Energetic Materials Frontiers,
Год журнала:
2020,
Номер
1(1), С. 16 - 25
Опубликована: Июнь 1, 2020
In
this
study,
the
synthesis
and
properties
of
6-nitramino-7-nitro-8-aminotetrazolo[1,5-b]pyridazine
(1)
its
alkali
metal
salts
(2–6)
were
presented.
The
hydrolysis
6-nitramino
8-amino
from
1
was
occurred
at
specified
conditions,
which
generated
a
series
6-nitramino-7-nitro-8-hydroxy-tetrazolo[1,5-b]pyridazine
(7,
12)
6-amino-7-nitro-8-hydroxy-tetrazolo
[1,5-b]pyridazine
(8-11).
Their
structures
characterized
by
SXRD,
IR,
EA,
HRMS
NMR,
respectively.
thermal
stability
investigated
using
DTA
TGA
techniques.
On
basis
ΔfH
ρ,
detonation
performances
(vD
p)
calculated
EXPLO5
software.
mechanical
sensitivities
(IS,
FS)
also
measured.
results
show
that
compounds
1–12
display
good
(Td
>
175
°C),
high
energy
level
6700
m
s−1)
low
(IS
≥
18
J)
as
promising
energetic
materials.
Journal of the American Chemical Society,
Год журнала:
2020,
Номер
142(7), С. 3652 - 3657
Опубликована: Янв. 31, 2020
Two
metal-free
explosives,
tetrazolo[1,5-b]pyridazine-containing
molecules
[6-azido-8-nitrotetrazolo[1,5-b]pyridazine-7-amine
(3at)
and
8-nitrotetrazolo[1,5-b]pyridazine-6,7-diamine
(6)],
were
obtained
via
straightforward
two-step
synthetic
routes
from
commercially
available
reagents.
Compound
3at
displays
an
excellent
detonation
performance
(Dv
=
8746
m
s–1
P
31.5
GPa)
that
is
superior
to
commercial
primary
explosives
such
as
lead
azide
diazodinitrophenol
(DDNP).
6
has
thermal
stability,
remarkable
insensitivity,
good
performance,
strongly
suggesting
it
acceptable
secondary
explosive.
The
initiating
ability
of
compound
been
tested
by
detonating
500
mg
RDX
with
a
surprisingly
low
minimum
charge
40
mg.
extraordinary
power
surpasses
conventional
DDNP
(70
mg)
reported
6-nitro-7-azido-pyrazol[3,4-d][1,2,3]triazine-2-oxide
(ICM-103)
(60
mg).
outstanding
contributes
its
future
prospects
promising
green
In
addition,
the
environmentally
benign
methodology
for
synthesis
effectively
shortens
time
laboratory-scale
research
practical
applications.
Chemical Communications,
Год журнала:
2020,
Номер
56(10), С. 1493 - 1496
Опубликована: Янв. 1, 2020
Two
5,6-fused
tetrazolo-pyridazine
compounds
were
synthesized
and
characterized,
which
exhibited
high
thermal
stability,
excellent
energetic
properties
low
mechanical
sensitivity.
Journal of Materials Chemistry A,
Год журнала:
2019,
Номер
7(33), С. 19248 - 19257
Опубликована: Янв. 1, 2019
A
versatile
host–guest
driven
explosive-oxidant
inclusion
strategy
was
proposed
to
develop
advanced
high-energy-density
materials
(HEDMs)
with
high
detonation
performances,
low
mechanical
sensitivities
and
excellent
combustion
properties.
Journal of Materials Chemistry A,
Год журнала:
2024,
Номер
12(17), С. 10050 - 10058
Опубликована: Янв. 1, 2024
A
zwitterionic
fused-ring
based
energetic
material
(ZDPT)
was
prepared.
ZDPT
has
excellent
thermal
stability
(
T
d
=
347
°C
)
and
great
detonation
velocity
D
8390
m
s
−1
),
which
endow
with
potential
as
a
heat-resistant
material.
Journal of Materials Chemistry A,
Год журнала:
2024,
Номер
12(22), С. 13231 - 13239
Опубликована: Янв. 1, 2024
Two
high-performance
heat-resistant
energetic
materials
were
developed
via
a
synergistic
strategy
of
designing
hydrogen
bonding
networks
and
expanding
the
π-conjugation
system.
New Journal of Chemistry,
Год журнала:
2021,
Номер
45(23), С. 10150 - 10159
Опубликована: Янв. 1, 2021
The
evergrowing
demand
for
cleaner,
high-performing
energetic
materials
(EMs)
has
led
to
a
quest
replacement
of
currently
used
toxic
metal-based
traditional
compounds
such
as
lead
azide
and
styphnate.
