SYNTHESIS, CHARACTERIZATION, COMPUTATIONAL STUDIES AND SINGLE CRYSTAL STRUCTURES OF [Ru(N–P)2(O–O)] COMPLEXES DOI

M. A. Al-Wahish,

Firas F. Awwadi, Hamdallah A. Hodali

и другие.

Journal of Structural Chemistry, Год журнала: 2021, Номер 62(7), С. 1056 - 1065

Опубликована: Июль 1, 2021

Язык: Английский

Transfer Hydrogenation from 2-propanol to Acetophenone Catalyzed by [RuCl2(η6-arene)P] (P = monophosphine) and [Rh(PP)2]X (PP = diphosphine, X = Cl−, BF4−) Complexes DOI Open Access
Alberto Mannu, Arnald Grabulosa, Salvatore Baldino

и другие.

Catalysts, Год журнала: 2020, Номер 10(2), С. 162 - 162

Опубликована: Фев. 1, 2020

The reduction of ketones through homogeneous transfer hydrogenation catalyzed by transition metals is one the most important routes for obtaining alcohols from carbonyl compounds. interest this method increases when opportune catalytic precursors are able to perform transformation in an asymmetric fashion, generating enantiomerically enriched chiral alcohols. This reaction has been extensively studied terms catalysts and variety substrates. A large amount information about possible mechanisms available nowadays, which high importance development systems with excellent outcomes conversion, enantioselectivity Turn Over Frequency. On other side, many mechanistic aspects still unclear, especially those have shown only moderate performances hydeogenation. case neutral [RuCl2(η6-arene)(P)] cationic [Rh(PP)2]X (X = anion; P PP mono- bidentate phosphine, respectively) complexes. Herein, a summary known Transfer Hydrogenation these complexes provided continuous focus on more relevant features.

Язык: Английский

Процитировано

19

Preparation of monocarbonyl ruthenium complexes bearing bidentate nitrogen and phosphine ligands and their catalytic activity in carbonyl compound reduction DOI
Steven Giboulot, Clara Comuzzi, Alessandro Del Zotto

и другие.

Dalton Transactions, Год журнала: 2019, Номер 48(33), С. 12560 - 12576

Опубликована: Янв. 1, 2019

A series of novel monocarbonyl ruthenium catalysts containing bidentate dinitrogen or/and diphosphine ligands are easily obtained through a general and straightforward approach.

Язык: Английский

Процитировано

16

Acetate Acetylacetonate Ampy Ruthenium(II) Complexes as Efficient Catalysts for Ketone Transfer Hydrogenation DOI Creative Commons
Daniela A. Hey,

Michael J. Sauer,

Pauline J. Fischer

и другие.

ChemCatChem, Год журнала: 2020, Номер 12(13), С. 3537 - 3544

Опубликована: Апрель 18, 2020

Abstract The mixed acetate acetylacetonate (acac) ruthenium(II) phosphine complexes Ru(OAc)(acac)P 2 [P =(PPh 3 ) , Ph P(CH 4 PPh (dppb)] were prepared by protonation of Ru(OAc) (PPh with acetylacetone in dichloromethane. Reaction the dppb derivative 2‐(aminomethyl)pyridine (ampy) affords complex Ru(OAc)(acac)(ampy)(dppb), which converts to [Ru(acac)(ampy)(dppb)](OAc) toluene at 90 °C. In former ampy ligand is monodentate and coordinates through NH ‐moiety. isolated acac are active catalysts for transfer hydrogenation ketones loadings as low 0.01 mol%, having a strong accelerating effect. Several aromatic aliphatic ketone substrates converted their corresponding alcohols, different electronic influences substituents on acetophenone tolerated.

Язык: Английский

Процитировано

13

Cationic carboxylate and thioacetate ruthenium(ii) complexes: synthesis and cytotoxic activity against anaplastic thyroid cancer cells DOI
Denise Lovison, Lorenzo Allegri, Federica Baldan

и другие.

Dalton Transactions, Год журнала: 2020, Номер 49(24), С. 8375 - 8388

Опубликована: Янв. 1, 2020

High cytotoxic and antimetastatic activities against anaplastic thyroid cancer are displayed by cationic complexes [RuX(CO)(dppb)(phen)]Y (X = Y OAc, OPiv, SAc, NCS; X Cl PF6).

