ACS Sustainable Chemistry & Engineering,
Год журнала:
2017,
Номер
5(3), С. 2562 - 2577
Опубликована: Янв. 10, 2017
In
this
study,
BiVO4
was
prepared
by
a
hydrothermal
synthesis
route
in
the
presence
of
sodium
dodecyl
sulfate
using
aqueous
NH3
as
precipitant.
g-C3N4
combustion
method
melamine.
order
to
develop
highly
efficient
photocatalyst,
heterojunction
catalyst
based
on
and
prepared.
Different
amounts
were
mixed
annealed
obtain
photocatalysts.
FeVO4
LaVO4
also
for
comparative
catalytic
investigation.
Catalysts
characterized
series
complementary
combinations
powder
X-ray
diffraction,
thermogravimetric
analysis,
elemental
N2
adsorption–desorption,
scanning
electron
microscopy,
transmission
temperature-programmed
desorption
CO2,
diffuse
reflectance
ultraviolet
visible
spectroscopy,
photoelectron
photoluminescence
photoelectrochemical
studies.
investigated
light
driven
oxidation
benzyl
alcohol,
amine,
aniline
with
O2.
propose
electrons,
holes,
radicals
mediated
reaction
pathways,
reactions
performed
an
electron/hole/radical
scavenger.
Further,
confirm
various
products
formed
during
photocatalytic
aniline,
several
model
carried
out.
Based
results
obtained,
mechanism
structure–activity
relationship
established.
Chemical Communications,
Год журнала:
2018,
Номер
54(50), С. 6591 - 6606
Опубликована: Янв. 1, 2018
The
necessity
of
sustainable
development
in
the
chemical
industry
has
continuously
drawn
attention
to
find
safe,
environmentally
friendly
and
atom-economic
processes,
which
is
defined
12
principles
green
chemistry.
Merging
photoredox
catalysis
reversible
addition-fragmentation
chain
transfer
(RAFT)
polymerisation,
photoinduced
electron/energy
(PET)-RAFT
process
opened
up
a
new
way
performing
deactivation
radical
polymerisation
for
well-defined
polymer
synthesis
using
light
as
an
external
stimulus.
While
providing
increased
level
control
(spatiotemporal,
wavelength,
intensity
control)
over
PET-RAFT
many
attractive
attributes
(abundant
catalyst
availability,
recyclability,
selectivity
oxygen
tolerance)
be
sustainable,
intriguing
precision
manufacturing
industry.
Journal of the American Chemical Society,
Год журнала:
2016,
Номер
138(48), С. 15535 - 15538
Опубликована: Ноя. 22, 2016
Photoinitiated
cationic
polymerizations
are
widely
used
in
industrial
processes;
however,
gaining
photocontrol
over
chain
growth
would
expand
the
utility
of
these
methods
and
facilitate
design
novel
complex
architectures.
We
report
herein
a
polymerization
regulated
by
visible
light.
This
proceeds
under
mild
conditions:
combination
metal-free
photocatalyst,
chain-transfer
agent,
light
irradiation
enables
synthesis
various
poly(vinyl
ether)s
with
good
control
molecular
weight
dispersity
as
well
excellent
chain-end
fidelity.
Significantly,
photoreversible
cation
formation
this
system
efficient
polymer
Journal of the American Chemical Society,
Год журнала:
2017,
Номер
139(31), С. 10665 - 10668
Опубликована: Июль 26, 2017
The
ability
to
combine
two
polymerization
mechanisms
in
a
one-pot
setup
and
switch
the
monomer
selectivity
via
an
external
stimulus
provides
excellent
opportunity
control
polymer
sequence
structure.
We
report
strategy
that
enables
incorporation
be
determined
selection
of
wavelength
light
through
selective
activation
either
cationic
or
radical
processes.
This
method
synthesis
varying
polymeric
structures
under
identical
solution
conditions
but
with
simple
modulation
stimulus.
Additionally,
changes
ratios
photocatalysts
afford
complementary
chemical
over
these
reactions
design
elaborated
structures.
Our
takes
advantage
unique
regulation
can
accessed
light.
ACS Sustainable Chemistry & Engineering,
Год журнала:
2017,
Номер
5(3), С. 2562 - 2577
Опубликована: Янв. 10, 2017
In
this
study,
BiVO4
was
prepared
by
a
hydrothermal
synthesis
route
in
the
presence
of
sodium
dodecyl
sulfate
using
aqueous
NH3
as
precipitant.
g-C3N4
combustion
method
melamine.
order
to
develop
highly
efficient
photocatalyst,
heterojunction
catalyst
based
on
and
prepared.
Different
amounts
were
mixed
annealed
obtain
photocatalysts.
FeVO4
LaVO4
also
for
comparative
catalytic
investigation.
Catalysts
characterized
series
complementary
combinations
powder
X-ray
diffraction,
thermogravimetric
analysis,
elemental
N2
adsorption–desorption,
scanning
electron
microscopy,
transmission
temperature-programmed
desorption
CO2,
diffuse
reflectance
ultraviolet
visible
spectroscopy,
photoelectron
photoluminescence
photoelectrochemical
studies.
investigated
light
driven
oxidation
benzyl
alcohol,
amine,
aniline
with
O2.
propose
electrons,
holes,
radicals
mediated
reaction
pathways,
reactions
performed
an
electron/hole/radical
scavenger.
Further,
confirm
various
products
formed
during
photocatalytic
aniline,
several
model
carried
out.
Based
results
obtained,
mechanism
structure–activity
relationship
established.
