Bioactive Materials,
Год журнала:
2023,
Номер
29, С. 50 - 71
Опубликована: Июнь 29, 2023
Cytoskeleton
plays
a
significant
role
in
the
shape
change,
migration,
movement,
adhesion,
cytokinesis,
and
phagocytosis
of
tumor
cells.
In
clinical
practice,
some
anti-cancer
drugs
achieve
cytoskeletal
therapeutic
effects
by
acting
on
different
protein
components.
However,
absence
cell-specific
targeting,
unnecessary
recombination
organisms
would
be
disastrous,
which
also
bring
about
severe
side
during
anticancer
process.
Nanomedicine
have
been
proven
to
superior
small
molecule
cancer
treatment
due
better
stability
lower
effects.
Therefore,
this
review
summarized
recent
developments
various
nanomaterials
disturbing
cytoskeleton
for
enhanced
therapeutics,
including
carbon,
noble
metals,
metal
oxides,
black
phosphorus,
calcium,
silicon,
polymers,
peptides,
metal-organic
frameworks,
etc.
A
comprehensive
analysis
characteristics
therapy
as
well
future
prospects
challenges
towards
application
were
discussed.
We
aim
drive
emerging
topic
through
refreshing
perspectives
based
our
own
work
what
we
learnt
from
others.
This
will
help
researchers
quickly
understand
relevant
information
further
advance
development
nanomedicine.
Chemical Science,
Год журнала:
2021,
Номер
13(3), С. 633 - 656
Опубликована: Ноя. 9, 2021
This
review
shows
how
chirality
may
be
used
for
the
design,
construction
and
evolution
of
higher
ordered
complex
chiral
nanostructures
through
hierarchical
self-assembly.
Advanced Materials,
Год журнала:
2021,
Номер
33(38)
Опубликована: Июль 26, 2021
Abstract
Chiral
plasmonic
nanomaterials
have
attracted
unprecedented
attention
due
to
their
broad
applications
in
biomedicine,
negative
refractive
index,
and
chiral
sensing.
Here,
using
a
wet‐chemistry
process,
triangular
Au
nanorings
are
fabricated
with
platinum
(Pt)
framework
(
l
/
d
‐Pt@Au
nanorings,
named
TNRs).
The
TNRs
exhibit
strong
optical
activity
g
‐factor
of
0.023
can
be
used
effectively
for
the
discrimination
enantiomers
selective
resonance
coupling
between
induced
electric
magnetic
dipoles
associated
TNRs,
also
known
as
surface‐enhanced
Raman
scattering‐chiral
anisotropy
(SERS‐ChA)
effect.
represent
label‐free
SERS
platform
that
applied
detect
Aβ
monomers
fibrils,
hallmarks
Alzheimer's
disease
(AD),
achieving
limit
detection
(LOD)
down
0.045
×
10
−12
m
4
−15
42‐residue‐long
amyloid‐β
(Aβ
42
)
monomer
respectively.
Furthermore,
successfully
carried
out
proteins
AD
patients
ultrahigh
levels
sensitivity,
thus
allowing
picogram
quantities
identified.
This
research
opens
up
an
avenue
use
ultrasensitive
substrates
early
diagnosis
protein‐misfolding
diseases.
ACS Applied Materials & Interfaces,
Год журнала:
2022,
Номер
15(21), С. 25248 - 25274
Опубликована: Июнь 17, 2022
The
creation
of
matter
with
varying
degrees
complexities
and
desired
functions
is
one
the
ultimate
targets
self-assembly.
ability
to
regulate
complex
interactions
between
individual
components
essential
in
achieving
this
target.
In
direction,
initial
success
controlling
pathways
final
thermodynamic
states
a
self-assembly
process
promising.
Despite
progress
made
field,
there
has
been
growing
interest
pushing
limits
processes.
main
inception
that
intended
self-assembled
state,
complexities,
may
not
be
"at
equilibrium
(or
at
global
minimum)",
rendering
free
energy
minimization
unsuitable
form
product.
Thus,
we
believe
thorough
understanding
design
principles
as
well
predict
outcome
collection
next
generation
matter.
present
review
highlights
potent
role
finely
tuned
interparticle
nanomaterials
achieve
preferred
structures
properties.
We
bringing
prediction
nanoparticle
processes
will
have
similar
effect
retrosynthesis
had
on
logic
chemical
synthesis.
Along
guiding
principles,
gives
summary
different
types
products
created
from
assemblies
functional
properties
emerging
them.
Finally,
highlight
reasonable
expectations
field
challenges
lying
ahead
evolvable
Advanced Materials,
Год журнала:
2023,
Номер
35(49)
Опубликована: Март 19, 2023
Abstract
Circularly
polarized
light
(CPL)
with
the
end
of
optical
vector
traveling
along
circumferential
trajectory
shows
left‐
and
right‐handedness,
which
transmits
chiral
information
to
materials
via
complicated
CPL–matter
interactions.
Materials
circular
dichroism
respond
CPL
illumination
selectively
differential
outputs
that
can
be
used
design
novel
photodetectors.
Racemic
or
achiral
compounds
under
go
through
photodestruction,
photoresolution,
asymmetric
synthesis
pathways
generate
enantiomeric
bias
activity.
By
this
strategy,
helical
polymers
inorganic
plasmonic
nanostructures
are
synthesized
directly,
their
intramolecular
folding
subsequent
self‐assembly
photomodulable
as
well.
In
aggregated
state
liquid
crystal
phase,
sense
dynamic
molecular
packing
is
sensitive
brought
by
CPL,
enabling
amplification
supramolecular
scale.
review,
application‐guided
strategies
CPL‐responsive
aimed
systematically
summarized
discussed.
Asymmetric
synthesis,
resolution,
property‐modulation
small
organic
compounds,
polymers,
nanoparticles,
assemblies
crystals
highlighted
based
on
important
developments
during
last
decades.
Besides,
applications
light–matter
interactions
including
detection
biomedical
also
referred.
Nano-Micro Letters,
Год журнала:
2023,
Номер
15(1)
Опубликована: Янв. 18, 2023
Abstract
For
decades,
chiral
nanomaterials
have
been
extensively
studied
because
of
their
extraordinary
properties.
Chiral
nanostructures
attracted
a
lot
interest
potential
applications
including
biosensing,
asymmetric
catalysis,
optical
devices,
and
negative
index
materials.
Circularly
polarized
light
(CPL)
is
the
most
attractive
source
for
chirality
owing
to
its
high
availability,
now
it
has
used
as
preparation
matter.
In
this
review,
recent
progress
in
field
CPL-enabled
summarized.
Firstly,
advancements
fabrication
materials
using
circularly
are
described,
focusing
on
unique
strategies.
Secondly,
an
overview
driven
by
CPL
provided,
with
particular
emphasis
phototherapy.
Finally,
perspective
challenges
given.
Advanced Materials,
Год журнала:
2024,
Номер
36(15)
Опубликована: Янв. 17, 2024
Hybrid
metal
halides
(HMHs)
with
efficient
circularly
polarized
luminescence
(CPL)
have
application
prospects
in
many
fields,
due
to
their
abundant
host-guest
structures
and
high
photoluminescence
quantum
yield
(PLQY).
However,
CPLs
HMHs
are
predominantly
excited
by
light
or
electricity,
limiting
use
multivariate
environments.
It
is
necessary
explore
a
novel
excitation
method
extend
the
of
chiral
as
smart
stimuli-responsive
optical
materials.
In
this
work,
an
enantiomeric
pair
0D
hybrid
manganese
bromides,
[H
