Coordination Chemistry Reviews, Journal Year: 2023, Volume and Issue: 493, P. 215301 - 215301
Published: June 18, 2023
Language: Английский
Coordination Chemistry Reviews, Journal Year: 2021, Volume and Issue: 432, P. 213743 - 213743
Published: Jan. 22, 2021
Language: Английский
Citations
424
Chemical Reviews, Journal Year: 2022, Volume and Issue: 122(9), P. 9078 - 9144
Published: March 28, 2022
In the past two decades, metal-organic frameworks (MOFs) or porous coordination polymers (PCPs) assembled from metal ions clusters and organic linkers via metal-ligand bonds have captivated significant scientific interest on account of their high crystallinity, exceptional porosity, tunable pore size, modularity, diverse functionality. The opportunity to achieve functional materials by design with promising properties, unattainable for solid-state in general, distinguishes MOFs other classes materials, particular, traditional such as activated carbon, silica, zeolites, thereby leading complementary properties. Scientists conducted intense research production chiral MOF (CMOF) specific applications including but not limited recognition, separation, catalysis since discovery first CMOF (i.e., d- l-POST-1). At present, CMOFs become interdisciplinary between chirality chemistry, material which involve many subjects physics, optics, medicine, pharmacology, biology, crystal engineering, environmental science, etc. this review, we will systematically summarize recent progress regarding strategies, synthetic approaches, cutting-edge applications. highlight successful implementation asymmetric catalysis, enantioselective sensing. We envision that review provide readers a good understanding chemistry and, more importantly, facilitate endeavors rational multifunctional industrial implementation.
Language: Английский
Citations
353
Journal of the American Chemical Society, Journal Year: 2022, Volume and Issue: 144(24), P. 10663 - 10687
Published: June 8, 2022
Hydrogen-bonded organic frameworks (HOFs), self-assembled from strategically pre-designed molecular tectons with complementary hydrogen-bonding patterns, are rapidly evolving into a novel and important class of porous materials. In addition to their common features shared other functionalized materials constructed modular building blocks, the intrinsically flexible reversible H-bonding connections endow HOFs straightforward purification procedures, high crystallinity, solution processability, recyclability. These unique advantages have attracted considerable attention across broad range fields, including gas adsorption separation, catalysis, chemical sensing, electrical optical However, relatively weak interactions within can potentially limit stability potential use in further applications. To that end, this Perspective highlights recent advances development chemically thermally robust HOF systematically discusses relevant design rules synthesis strategies access highly stable HOFs.
Language: Английский
Citations
344
ACS Omega, Journal Year: 2022, Volume and Issue: 7(49), P. 44507 - 44531
Published: Dec. 2, 2022
Metal ions or clusters that have been bonded with organic linkers to create one- more-dimensional structures are referred as metal–organic frameworks (MOFs). Reticular synthesis also forms MOFs properly designated components can result in crystals high porosities and great chemical thermal stability. Due the wider surface area, huge pore size, crystalline nature, tunability, numerous shown be potential candidates various fields like gas storage delivery, energy storage, catalysis, chemical/biosensing. This study provides a quick overview of current MOF techniques order familiarize newcomers sciences field fast-growing research. Beginning classification nomenclature MOFs, approaches demonstrated. We emphasize applications such drug rechargeable batteries, supercapacitors, separation membranes. Lastly, future scope is discussed along prospective opportunities for application nano-MOFs, which will help promote their uses multidisciplinary
Language: Английский
Citations
316
Angewandte Chemie International Edition, Journal Year: 2021, Volume and Issue: 60(45), P. 23946 - 23974
Published: March 30, 2021
At its core, reticular chemistry has translated the precision and expertise of organic inorganic synthesis to solid state. While initial excitement over metal-organic frameworks (MOFs) covalent (COFs) was undoubtedly fueled by their unprecedented porosity surface areas, most profound scientific innovation field been elaboration design strategies for extended crystalline solids through strong directional bonds. In this contribution we highlight different classes materials that have developed, how these can be functionalized, complexity introduced into backbones. Finally, show structural control is being from molecular scale crystal morphology shape on nanoscale, all way shaping bulk scale.
Language: Английский
Citations
310
Matter, Journal Year: 2021, Volume and Issue: 4(7), P. 2230 - 2265
Published: July 1, 2021
Language: Английский
Citations
262
Chemical Society Reviews, Journal Year: 2022, Volume and Issue: 51(3), P. 1045 - 1097
Published: Jan. 1, 2022
This review illustrates molecular-scale confinement, containment, isolation, and related concepts to present MOF-centric catalysts realize desired chemical transformations.
Language: Английский
Citations
243
Chemical Society Reviews, Journal Year: 2021, Volume and Issue: 50(11), P. 6349 - 6368
Published: Jan. 1, 2021
Since the transition of energy platforms, proton-conductive metal–organic frameworks (MOFs) exhibiting high performance have been extensively investigated with rational strategies for their potential application in solid-state electrolytes.
Language: Английский
Citations
238
Nature Protocols, Journal Year: 2022, Volume and Issue: 17(12), P. 2990 - 3027
Published: Sept. 5, 2022
Language: Английский
Citations
235
Advanced Energy Materials, Journal Year: 2021, Volume and Issue: 11(39)
Published: Sept. 1, 2021
Abstract Proton conductivity is the paramount property of proton‐conducting materials that are playing significant roles in diverse electrochemical devices with applications proton exchange membranes (PEMs) for fuel cells (PEMFCs). Considering scarcity fossil fuels, development clean and green renewable energy resources in‐demand across globe. Toward this direction, solid‐state conductors interest. The higher structural tunability, lower density, good crystallinity, accessible well‐defined pores, excellent thermal chemical stability covalent‐organic frameworks (COFs) make them versatile platforms as both under hydrous anhydrous conditions. Taking advantage such superior properties, reports on COFs have been increasing swiftly since 2014, which demands a summarization comprehensive discussion “at glance” visualization further development. In review, showcased newer class material. A presented by organizing strategies taken to develop COFs. Establishment structure–function relationships implementation discussed well. Moreover, challenges future prospects elaborately critically analyzed.
Language: Английский
Citations
186