Superhydrophobic MOF/polymer composite with hierarchical porosity for boosting catalytic performance in an humid environment

Nanoscale, Journal Year: 2024, Volume and Issue: 16(22), P. 10637 - 10644

Published: Jan. 1, 2024

The superhydrophobic nanocomposite with hierarchical porosity was prepared by growing ZIF-8 nanocrystals within PDVB-vim to form ZIF-8/PDVB-vim composite. In an humid environment, the composite exhibits enhanced catalytic activity in Friedel–Crafts reaction.

Language: Английский

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Auxiliary ligand influence on interpenetration and C2H2/CO2 separation in NDI based isoreticular MOFs

Inorganic Chemistry Communications, Journal Year: 2024, Volume and Issue: 165, P. 112578 - 112578

Published: May 19, 2024

Language: Английский

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A Pd-catalyzed route to carborane-fused boron heterocycles

Chemical Science, Journal Year: 2024, Volume and Issue: 15(27), P. 10392 - 10401

Published: Jan. 1, 2024

A Pd-catalyzed cross-coupling system has been developed to achieve vicinal diamination of 9,10-dibromo-carborane with NH-heterocycles and anilines. These products can be further converted carborane-fused six- seven-membered heterocycles.

Language: Английский

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Responsive structural adaptability in ultra-microporous frameworks: guest recognition and macroscopic shape transformations induced by spin transitions within single crystals

Inorganic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(18), P. 5946 - 5956

Published: Jan. 1, 2024

A coordination framework undergoes responsive structural adaptability, associated with spin-crossover activation and CO 2 /C H separation. Dihydrogen bonds ensure efficient unit functions, enabling a macroscopic shape change in the single crystal.

Language: Английский

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Nitrogen‐Site Engineering in Covalent Organic Frameworks for H₂O₂ Photogeneration via Dual Channels of Indirect Two‐Electron O₂ Reduction

Small, Journal Year: 2024, Volume and Issue: 20(47)

Published: Aug. 15, 2024

Photocatalytic H

Language: Английский

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