Dry Bondable Porous Silk Fibroin Films for Embedding Micropatterned Electronics in Hierarchical Silk Nacre DOI Open Access

Jiajin Xue,

Duote Cai, Xiaojing Zhang

и другие.

Small, Год журнала: 2024, Номер unknown

Опубликована: Дек. 15, 2024

Future structural materials is not only be lightweight, strong, and tough, but also capable of integrating functions like sensing, adaptation, self-healing, deformation, recovery as needed. Although bio-inspired are well developed, directly microelectronic patterns into nacre-mimetic structures remains challenging, limiting the widespread application electronic biomimetic materials. Here, an in situ freeze-drying method reported for successful preparation porous silk fibroin that can achieve dry bonding. The preserves integrity lyophilized membrane while reducing procedural steps, achieving control over pore gradient feasible with traditional techniques. By leveraging their smooth surfaces capacity to support heat transfer patterns, layer-by-layer assembly at a macroscopic scale achieved. material's excellent mechanical properties, controllable graded structure, adjustable degradation behavior enable construction electronically functionalized hierarchical structures. Additionally, dry-state, bonding polymer films provides advantages precision control, stability, functional versatility, structuring, scalability. It represents innovative approach, offering multi-functional customizable bulk materials, especially suited biomedical applications. This work offers effective pathway developing high-performance multifunctional devices

Язык: Английский

Operando X‐Ray Tomoscopy of Laser Beam Welding DOI Creative Commons
Paul H. Kamm, Stephan Börner, Tillmann Robert Neu

и другие.

Advanced Science, Год журнала: 2025, Номер unknown

Опубликована: Янв. 13, 2025

Abstract The phenomena occurring in a weld seam during advancement of laser beam over metallic component are still under dispute. occurrence and evolution porosity the occasional blowout melt need to be understood. Here, recently developed X‐ray tomoscopy setup is applied, providing one hundred 3D images per second capture temporal pool an AlSi9Cu3(Fe) die‐casting while advances. number pores, their size, shape distribution quantified with 10 ms time resolution reflect complex dynamic pattern. Apart from conventional welding, variant involving modulation superimposed onto linear motion studied. Reductions surface roughness observed explained by increased pore mobility stepwise degassing as repeatedly cuts through pores. keyhole formed integrated represented 3D.

Язык: Английский

Процитировано

2

Tough and Fast Thermoresponsive Hydrogel Soft Actuators DOI Creative Commons
Xi Zhang, Shazed Aziz, Zhonghua Zhu

и другие.

Advanced Materials Technologies, Год журнала: 2025, Номер unknown

Опубликована: Янв. 29, 2025

Abstract Thermoresponsive hydrogels hold significant potential for soft actuators due to their ability undergo reversible shape deformation in response temperature changes. However, the mechanical brittleness along with slow actuation responsiveness of such limit usage high‐stress environments. Herein, design and fabrication tough fast‐responding thermoresponsive double‐network (DN) hydrogels, specifically developed use actuators, are introduced. Using a one‐pot free‐radical polymerization method, DN composed poly(N‐isopropylacrylamide) (PNIPAm) first network an ether‐based polyurethane (EPU) second network, providing both strength fast variation synthesized. The fabricated exhibit excellent properties, ultimate compressive stress ≈8 MPa, demonstrate rapid actuation, achieving ≈30% linear contraction ≈28% radial within 2 min under hydrothermal conditions at 50 °C. Furthermore, tubular from these act as fluidic sensors, automatically switching fluid flow direction change. These combine toughness, sensing, offering substantial advancements robotics adaptive systems.

Язык: Английский

Процитировано

2

Moisture Harvesting by the Structure Regulation of Hygroscopic Hydrogel for Energy and Water Sustainability DOI Creative Commons
Yujie Du,

Yongliang Zheng,

Hong Liu

и другие.

Advanced Electronic Materials, Год журнала: 2025, Номер unknown

Опубликована: Фев. 9, 2025

Abstract Water and energy are the cornerstones of human development, with more than half world's population facing water scarcity issues. Atmospheric moisture is widely distributed around globe, rational utilization can create tremendous value. Here, sources hygroscopic materials, methods manufacturing hydrogels, properties these potential applications concluded. To make hydrogels high hydrophilicity, ultrasonic oscillation, freeze drying, spin coating be used as synthesis strategies. The main focus on characteristic parameters uptake, dehydration temperature, conductivity, mechanical stability, swelling behaviors, heat transfer coefficient. These unique features will affect performances assembles, devices, instruments. Subsequently, summarized, such harvesting splitting fuel production, dehumidification, thermal management in electronic solar evaporation, electricity production. Finally, future directions issues interest proposed to promote diverse development relational systems.

Язык: Английский

Процитировано

1

Nanofibrous Hydrogel with Highly Salt‐Resistant Radial/Vertical‐Combined Structure for Efficient Solar Interfacial Evaporation DOI Open Access

Yong Wen,

Shengwu Deng,

Quanpei Xie

и другие.

Small, Год журнала: 2025, Номер unknown

Опубликована: Март 13, 2025

Abstract Hydrogel‐based solar interfacial evaporators, featuring various channels such as random, unidirectional, and radial array, are considered effective for seawater desalination owing to their porous structure, lower evaporation enthalpy, controllable water transport capacity. However, each individual array structure has its own strengths limitations, influencing transportation, thermal management, salt rejection. By combining the benefits of configuration into a single evaporator, performance can be maximized. Herein, study develops unique nanofibrous hydrogel‐based evaporator combined radical/vertical structure. This integrated with external internal vertical endows this excellent capability reduced heat loss, resulting in superior high salty resistance. The addition nanofibers hydrogels not only enhances hydrogel's stability but also facilitates transport. Under 1 sun illumination, achieve an impressive rate 4.62 kg m −2 h −1 energy efficiency 149.57%. After 12 20 wt.% NaCl solution, it still maintains average 3.98 minimal accumulation, thereby exhibiting exceptional resistance durability.