Язык: Английский

Процитировано

13

Abnormal NHC ruthenium catalysts: mechanistic investigations of their preparation and steric influence on catalytic performance DOI
Alexander D. Böth,

Michael J. Sauer,

Walter Baratta

и другие.

Catalysis Science & Technology, Год журнала: 2022, Номер 12(18), С. 5597 - 5603

Опубликована: Янв. 1, 2022

Preparation of bis-aNHC Ru catalysts, identification formation intermediates and application in transfer hydrogenation Oppenauer-type oxidation, observing an inversion activity appearing to be dependent on steric hindrance.

Язык: Английский

Процитировано

9

Preparation of Neutral trans - cis [Ru(O2CR)2P2(NN)], Cationic [Ru(O2CR)P2(NN)](O2CR) and Pincer [Ru(O2CR)(CNN)P2] (P = PPh3, P2 = diphosphine) Carboxylate Complexes and their Application in the Catalytic Carbonyl Compounds Reduction DOI Creative Commons
Salvatore Baldino, Steven Giboulot, Denise Lovison

и другие.

Organometallics, Год журнала: 2021, Номер 40(8), С. 1086 - 1103

Опубликована: Апрель 14, 2021

The diacetate complexes trans-[Ru(κ1-OAc)2(PPh3)2(NN)] (NN = ethylenediamine (en) (1), 2-(aminomethyl)pyridine (ampy) (2), 2-(aminomethyl)pyrimidine (ampyrim) (3)) have been isolated in 76–88% yield by reaction of [Ru(κ2-OAc)2(PPh3)2] with the corresponding nitrogen ligands. ampy-type derivatives 2 and 3 undergo isomerization to thermodynamically most stable cationic [Ru(κ1-OAc)(PPh3)2(NN)]OAc (2a 3a) cis-[Ru(κ1-OAc)2(PPh3)2(NN)] (2b 3b) methanol at RT. trans-[Ru(κ1-OAc)2(P2)2] (P2 dppm (4), dppe (5)) compounds synthesized from suitable diphosphine toluene 95 °C. complex cis-[Ru(κ1-OAc)2(dppm)(ampy)](6) has obtained reflux ampy. trans-[Ru(κ1-OAc)2P2(NN)] (7–16; NN en, ampy, ampyrim, 8-aminoquinoline; P2 dppp, dppb, dppf, (R)-BINAP) can be easily a treatment ligands Alternatively these prepared trans-[Ru(OAc)2(PPh3)2(NN)] MEK 50 use (R)-BINAP affords trans-[Ru(κ1-OAc)2((R)-BINAP)(NN)] ampy (11), ampyrim (15)) as single stereoisomers. Treatment 8–15 RT leads [Ru(κ2-OAc)P2(NN)]OAc (8a–15a; ampyrim; (R)-BINAP). Similarly 2, dipivalate trans-[Ru(κ1-OPiv)2(PPh3)2(ampy)] (18) is [Ru(κ2-OPiv)2(PPh3)2] (17) CHCl3. pincer acetate [Ru(κ1-OAc)(CNNOMe)(PPh3)2] (19) HCNNOMe ligand 2-propanol NEt3 reflux. In addition, dppb [Ru(κ1-OAc)(CNN)(dppb)] (CNN AMTP (20), AMBQPh (21)) [Ru(κ2-OAc)2(PPh3)2], HAMTP or HAMBQPh NEt3, respectively. are active transfer hydrogenation H2 carbonyl S/C values up 10000 TOF 160000 h–1.

Язык: Английский

Процитировано

9

Bulky Diphosphine Acetate Ruthenium Complexes: Synthesis and Catalytic Activity in Ketone Transfer Hydrogenation and Alkyne Dimerization DOI Creative Commons
Maurizio Ballico, Daniele Zuccaccia, Rosario Figliolia

и другие.

