Responsive structural adaptability in ultra-microporous frameworks: guest recognition and macroscopic shape transformations induced by spin transitions within single crystals DOI
Yuting Yang, Wei Guo,

Yu-Xia Li

и другие.

Inorganic Chemistry Frontiers, Год журнала: 2024, Номер 11(18), С. 5946 - 5956

Опубликована: Янв. 1, 2024

A coordination framework undergoes responsive structural adaptability, associated with spin-crossover activation and CO 2 /C H separation. Dihydrogen bonds ensure efficient unit functions, enabling a macroscopic shape change in the single crystal.

Язык: Английский

Multiple Energy Transfer Modes From o‐Carborane Dyad Induced by Synergetic Conformational Regulations and Intense Circularly Polarized Luminescence in Self‐Assembly Aggregates DOI
Junfeng Li, Yu Chen, Wei Wu

и другие.

Advanced Optical Materials, Год журнала: 2024, Номер unknown

Опубликована: Окт. 15, 2024

Abstract Photothermal modulated excited conformations in traditional optoelectronic materials have been extensively investigated for the manipulation of emissive properties. However, photoinduced molecular synergetic conformational changes, which are promising controlling intramolecular energy transfer modes through orbital breaking, never explored. Herein, a novel o ‐carborane dyad composed carbazole units as electron donors and triazine derivatives acceptors is demonstrated to achieve conformation‐dependent emissions abundant via changes. Notably, resulting exhibited multiple changes that induced different involved “through space” bond.” Exactly, spin from singlet triplet state took flip accompanied by orbitals π–π space charge style π σ bond mode. The circularly polarized luminescence (CPL) properties systematically investigated, exhibiting intense CPL with large g lum values. These results provide perspectives elucidating complicated emission aggregated states, well unique on relationship between conformations, modes, breaking.

Язык: Английский

Процитировано

2
Superhydrophobic MOF/polymer composite with hierarchical porosity for boosting catalytic performance in an humid environment DOI
Ming‐Liang Gao, Shuo Liu, Lin Liu

и другие.

Nanoscale, Год журнала: 2024, Номер 16(22), С. 10637 - 10644

Опубликована: Янв. 1, 2024

The superhydrophobic nanocomposite with hierarchical porosity was prepared by growing ZIF-8 nanocrystals within PDVB-vim to form ZIF-8/PDVB-vim composite. In an humid environment, the composite exhibits enhanced catalytic activity in Friedel–Crafts reaction.

Язык: Английский

Процитировано

1
Delayed linker addition (DLA) synthesis of dual linker ZIF-8 for separation mono- and di-branched isomers of hexane DOI
Jiayan Zhu, Lin Zhang, Zongjian Liu

и другие.

Separation and Purification Technology, Год журнала: 2024, Номер 350, С. 127947 - 127947

Опубликована: Май 14, 2024

Язык: Английский

Процитировано

1
Auxiliary ligand influence on interpenetration and C2H2/CO2 separation in NDI based isoreticular MOFs DOI
Meng Guo, Ziyi Jiang, Susu Wu

и другие.

Inorganic Chemistry Communications, Год журнала: 2024, Номер 165, С. 112578 - 112578

Опубликована: Май 19, 2024

Язык: Английский

Процитировано

1
Responsive structural adaptability in ultra-microporous frameworks: guest recognition and macroscopic shape transformations induced by spin transitions within single crystals DOI
Yuting Yang, Wei Guo,

Yu-Xia Li

и другие.

Inorganic Chemistry Frontiers, Год журнала: 2024, Номер 11(18), С. 5946 - 5956

Опубликована: Янв. 1, 2024

A coordination framework undergoes responsive structural adaptability, associated with spin-crossover activation and CO 2 /C H separation. Dihydrogen bonds ensure efficient unit functions, enabling a macroscopic shape change in the single crystal.

Язык: Английский

Процитировано

1