Язык: Английский

Процитировано

1

Marine Amoebae‐Inspired Salting Hydrogels to Reconfigure Anisotropy for Reprogrammable Shape Morphing DOI

Guorong Gao,

Kaiyang Yin,

Junyi Han

и другие.

Angewandte Chemie International Edition, Год журнала: 2024, Номер unknown

Опубликована: Окт. 11, 2024

Abstract Reprogrammable shape morphing is ubiquitous in living beings and highly crucial for them to move normal situations, even survive under dangerous conditions. There increasing interest using asymmetric hydrogel structures understand mimic beings’ upon an external trigger a controlled way. However, these or heterogeneous configurations cannot be further modified once the polymer hydrogels are prepared. Therefore, it great challenge achieve reprogrammable existing hydrogels. Inspired by marine amoebae, which transform into several different morphologies according various salt concentrations, new strategy developed salting reconfigure their anisotropy toward morphing. Polyampholyte with equal stoichiometric COO − N + (CH 3 ) groups were first swollen HCl/NaCl solution. After being then transferred water, they again water uptake driven osmotic pressure, spontaneously deswollen due increase internal pH dialysis of ions leading deprotonation COOH regeneration /N electrostatic attraction. This work provides novel soft actuators open up avenue

Язык: Английский

Процитировано

5

Bioinspired Nanochitin‐Based Porous Constructs for Light‐Driven Whole‐Cell Biotransformations DOI Open Access
Vishnu Arumughan, Hitesh Medipally, Arun Torris

и другие.

Advanced Materials, Год журнала: 2025, Номер unknown

Опубликована: Фев. 3, 2025

Abstract Solid‐state photosynthetic cell factories (SSPCFs) are a new production concept that leverages the innate abilities of microbes to drive valuable chemicals. It addresses practical challenges such as high energy and water demand improper light distribution associated with suspension‐based culturing; however, these systems often face significant related mass transfer. The approach focuses on overcoming limitations by carefully engineering microstructure immobilization matrix through freeze‐induced assembly nanochitin building blocks. use nanochitins optimized size enabled formation macropores lamellar spatial organization, which significantly improves transmittance distribution, crucial for maximizing efficiency reactions. biomimetic crosslinking strategy, leveraging specific interactions between polyphosphate anions primary amine groups featured chitin fibers, produced mechanically robust wet‐resilient cryogels maintained their functionality under operational conditions. Various model biotransformation reactions leading value‐added chemicals performed in chitin‐based matrix. demonstrates superior or comparable performance existing state‐of‐the‐art matrices systems. findings suggest cryogel holds promise advancing development solid‐state factories, offering scalable solution improve productivity light‐driven biotransformation.

Язык: Английский

Процитировано

0

Effect of pore architecture on quasistatic compressive deformation of freeze-cast porous alumina scaffolds DOI
Satyanarayana Sabat, Soumavo Sikder, Shantanu K. Behera

и другие.

Journal of the European Ceramic Society, Год журнала: 2025, Номер unknown, С. 117263 - 117263

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

0

ONE-STEP ROOM TEMPERATURE FABRICATION OF FREEZE-CAST 58S BIOACTIVE GLASS / POLYVINYL ALCOHOL COMPOSITE SCAFFOLDS FOR BONE TISSUE ENGINEERING DOI
Diogo M.M. dos Santos,

G.L. Oliveira,

Daniel Crístian Ferreira Soares

и другие.

Ceramics International, Год журнала: 2025, Номер unknown

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

0

Microneedles with an anisotropic porous microstructure facilitate the transdermal delivery of small molecules, lipid nanoparticles, and T cells DOI Creative Commons
Tianli Hu, Ka Sin Lui,

E.I. Ko

и другие.

Matter, Год журнала: 2025, Номер unknown, С. 102038 - 102038

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0

Biomass Nanofiber‐Assembled Superhydrophobic Aerogels with Simultaneously Enhanced Mechanical Strength and Shape Recovery DOI Creative Commons
Xinyu Dong, Quyang Liu, Hao Zhuo

и другие.

Small Structures, Год журнала: 2025, Номер unknown

Опубликована: Март 17, 2025

Oil spills and water pollution present significant environmental challenges, calling for the development of sustainable efficient material solutions. In this study, aerogels are prepared from chitosan sodium alginate, two renewable natural polysaccharides, through ultrasonication‐assisted nanofiber assembly combined with freeze casting. This approach leverages inherent electrostatic interactions between polysaccharides to assemble nanofibers, which then aggregated into an anisotropic honeycomb‐like cellular microstructure during The addition methyltrimethoxysilane further consolidates network, resulting in CSNF‐Si a superlow density 0.0198 g cm −3 , yet high mechanical strength (105.7 kPa at 80% strain) shape recovery (95% after deformation). addition, exhibit superhydrophobicity contact angle 151° rolling 4.3°, enabling effective oil absorption capacities reaching up 90 times their own weight. They also demonstrate excellent reusability over multiple absorption‐release cycles, thanks enhanced ability. Furthermore, study presents hierarchical fabrication strategy that synergistically integrates molecular, nano‐, microscale designs reinforce functionalize engineering

Язык: Английский

Процитировано

0