Organometallics, Год журнала: 2020, Номер 39(17), С. 3180 - 3193

Опубликована: Авг. 18, 2020

Several mononuclear ruthenium complexes containing bulky diphosphines have been easily prepared from acetate precursors. The cyclohexyl complex [Ru(η2-OAc)2(DCyPF)] (1-cy; DCyPF = 1,1′-bis(dicyclohexylphosphino)ferrocene) is synthesized [Ru(η2-OAc)2(PPh3)2] and in toluene at reflux, whereas the ethylenediamine (en) derivatives trans-[Ru(η1-OAc)2(PP)(en)] (PP 1,1′-bis(diisopropylphosphino)ferrocene (DiPPF) (2), (3)) obtained a one-pot reaction [Ru(η2-OAc)2(PPh3)2], PP, en n-heptane. Treatment of isopropylphosphine [Ru(η2-OAc)2(DiPPF)] (1-ip) with 2-(aminomethyl)pyridine (ampy) methanol affords isolation mixture cationic [Ru(η2-OAc)(DiPPF)(ampy)]OAc (5a) cis-[Ru(η1-OAc)2(DiPPF)(ampy)] (5b) (4/1 molar ratio), via trans-[Ru(η1-OAc)2(DiPPF)(ampy)] (4) characterized low temperature. analogous compound trans-[Ru(η1-OAc)2(DCyPF)(ampy)] (6), ampy heptane, slowly converts into [Ru(η2-OAc)(DCyPF)(ampy)]OAc (7) RT. monocarbonyl [Ru(η1-OAc)(η2-OAc)(PP)(CO)] 1,3-bis(cyclohexylphosphino)propane (DCyPP) (8), (R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine (Josiphoscy) (9)) are [Ru(η1-OAc)(η2-OAc)(PPh3)2(CO)] suitable diphosphine. [Ru(η1-OAc)(η2-OAc)(DiPPF)(CO)] (10) phenylacetylene presence pyridine leads to alkynyl [Ru(η2-OAc)(C≡CPh)(DiPPF)(CO)] (11), by X-ray diffraction analysis. Protonation 10 2 equiv TFA RT gives [Ru(η1-OCOCF3)(η2-OCOCF3)(DiPPF)(CO)] (12). dicarbonyl trans,cis-[Ru(η1-OAc)2(DiPPF)(CO)2] (13) 1-ip CO (1 atm) CH2Cl2, isomer cis,cis-[Ru(η1-OAc)2(DiPPF)(CO)2] (14) can be carbonylation 10. When 13 heated solid state, formed decarbonylation. These promote transfer hydrogenation acetophenone 2-propanol (S/C 1000–2000) NaOiPr (2 mol %), affording TOF value up 81000 h–1 for 9 30 °C. Complex catalyzes head-to-head dimerization terminal alkynes 1,4-enynes reflux high stereoselectivity kinetic Z isomer.

Язык: Английский

Процитировано

8

Towards mid-valent rhenium fluoro-phosphine complexes via hexafluoridorhenate(IV) anion pathway assisted by trifluoro acetic acid DOI Creative Commons
Samundeeswari Mariappan Balasekaran, Adelheid Hagenbach, Frédéric Poineau

и другие.

Inorganic Chemistry Communications, Год журнала: 2020, Номер 119, С. 108064 - 108064

Опубликована: Июнь 29, 2020

Язык: Английский

Процитировано

4

Efficient, Facile, and Green Synthesis of Ruthenium Carboxylate Complexes by Manual Grinding DOI Open Access
Eleonora Aneggi, Daniele Zuccaccia, Andrea Porcheddu

и другие.

Processes, Год журнала: 2024, Номер 12(7), С. 1413 - 1413

Опубликована: Июль 6, 2024

Recently, scientists have been developing sustainable processes, and in this context, mechanochemistry is commonly associated with green chemistry for its ability to reduce waste generation from chemical reactions. The well-known acetate complex, diacetate bis(triphenylphosphine) ruthenium(II) [Ru(OAc)2(PPh3)2], a versatile precursor preparing active complexes several catalytic This report presents an efficient straightforward manual grinding protocol the synthesis of ruthenium carboxylate starting commercially available [RuCl2(PPh3)3] metal carboxylates. work represents novel preliminary investigation into precursors’ alternative solventless route based on grinding. To our knowledge, first time [Ru(OAc)2(PPh3)2] has prepared via mechanochemical procedure. method also investigated other alkali carboxylates yields ranging 30 80% were obtained. A comparison sustainability environmental impact between conventional solution carried out using E-factor Mass Productivity. While complex MP only slightly better compared solvent (3 vs. 4 ~6 5 MP), benzoate higher results found (1 ~4 10 MP).

Язык: Английский

Процитировано

0

Ruthenium and Osmium Complexes Containing NHC and π-Acid Ligands DOI
Alexander D. Böth,

Michael J. Sauer,

Robert M. Reich

и другие.

Elsevier eBooks, Год журнала: 2022, Номер unknown, С. 444 - 527

Опубликована: Янв. 1, 2022

Язык: Английский

Процитировано

1