Odorless Synthesis of Thioglycosides Using Isothiouronium Salts DOI
J. Liu, Li Tang, Jie Zhang

и другие.

Опубликована: Янв. 1, 2024

Язык: Английский

Modular three-component radical fluoroalkyl-sulfuration of unactivated alkenes DOI

Gao-feng Yang,

Zhi Liu, Kai Liu

и другие.

CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Год журнала: 2025, Номер 69, С. 249 - 258

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

1
Synthesis of Thioethers via Nickel-Catalyzed Cross-Coupling of Aryl Halides with Ketene Dithioacetal DOI

Baolong Xu,

Shaowen Ling,

Shengping Zheng

и другие.

Organic Letters, Год журнала: 2025, Номер unknown

Опубликована: Фев. 9, 2025

Herein, we present a nickel-catalyzed C–S cross-coupling between aryl halides and ketene dithioacetals under "base-free" conditions without an exogenous ligand. By employing easily available as sulfide donors, this reaction affords broad range of unsymmetrical alkyl-aryl sulfides using odorous toxic thiols. The newly developed catalytic methodology features excellent functional group tolerance, wide substrate scope, diverse downstream synthesis. Preliminary mechanism investigations reveal that Ni(I)/Ni(III) cycle might be involved.

Язык: Английский

Процитировано

1
Photochemical Synthesis of Thioesters from Aryl Halides and Carboxylic Acids DOI Creative Commons
Shuo Wu, Paolo Melchiorre

Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(37)

Опубликована: Июнь 18, 2024

Thioesters are important in synthesis, materials science, and biology, their preparation traditionally relies on the use of disagreeable thiols. Here, we report a thiol-free protocol that stitches together widespread carboxylic acids aryl halides, producing diverse array thioesters. Crucial to this strategy is discovery tetramethylthiourea can serve as both sulfur source and, upon direct excitation by purple light, strong reductant, suitable for activating halides via single-electron transfer. Coupling resulting radicals provides an isothiouronium ion intermediate, which be attacked polar pathway, affording thioester products under mild conditions.

Язык: Английский

Процитировано

6
Bromothiolation of Arynes for the Synthesis of 2-Bromobenzenethiol Equivalents DOI Creative Commons

Shinya Tabata,

Suguru Yoshida

Organic Letters, Год журнала: 2024, Номер 26(18), С. 3816 - 3821

Опубликована: Апрель 30, 2024

A new method to synthesize o-bromobenzenethiol equivalents through aryne intermediates is disclosed. Various are prepared by the bromothiolation of with potassium xanthates. Aryl xanthates serve in synthesis diverse organosulfurs involving phenothiazines and thianthrenes further transformations.

Язык: Английский

Процитировано

5
Advances and perspectives on photochemical/electrochemical synthesis of nitrogen, sulfur, and phosphorus heteroatom containing compounds from biomass-based feedstocks DOI

Hanjing Tian,

Anping Wang, Pan Hu

и другие.

Industrial Crops and Products, Год журнала: 2024, Номер 222, С. 119738 - 119738

Опубликована: Сен. 27, 2024

Язык: Английский

Процитировано

4
p-Diarylboryl Halothiophenols as Multifunctional Catalysts via Photoactive Intramolecular Frustrated Lewis Pairs DOI

Takeru Kikura,

Y. B. Taura,

Yoshitaka Aramaki

и другие.

Journal of the American Chemical Society, Год журнала: 2024, Номер 146(29), С. 20425 - 20431

Опубликована: Июль 8, 2024

p-Diarylboryl halothiophenols are developed and unequivocally characterized. Their photophysical properties catalytic performance unveiled by experimental theoretical investigations. This novel class of triarylboranes behaves as a Brønsted acid to generate the corresponding borylthiophenolate that can absorb visible light undergo intramolecular charge transfer form radical pair consisting boron anion thiyl radical, which acts single-electron reductant while engaging in hydrogen atom regenerate parent borylthiophenol. The synthetic relevance this mode action is demonstrated establishment unique catalysis integrates three different yet tunable functions single cycle, thereby allowing borylthiophenols solely promote assembly sterically congested 1,2-diols 1,2-aminoalcohol derivatives via radical–radical cross-coupling.

Язык: Английский

Процитировано

3
Perylene-Diimide-Based Supramolecular Radical Anion as a Platform for Highly Effective Photoreduction of Inert Sulfoxide to Sulfide DOI

Kai‐Kai Niu,

Yu‐Song Bi,

Hui Liu

и другие.

Organic Letters, Год журнала: 2024, Номер 26(37), С. 7987 - 7992

Опубликована: Сен. 10, 2024

Due to the limitations of common photoredox catalysts, unlocking their applications in photoreduction reactions remains an ongoing challenge. We herein present a supramolecular radical anion, PDI(CB[7])

Язык: Английский

Процитировано

3
A Catalyst- and Thiol-Free Protocol for Arene C–H Thioetherification via Photoactive Electron Donor–Acceptor Complexes DOI
Ang Gao,

Hongqiong Liu,

Yanan Zhou

и другие.

Green Chemistry, Год журнала: 2025, Номер 27(8), С. 2286 - 2292

Опубликована: Янв. 1, 2025

We present a catalyst- and thiol-free protocol for arene C–H thioetherification under visible light irradiation.

Язык: Английский

Процитировано

0
Odorless Synthesis of Thioglycosides Using Isothiouronium Salts DOI
Li Tang, Jie Zhang,

Tianyun Guo

и другие.

Carbohydrate Research, Год журнала: 2025, Номер unknown, С. 109408 - 109408

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

0
Semiconductor clusters enable high-efficiency extraction of hot electrons from gold nanorods for photocatalytic organic conversions DOI
Jiaxing Liu,

Hao Ma,

Shang‐Fu Yuan

и другие.

Science China Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Фев. 6, 2025

Язык: Английский

Процитировано

0