Metal-organic
polyhedra
(MOPs)
are
a
subclass
of
coordination
cages
that
can
adsorb
and
host
species
in
solution
permanently
porous
solid-state.
These
characteristics,
together
with
the
recent
development
their
orthogonal
surface
chemistry
assembly
more
stable
cages,
have
awakened
latent
potential
MOPs
to
be
used
as
building
blocks
for
synthesis
extended
networks.
This
review
article
focuses
on
exploring
key
developments
make
extension
possible,
highlighting
most
remarkable
examples
MOP-based
soft
materials
crystalline
frameworks.
Finally,
ventures
offer
future
perspectives
exploitation
fields
still
remain
ripe
toward
use
such
unorthodox
molecular
platforms.
Chemical Society Reviews,
Год журнала:
2022,
Номер
51(8), С. 3181 - 3225
Опубликована: Янв. 1, 2022
This
review
summarizes
recent
advances
and
design
strategies
of
porous
organic
polymers
as
efficient
electrode
materials
for
high-performance
supercapacitors.
ACS Applied Materials & Interfaces,
Год журнала:
2021,
Номер
13(5), С. 6359 - 6366
Опубликована: Фев. 1, 2021
Developing
efficient
adsorbents
for
the
removal
of
water
pollutants
is
great
significance
environmental
protection.
In
this
study,
conjugated
triaryl
triazines
(CTT),
containing
intramolecular
hydrogen-bonding
patterns,
were
recognized
to
be
intriguing
building
blocks
construction
porous
organic
polymer
(POP)
adsorbents.
These
planar
monomers
with
multiple
phenolic
hydroxyl
groups
facilitated
formation
aza-linked
polymers
hierarchical
structures,
sheet-like
morphology,
good
surface
wettability,
and
high
degree
functionality.
Such
structural
characteristics
CTT-POP
provided
superfast
adsorption
various
cationic
dyes
from
water.
For
methylene
blue
dye,
pseudo-second-order
rate
constant
CTT-POP-1
12.9
g
mg–1
min–1,
superior
those
reported
in
existing
literature.
addition,
can
regenerated
at
least
seven
times
no
loss
performance,
indicating
its
potential
application
treatment.
Chemical Society Reviews,
Год журнала:
2021,
Номер
51(1), С. 43 - 56
Опубликована: Дек. 3, 2021
Porous
organic
polymers
(POPs)
are
prepared
by
crosslinked
polymerization
of
multidimensional
rigid
aromatic
building
blocks
followed
PSM
depending
on
the
application.
Angewandte Chemie International Edition,
Год журнала:
2022,
Номер
62(11)
Опубликована: Дек. 20, 2022
Abstract
Water
pollution
is
a
growing
threat
to
humanity
due
the
pervasiveness
of
contaminants
in
water
bodies.
Significant
efforts
have
been
made
separate
these
hazardous
components
purify
polluted
through
various
methods.
However,
conventional
remediation
methods
suffer
from
limitations
such
as
low
uptake
capacity
or
selectivity,
and
current
quality
standards
cannot
be
met.
Recently,
advanced
porous
materials
(APMs)
shown
promise
improved
segregation
compared
traditional
selectivity.
These
feature
merits
high
surface
area
versatile
functionality,
rendering
them
ideal
platforms
for
design
novel
adsorbents.
This
Review
summarizes
development
employment
APMs
variety
treatments
accompanied
by
assessments
task‐specific
adsorption
performance.
Finally,
we
discuss
our
perspectives
on
future
opportunities
purification.
Advanced Materials,
Год журнала:
2023,
Номер
35(17)
Опубликована: Фев. 4, 2023
Sustainable
organic
electrode
materials,
as
promising
alternatives
to
conventional
inorganic
materials
for
sodium-ion
batteries
(SIBs),
are
still
challenging
realize
long-lifetime
and
high-rate
because
of
their
poor
conductivity,
limited
electroactivity,
severe
dissolution.
It
is
also
urgent
deeply
reveal
electrochemical
mechanism
evolution
processes.
A
porous
polymer
(POP)
with
a
conjugated
hierarchical
structure
designed
synthesized
here.
The
unique
molecule
endow
the
POP
electron
delocalization,
high
ionic
diffusivity,
plentiful
active
sites,
exceptional
stability,
solubility
in
electrolytes.
When
evaluated
an
anode
SIBs,
exhibits
appealing
properties
regarding
reversible
capacity,
rate
behaviors,
long-duration
life.
Importantly,
using
judiciously
combined
experiments
theoretical
computation,
including
situ
transmission
microscopy
(TEM),
ex
spectroscopy,
we
Na-storage
dynamic
processes
POP,
12-electron
reaction
process
Na,
low
volume
expansion
(125-106%
vs
initial
100%),
stable
composition
during
repeating
sodiation/de-sodiation
This
quantitative
design
ultrafast
highly
durable
sodium
storage
could
be
immediate
benefit
rational
ideal
properties.
Conjugated
microporous
polymers
(CMPs)
with
donor-acceptor
(D-A)
molecular
structure
show
high
photocatalytic
activity
for
hydrogen
evolution
due
to
the
efficient
light-induced
electron/hole
separation,
which
is
mostly
determined
by
nature
of
electron
donor
and
acceptor
units.
Therefore,
selection
holds
key
point
construct
performance
polymer
photocatalysts.
Herein,
two
dibenzo[b,d]thiophene-S,S-dioxide
(BTDO)
containing
CMP
photocatalysts
using
tetraphenylethylene
(TPE)
or
dibenzo[g,p]chrysene
(DBC)
as
investigate
influence
geometry
on
are
design
synthesized.
Compared
twisted
TPE
donor,
DBC
has
a
planar
extended
π-conjugation,
promotes
charges
transmission
separation.
As
result,
DBC-BTDO
produced
from
shows
remarkable
rate
(HER)
104.86
mmol
h-1
g-1
under
full
arc
light
(λ
>
300
nm),
much
higher
than
that
TPE-BTDO
(1.80
),
demonstrating
can
be
an
constructing
D-A
evolution.
