Modular 1,2‐Selective Carboarylation of Conjugated Dienes under Cobalt Catalysis

ChemCatChem, Год журнала: 2024, Номер 16(22)

Опубликована: Авг. 12, 2024

Abstract A highly 1,2‐regioselective cobalt‐catalyzed alkylarylation of conjugated dienes in a stereoretentive fashion has been disclosed. Indeed, the anion‐coordination played critical role for tuning reactivity arylzinc pivalates, thereby efficiently steering three‐component coupling reaction via radical relay pathway. Moreover, this protocol also distinguished by its mild conditions, ample substrate scope and good functional group compatibility.

Язык: Английский

Ortho-allylation of anilines with vinylaziridines in hexafluoroisopropanol

Organic Chemistry Frontiers, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 14, 2024

Reaction of N , -dialkylanilines with 2-vinylaziridines in hexafluoroisopropanol affords 2-monoallylated anilines ( E )-configured C–C double bonds.

Язык: Английский