Nickel-catalyzed cross-electrophile couplings of aryl fluorosulfates with vinyl chlorosilanes
Jin-He Na,
No information about this author
Hong-Jian Du,
No information about this author
Jia-Wen Jing
No information about this author
et al.
Journal of Catalysis,
Journal Year:
2024,
Volume and Issue:
437, P. 115636 - 115636
Published: July 6, 2024
Language: Английский
Influence of the Counterion on the Activation of Nickel(σ-Aryl) Precatalysts
Ivo H. Lindenmaier,
No information about this author
Anna S. Harzer,
No information about this author
Markus Ströbele
No information about this author
et al.
Organometallics,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 2, 2025
Language: Английский
Nickel-Catalyzed Reductive Amidation of Aryl Fluorosulfates with Isocyanates: Synthesis of Amides via C–O Bond Cleavage
Gan‐Qi Qin,
No information about this author
Jiao Wang,
No information about this author
Xu-Rong Cao
No information about this author
et al.
The Journal of Organic Chemistry,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Aug. 30, 2024
With
the
assistance
of
nickel
as
catalyst,
2,2'-bipyridine
(bpy)
ligand,
and
manganese
reducing
metal,
reductive
amidation
isocyanates
with
readily
accessible
aryl
fluorosulfates
could
be
successfully
accomplished.
The
reactions
proceeded
effectively
via
C-O
bond
activation
in
DMF
at
room
temperature,
enabling
facile
synthesis
a
range
structurally
diverse
amides
moderate
to
high
yields
broad
functionality
compatibility.
In
addition,
synthetic
usefulness
method
was
further
demonstrated
by
applying
reaction
scale-up
late-stage
functionalization
complex
molecules
biological
activities.
Language: Английский
The First Decade of SuFEx Chemistry: Advancements in SuFEx Polymerization, Non-Canonical SuFEx Reactions, and SuFEx Radiochemistry
Synthesis,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 7, 2024
Abstract
This
year
marks
the
10th
anniversary
of
SuFEx
chemistry,
a
field
that
has
witnessed
significant
advancements
over
past
decade.
These
include
efficient
synthetic
strategies
toward
polymerization
via
approach
leading
to
diverse
polymers,
alongside
discovery
new
SuFExable
hubs
and
coupling
conditions.
Non-canonical
reactions,
such
as
deoxyfluorination
on-water
have
also
emerged.
Furthermore,
there
been
substantial
strides
in
radiosynthesis
[18F]
hubs.
review
provides
an
overview
these
developments,
focusing
on
polymerization,
non-canonical
reaction,
radiochemistry
chemistry.
1
Introduction
2
Polymerization
3
Non-Canonical
Reactions
4
Fluorine-18
Radiochemistry
5
Conclusions
Outlook
Language: Английский
Application of Sulfonyl Fluorides in Organic Transformation
Sichang Wang,
No information about this author
Chengxiang Zhou,
No information about this author
Yifeng Han
No information about this author
et al.
Synthesis,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 21, 2024
Abstract
Sulfonyl
fluorides,
due
to
their
balanced
potential
reactivity
and
stability
as
well
compatibility
with
biological
systems,
have
become
important
synthetic
intermediates
building
blocks
in
the
fields
of
organic
synthesis,
drug
discovery,
materials
science.
Especially
after
report
sulfur(VI)
fluoride
exchange
(SuFEx)
chemistry
by
Sharpless
others,
research
on
sulfonyl
compounds
related
has
increased
significantly.
This
review
summarizes
application
fluorides
synthesis
period
2014–2024,
discussing
different
types
reactions,
including
C–X
bond
formation
(including
C–C,
C–N,
C–F
etc.),
S–C
formation,
S–N
S–O
multicomponent
‘one-pot’
cyclization.
1
Introduction
2
Fluorides
Applied
(C,
N,
F)
Bond
Formation
3
4
5
6
Multicomponent
Reactions
7
Cyclizations
8
Conclusion
Perspective
Language: Английский