Defence Technology,
Год журнала:
2023,
Номер
35, С. 18 - 46
Опубликована: Сен. 11, 2023
From
the
standpoint
of
chemical
structures,
organic
backbones
energetic
materials
can
be
classified
into
aromatic
rings,
nonaromatic
and
open
chains.
Although
category
compounds
exhibits
several
advantages
in
regulation
properties,
heterocycles,
assembling
nitramino
explosophores
with
simple
alkyl
bridges,
still
have
prevailed
benchmark
materials.
The
methylene
bridge
plays
a
pivotal
role
constructions
classic
heterocycle-based
compounds,
e.g.,
hexahydro-1,3,5-trinitro-1,3,5-triazine
(RDX)
octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine
(HMX),
whereas
ethylene
is
core
moiety
state-of-the-art
explosive
2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane
(CL-20).
In
this
context,
it
great
interest
to
employ
practical
bridges
assemble
nitrogen-rich
thereby
expanding
structural
diversity
materials,
bridged
fused
poly-heterocycles.
Furthermore,
alkyl-bridged
poly-heterocycles
highlight
potential
for
chain
type
review,
development
linking
heterocycles
presented,
perspective
newly
constructed
summarized
future
design
advanced
Journal of Materials Chemistry A,
Год журнала:
2019,
Номер
7(33), С. 19248 - 19257
Опубликована: Янв. 1, 2019
A
versatile
host–guest
driven
explosive-oxidant
inclusion
strategy
was
proposed
to
develop
advanced
high-energy-density
materials
(HEDMs)
with
high
detonation
performances,
low
mechanical
sensitivities
and
excellent
combustion
properties.
Journal of Materials Chemistry A,
Год журнала:
2022,
Номер
10(23), С. 12702 - 12712
Опубликована: Янв. 1, 2022
A
series
of
new
pyrimidine-based
nitrogen-rich
green
energetic
materials
were
effectively
synthesized
from
commercially
available
inexpensive
starting
materials,
with
short
reaction
times,
easy
isolation,
and
essentially
quantitative
yields.
Organic Letters,
Год журнала:
2020,
Номер
22(4), С. 1321 - 1325
Опубликована: Янв. 30, 2020
Using
the
triazine
ring
as
stabilizing
factor,
a
series
of
energy-safety
balanced
fused
compounds
were
successfully
studied.
Compounds
1,
7,
and
9·H2O
further
confirmed
by
single-crystal
X-ray
diffraction
analysis.
The
detonation
performance
safety
parameters
associated
with
impact
friction
sensitivities
investigated
using
EXPLO5
(version
6.01)
BAM
methods,
respectively.
Based
on
their
good
properties
high
thermal
mechanical
stabilities,
these
materials
are
potentially
insensitive
explosives.
Journal of Materials Chemistry A,
Год журнала:
2023,
Номер
11(26), С. 13876 - 13888
Опубликована: Янв. 1, 2023
Hydrogen
transfer
from
nitroamino
to
nitroimino
promotes
density,
energy
and
safety
of
energetic
materials
suggesting
excellent
application
prospects
in
designing
next
generation
high
density
materials.
Crystal Growth & Design,
Год журнала:
2023,
Номер
23(5), С. 3463 - 3470
Опубликована: Апрель 21, 2023
In
recent
years,
the
safety
of
energetic
materials
has
attracted
more
and
attention.
How
to
design
synthesize
heat-resistant
insensitive
become
an
urgent
problem
be
solved.
this
work,
two
series
salts
based
on
isomeric
triamino
triazolo-triazine
fused-ring
compounds
were
designed
synthesized
by
incorporating
oxygen-rich
anions
(such
as
NO3–
or
ClO4–)
with
nitrogen-rich
cations.
All
new
fully
characterized
infrared
(IR)
spectroscopy,
nuclear
magnetic
resonance
(NMR),
elemental
analysis,
differential
scanning
calorimetry
(DSC).
Decomposition
temperatures
(Td)
perchlorate
3
9
are
315
364
°C,
respectively.
Their
different
properties,
densities
molecular
stabilities
rationally
explained
crystal
structures
packing
patterns.
Meanwhile,
highest
decomposition
temperature
good
detonation
performance
(D
=
8485
m
s–1,
P
27.7
GPa),
which
is
superior
HNS
PYX
suggests
that
it
could
applied
a
explosive.
Materials Chemistry Frontiers,
Год журнала:
2021,
Номер
5(19), С. 7108 - 7118
Опубликована: Янв. 1, 2021
A
systematic
introduction
to
the
developments
in
heterocyclic
high
energy
density
materials
(HEDMs)
with
various
explosive
units
form
of
tricyclic-based
oxadiazole.
