Confining Polymer Electrolyte in MOF for Safe and High‐Performance All‐Solid‐State Sodium Metal Batteries DOI Creative Commons

Jinfang Zhang,

Yuanyuan Wang, Qingbing Xia

и другие.

Angewandte Chemie, Год журнала: 2024, Номер 136(16)

Опубликована: Фев. 19, 2024

Abstract Nanoconfined polymer molecules exhibit profound transformations in their properties and behaviors. Here, we present the synthesis of a polymer‐in‐MOF single ion conducting solid electrolyte, where segments are partially confined within nanopores ZIF‐8 particles through Lewis acid‐base interactions for solid‐state sodium‐metal batteries (SSMBs). The unique nanoconfinement effectively weakens Na coordination with anions, facilitating dissociation from salt. Simultaneously, well‐defined provide oriented ordered migration channels migration. As result, this pioneering design allows electrolyte to achieve transference number 0.87, conductivity 4.01×10 −4 S cm −1 , an extended electrochemical voltage window up 4.89 V vs. Na/Na + . assembled SSMBs (with 3 2 (PO 4 ) as cathode) dendrite‐free Na‐metal deposition, promising rate capability, stable cycling performance 96 % capacity retention over 300 cycles. This innovative offers compelling strategy advancing high‐performance safe metal battery technologies.

Язык: Английский

Metal–Organic Framework-Based Hierarchically Porous Materials: Synthesis and Applications DOI
Guorui Cai, Yan Peng, Liangliang Zhang

и другие.

Chemical Reviews, Год журнала: 2021, Номер 121(20), С. 12278 - 12326

Опубликована: Июль 19, 2021

Metal-organic frameworks (MOFs) have been widely recognized as one of the most fascinating classes materials from science and engineering perspectives, benefiting their high porosity well-defined tailored structures components at atomic level. Although intrinsic micropores endow size-selective capability surface area, etc., narrow pores limit applications toward diffusion-control large-size species involved processes. In recent years, construction hierarchically porous MOFs (HP-MOFs), MOF-based composites, derivatives has captured widespread interest to extend conventional materials. this Review, advances in design, synthesis, functional are summarized. Their structural characters various applications, including catalysis, gas storage separation, air filtration, sewage treatment, sensing energy storage, demonstrated with typical reports. The comparison HP-MOFs traditional (e.g., zeolite, silica, carbons, metal oxides, polymers), subsisting challenges, well future directions research field, also indicated.

Язык: Английский

Процитировано

1082
The Current Status of MOF and COF Applications DOI
Ralph Freund, Orysia Zaremba, Giel Arnauts

и другие.

Angewandte Chemie International Edition, Год журнала: 2021, Номер 60(45), С. 23975 - 24001

Опубликована: Май 14, 2021

The amalgamation of different disciplines is at the heart reticular chemistry and has broadened boundaries by opening up an infinite space chemical composition, structure, material properties. Reticular design enabled precise prediction crystalline framework structures, tunability incorporation various functionalities onto backbone, as a consequence, fine-tuning metal-organic (MOF) covalent organic (COF) properties beyond that any other class. Leveraging unique materials resulted in significant advances from both fundamental applied perspective. Here, we wish to review milestones MOF COF research give critical view on progress their real-world applications. Finally, briefly discuss major challenges field need be addressed pave way for industrial

Язык: Английский

Процитировано

785
Filler‐Integrated Composite Polymer Electrolyte for Solid‐State Lithium Batteries DOI

Shuailei Liu,

Wenyi Liu, Deliang Ba

и другие.

Advanced Materials, Год журнала: 2022, Номер 35(2)

Опубликована: Авг. 11, 2022

Composite polymer electrolytes (CPEs) utilizing fillers as the promoting component bridge gap between solid and inorganic electrolytes. The integration of into matrices is demonstrated a prevailing strategy to enhance Li-ion transport assist in constructing Li+ -conducting electrode-electrolyte interface layer, which addresses two key barriers solid-state lithium batteries (SSLBs): low ionic conductivity electrolyte high interfacial impedance. Recent review articles have largely focused on performance broad spectrum CPEs general effects SSLBs device. Recognizing this, this review, after briefly presenting categories (traditional emerged) promoted conducting mechanisms CPEs, progress structure design principle, with emphasis crucial influence filler size, concentration, hybridization strategies filler-polymer that most critical assessed. latest exciting advances filler-enabled situ generation -conductive layer at greatly reduce impedance are further elaborated. Finally, discusses challenges be addressed, outlines research directions, provides future vision for developing advanced high-performing SSLBs.

Язык: Английский

Процитировано

321
Progress in Solid Polymer Electrolytes for Lithium‐Ion Batteries and Beyond DOI Creative Commons
Yong An,

Xue Han,

Yuyang Liu

и другие.

Small, Год журнала: 2021, Номер 18(3)

Опубликована: Сен. 28, 2021

Abstract Solid‐state polymer electrolytes (SPEs) for high electrochemical performance lithium‐ion batteries have received considerable attention due to their unique characteristics; they are not prone leakage, and exhibit low flammability, excellent processability, good flexibility, safety levels, superior thermal stability. However, current SPEs far from commercialization, mainly the ionic conductivity, Li + transference number ( t Li+ ), poor electrode/electrolyte interface contact, narrow oxidation window, long‐term stability of metal. Recent work on improving these aspects summarized systematically here with a particular focus underlying mechanisms, improvement strategies also proposed. This review could lead deeper consideration issues solutions affecting application pave new pathway safe, high‐performance batteries.

