Dalton Transactions, Год журнала: 2021, Номер 50(7), С. 2342 - 2349
Опубликована: Янв. 1, 2021
The current state-of-the-art strategies to improve the photoactivity of metal–organic frameworks are summarized.
Язык: Английский
Progress in Materials Science, Год журнала: 2021, Номер 125, С. 100904 - 100904
Опубликована: Ноя. 22, 2021
Язык: Английский
Процитировано
341
Materials Today Chemistry, Год журнала: 2021, Номер 19, С. 100380 - 100380
Опубликована: Янв. 10, 2021
Язык: Английский
Процитировано
294
Solar RRL, Год журнала: 2021, Номер 5(7)
Опубликована: Май 20, 2021
Various photocatalysts have been developed for photocatalytic water splitting—one of the most important processes that produces dihydrogen as clean energy fuel cells. The successful achievements this application are based mainly on transition metal oxides and some sulfides/nitrides. Recently, metal–organic frameworks (MOFs), a class hybrid functional materials comprising organic backbone tethered infinitively in limitless way by metal‐oxide clusters, both which can be customized accurately at molecular level targeted applications, able to photocatalytically degrade water. Herein, it is first aimed comprehensively review fundamentals splitting catalyzed semiconductor photocatalysts, casts light understanding challenges area, thus providing strategies development, if not rational design, visible‐light‐driven MOFs capable degrading hydrogen oxygen. recent advancements using MOF further described benchmark limitations considered so readers imagine big picture field pay considerable attention future solutions.
Язык: Английский
Процитировано
270
Journal of Materials Chemistry A, Год журнала: 2020, Номер 8(35), С. 18215 - 18219
Опубликована: Янв. 1, 2020
A series of morphology-regulated oxygen-evolution electrocatalysts including nanosheets, nanoflowers, nanotubes and aggregations derived from Hofmann-type metal–organic frameworks have been developed demonstrated efficient catalytic properties.
Язык: Английский
Процитировано
187
Journal of Power Sources, Год журнала: 2021, Номер 488, С. 229444 - 229444
Опубликована: Янв. 18, 2021
Язык: Английский
Процитировано
174
Advanced Energy and Sustainability Research, Год журнала: 2021, Номер 2(8)
Опубликована: Март 14, 2021
Metal–organic frameworks (MOFs), constructed from metal clusters/ions and organic ligands, are ideal materials for photo/electrocatalysis, mainly due to the advantages of large surface areas, high porosity, easily tunable optical electronic structures. Herein, recent important advances on MOF‐based photo/electrocatalysts including pristine MOFs, MOF composites, derivatives summarized. The novel strategies improve photo/electrocatalytic performances highlighted. Finally, current challenges future development MOFs photo/electrocatalysis discussed ad outlined.
Язык: Английский
Процитировано
152
Dalton Transactions, Год журнала: 2021, Номер 50(33), С. 11331 - 11346
Опубликована: Янв. 1, 2021
Recent progress on 2D conductive MOFs and layered containing pillar-layered nanosheets as electrode materials in SCs is reviewed, including synthetic design strategies, electrochemical performances, working mechanisms.
Язык: Английский
Процитировано
146
Angewandte Chemie International Edition, Год журнала: 2021, Номер 61(3)
Опубликована: Ноя. 15, 2021
Titanium metal-organic frameworks (Ti-MOFs), as an appealing type of artificial photocatalyst, have shown great potential in the field solar energy conversion due to their well-studied photoredox activity (similar TiO2 ) and good optical responsiveness linkers, which serve antenna absorb visible-light. Although much effort has been dedicated developing Ti-MOFs with high photocatalytic activity, performances are still poor. Herein, we implemented a covalent-integration strategy construct series multivariate Ti-MOF/COF hybrid materials PdTCPP⊂PCN-415(NH2 )/TpPa (composites 1, 2, 3), featuring excellent visible-light utilization, suitable band gap, surface area for H2 production. Notably, resulting composites demonstrated remarkably enhanced visible-light-driven evolution performance, especially composite 2 maximum rate 13.98 mmol g-1 h-1 (turnover frequency (TOF)=227 ), is higher than that (0.21 TpPa (6.51 ). Our work thereby suggests new approach highly efficient photocatalysts beyond.
Язык: Английский
Процитировано
123
Journal of Materials Chemistry A, Год журнала: 2021, Номер 10(2), С. 475 - 507
Опубликована: Дек. 15, 2021
MOF/COF-based hybrids show the properties of precisely tunable compositions and structures, provide a broad range potential applications in gas sorption separation, catalysis, energy transfer, biomedicine, etc.
Язык: Английский
Процитировано
116
Small Structures, Год журнала: 2021, Номер 3(5)
Опубликована: Окт. 9, 2021
Iron‐series (Fe, Co, and Ni) containing metal–organic frameworks (MOFs) have gained great concern in supercapacitors (SCs) because of their tailorable architectures, multiple redox‐active sites, intriguing properties. Given the importance porosities MOFs for charge transmission, an essential assessment designs, preparation methods, engineering technologies is strongly required to further explore optimize SCs. Through empowering conductive backbones centers, iron‐series MOF‐based electrodes made outstanding achievements recently. This review aims summarize these core reports on MOFs. Correspondingly, design strategy, reason compositing, strategy introducing heteroatoms, current divergences structural alteration mechanisms are discussed. Potential bottleneck issues coping strategies also perspectively discussed guide future optimization.
Язык: Английский
Процитировано
111