metalated semiconductors heterojunction photocatalysts. Then, principles structural designs functional building units stacking mode exchange. Finally, outlook challenges provided. This Review is intended give some guidance design synthesis diverse different linkages, various structures, divergent modes efficient photoreduction CO2.
Язык: Английский
Процитировано
27
Advanced Science, Год журнала: 2024, Номер 11(28)
Опубликована: Май 13, 2024
The photocatalytic reduction of CO
Язык: Английский
Процитировано
22
Chemical Society Reviews, Год журнала: 2024, Номер 53(14), С. 7531 - 7565
Опубликована: Янв. 1, 2024
Covalent organic frameworks (COFs) have recently seen significant advancements. Large quantities of structurally & functionally oriented COFs with a wide range applications, such as gas adsorption, catalysis, separation, and drug delivery, been explored. Recent achievements in this field are primarily focused on advancing synthetic methodologies, catalysts playing crucial role achieving highly crystalline COF materials, particularly those featuring novel linkages chemistry. A series reviews already published over the last decade, covering fundamentals, synthesis, applications COFs. However, despite pivotal that auxiliaries play forming materials adjusting their properties (
Язык: Английский
Процитировано
21
Angewandte Chemie International Edition, Год журнала: 2024, Номер unknown
Опубликована: Июль 8, 2024
Organic piezoelectric nanogenerators (PENGs) are attractive in harvesting mechanical energy for various self-powering systems. However, their practical applications severely restricted by low output open circuit voltage. To address this issue, herein, we prepared two two-dimensional (2D) covalent organic frameworks (COFs, CityU-13 and CityU-14), functionalized with fluorinated alkyl chains PENGs. The piezoelectricity of both COFs was evidenced switchable polarization, characteristic butterfly amplitude loops, phase hysteresis conspicuous surface potentials high coefficient value (d
Язык: Английский
Процитировано
19
Angewandte Chemie, Год журнала: 2024, Номер 136(22)
Опубликована: Апрель 2, 2024
Abstract The ion extraction and electro/photo catalysis are promising methods to address environmental energy issues. Covalent organic frameworks (COFs) a class of template construct absorbents catalysts because their stable frameworks, high surface areas, controllable pore environments, well‐defined catalytic sites. Among them, ionic COFs as unique crystalline porous materials, with charges in the or along walls, have shown different properties resulting performance these applications those from charge‐neutral COFs. In this review, current research progress based on for conversion, including cationic/anionic materials is reviewed terms synthesis strategy, modification methods, mechanisms adsorption catalysis, well applications. Finally, we demonstrated challenges future development design strategies
Язык: Английский
Процитировано
18
Chemical Communications, Год журнала: 2025, Номер unknown
Опубликована: Янв. 1, 2025
This review identifies COFs as promising materials for radioactive iodine adsorption, and highlights how structural functional modifications, including electron-rich, flexible, ionic COF nanosheets significantly enhance capture.
Язык: Английский
Процитировано
2