Язык: Английский

Процитировано

220
Porosity Engineering of MOF‐Based Materials for Electrochemical Energy Storage DOI
Ran Du, Yifan Wu, Yuchen Yang

и другие.

Advanced Energy Materials, Год журнала: 2021, Номер 11(20)

Опубликована: Апрель 17, 2021

Abstract Metal–organic frameworks (MOFs) feature rich chemistry, ordered micro‐/mesoporous structure and uniformly distributed active sites, offering great scope for electrochemical energy storage (EES) applications. Given the particular importance of porosity charge transport catalysis, a critical assessment its design, formation, engineering is needed development optimization EES devices. Such efforts can be realized via design reticular multiscale pore engineering, synthesis methodologies, postsynthesis treatment, which remarkably expand By imparting conductive backbones, guest compounds, and/or redox‐active centers, MOFs their derivatives have been heavily explored in last decade. To improve MOF‐based materials EES, strategies architecturing are systematically analyzed applications reviewed supercapacitors metal‐ion batteries. Potential challenges future opportunities also discussed to guide development.

Язык: Английский

Процитировано

155
Carbon neutrality strategies for sustainable batteries: from structure, recycling, and properties to applications DOI
Jiao Lin, Xiaodong Zhang,

Ersha Fan

и другие.

Energy & Environmental Science, Год журнала: 2023, Номер 16(3), С. 745 - 791

Опубликована: Янв. 1, 2023

Research on new energy storage technologies has been sparked by the crisis, greenhouse effect, and air pollution, leading to continuous development commercialization of electrochemical batteries.

Язык: Английский

Процитировано

154
Metal-air batteries: progress and perspective DOI
Yuhui Chen, Ji‐Jing Xu, Ping He

и другие.

Science Bulletin, Год журнала: 2022, Номер 67(23), С. 2449 - 2486

Опубликована: Ноя. 26, 2022

Язык: Английский

Процитировано

136
A 3D interconnected metal-organic framework-derived solid-state electrolyte for dendrite-free lithium metal battery DOI
Zhongliang Li, Shuxian Wang,

Junkai Shi

и другие.

Energy storage materials, Год журнала: 2022, Номер 47, С. 262 - 270

Опубликована: Фев. 10, 2022

Язык: Английский

Процитировано

135
Glassy Metal–Organic‐Framework‐Based Quasi‐Solid‐State Electrolyte for High‐Performance Lithium‐Metal Batteries DOI Creative Commons
Guangshen Jiang,

Changzhen Qu,

Fei Xu

и другие.

Advanced Functional Materials, Год журнала: 2021, Номер 31(43)

Опубликована: Авг. 3, 2021

Abstract Enhancing ionic conductivity of quasi‐solid‐state electrolytes (QSSEs) is one the top priorities, while conventional metal–organic frameworks (MOFs) severely impede ion migration due to their abundant grain boundaries. Herein, ZIF‐4 glass, a subset MOFs, reported as QSSEs (LGZ) for lithium‐metal batteries. With lean Li content (0.12 wt%) and solvent amount (19.4 wt%), LGZ can achieve remarkable 1.61 × 10 −4 S cm −1 at 30 °C, higher than those crystalline ZIF‐4‐based (LCZ, 8.21 −5 ) containing high contents (0.32–5.4 huge plasticizer (30–70 wt%). Even −56.6 still deliver 5.96 −6 (vs 4.51 −7 LCZ). Owing boundary‐free isotropic properties glassy ZIF‐4, facilitated conduction enables homogeneous flux, suppressing dendrites. When paired with LiFePO 4 cathode, cell demonstrates prominent cycling capacity 101 mAh g 500 cycles 1 C near‐utility retention, outperforming LCZ (30.7 explored MOF‐/covalent–organic (COF)‐based QSSEs. Hence, MOF glasses will be potential platform practical batteries in future.

Язык: Английский

Процитировано

122
Ionic Covalent Organic Frameworks for Energy Devices DOI
Xiaoguang Liang, Ye Tian, Yufei Yuan

и другие.

Advanced Materials, Год журнала: 2021, Номер 33(52)

Опубликована: Окт. 8, 2021

Covalent organic frameworks (COFs) are a class of porous crystalline materials whose facile preparation, functionality, and modularity have led to their becoming powerful platforms for the development molecular devices in many fields (bio)engineering, such as energy storage, environmental remediation, drug delivery, catalysis. In particular, ionic COFs (iCOFs) highly useful constructing devices, functional groups can transport ions efficiently, nonlabile ordered all-covalent pore structures backbones provide ideal pathways long-term under harsh electrochemical conditions. Here, current research progress on use iCOFs specifically lithium-based batteries fuel cells, is reviewed terms iCOF backbone-design strategies, synthetic approaches, properties, engineering techniques, applications. categorized anionic or cationic COFs, how each these types lithium ions, protons, hydroxides illustrated. Finally, challenges future opportunities utilization described. This review will therefore serve reference state-of-the-art design application strategies focusing devices.

Язык: Английский

Процитировано

122