Nickel-catalyzed cross-electrophile couplings of aryl fluorosulfates with vinyl chlorosilanes
Jin-He Na,
Hong-Jian Du,
Jia-Wen Jing
и другие.
Journal of Catalysis,
Год журнала:
2024,
Номер
437, С. 115636 - 115636
Опубликована: Июль 6, 2024
Язык: Английский
Influence of the Counterion on the Activation of Nickel(σ-Aryl) Precatalysts
Organometallics,
Год журнала:
2025,
Номер
unknown
Опубликована: Фев. 2, 2025
Язык: Английский
Nickel-Catalyzed Reductive Amidation of Aryl Fluorosulfates with Isocyanates: Synthesis of Amides via C–O Bond Cleavage
The Journal of Organic Chemistry,
Год журнала:
2024,
Номер
unknown
Опубликована: Авг. 30, 2024
With
the
assistance
of
nickel
as
catalyst,
2,2'-bipyridine
(bpy)
ligand,
and
manganese
reducing
metal,
reductive
amidation
isocyanates
with
readily
accessible
aryl
fluorosulfates
could
be
successfully
accomplished.
The
reactions
proceeded
effectively
via
C-O
bond
activation
in
DMF
at
room
temperature,
enabling
facile
synthesis
a
range
structurally
diverse
amides
moderate
to
high
yields
broad
functionality
compatibility.
In
addition,
synthetic
usefulness
method
was
further
demonstrated
by
applying
reaction
scale-up
late-stage
functionalization
complex
molecules
biological
activities.
Язык: Английский
The First Decade of SuFEx Chemistry: Advancements in SuFEx Polymerization, Non-Canonical SuFEx Reactions, and SuFEx Radiochemistry
Synthesis,
Год журнала:
2024,
Номер
unknown
Опубликована: Окт. 7, 2024
Abstract
This
year
marks
the
10th
anniversary
of
SuFEx
chemistry,
a
field
that
has
witnessed
significant
advancements
over
past
decade.
These
include
efficient
synthetic
strategies
toward
polymerization
via
approach
leading
to
diverse
polymers,
alongside
discovery
new
SuFExable
hubs
and
coupling
conditions.
Non-canonical
reactions,
such
as
deoxyfluorination
on-water
have
also
emerged.
Furthermore,
there
been
substantial
strides
in
radiosynthesis
[18F]
hubs.
review
provides
an
overview
these
developments,
focusing
on
polymerization,
non-canonical
reaction,
radiochemistry
chemistry.
1
Introduction
2
Polymerization
3
Non-Canonical
Reactions
4
Fluorine-18
Radiochemistry
5
Conclusions
Outlook
Язык: Английский
Application of Sulfonyl Fluorides in Organic Transformation
Synthesis,
Год журнала:
2024,
Номер
unknown
Опубликована: Окт. 21, 2024
Abstract
Sulfonyl
fluorides,
due
to
their
balanced
potential
reactivity
and
stability
as
well
compatibility
with
biological
systems,
have
become
important
synthetic
intermediates
building
blocks
in
the
fields
of
organic
synthesis,
drug
discovery,
materials
science.
Especially
after
report
sulfur(VI)
fluoride
exchange
(SuFEx)
chemistry
by
Sharpless
others,
research
on
sulfonyl
compounds
related
has
increased
significantly.
This
review
summarizes
application
fluorides
synthesis
period
2014–2024,
discussing
different
types
reactions,
including
C–X
bond
formation
(including
C–C,
C–N,
C–F
etc.),
S–C
formation,
S–N
S–O
multicomponent
‘one-pot’
cyclization.
1
Introduction
2
Fluorides
Applied
(C,
N,
F)
Bond
Formation
3
4
5
6
Multicomponent
Reactions
7
Cyclizations
8
Conclusion
Perspective
Язык: Английский