UiO-66 metal–organic frameworks in water treatment: A critical review

Progress in Materials Science, Journal Year: 2021, Volume and Issue: 125, P. 100904 - 100904

Published: Nov. 22, 2021

Language: Английский

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Recent developments in the use of metal oxides for photocatalytic degradation of pharmaceutical pollutants in water—a review

Materials Today Chemistry, Journal Year: 2021, Volume and Issue: 19, P. 100380 - 100380

Published: Jan. 10, 2021

Language: Английский

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Metal–Organic Frameworks for Photocatalytic Water Splitting

Solar RRL, Journal Year: 2021, Volume and Issue: 5(7)

Published: May 20, 2021

Various photocatalysts have been developed for photocatalytic water splitting—one of the most important processes that produces dihydrogen as clean energy fuel cells. The successful achievements this application are based mainly on transition metal oxides and some sulfides/nitrides. Recently, metal–organic frameworks (MOFs), a class hybrid functional materials comprising organic backbone tethered infinitively in limitless way by metal‐oxide clusters, both which can be customized accurately at molecular level targeted applications, able to photocatalytically degrade water. Herein, it is first aimed comprehensively review fundamentals splitting catalyzed semiconductor photocatalysts, casts light understanding challenges area, thus providing strategies development, if not rational design, visible‐light‐driven MOFs capable degrading hydrogen oxygen. recent advancements using MOF further described benchmark limitations considered so readers imagine big picture field pay considerable attention future solutions.

Language: Английский

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Morphology regulation of metal–organic framework-derived nanostructures for efficient oxygen evolution electrocatalysis

Journal of Materials Chemistry A, Journal Year: 2020, Volume and Issue: 8(35), P. 18215 - 18219

Published: Jan. 1, 2020

A series of morphology-regulated oxygen-evolution electrocatalysts including nanosheets, nanoflowers, nanotubes and aggregations derived from Hofmann-type metal–organic frameworks have been developed demonstrated efficient catalytic properties.

Language: Английский

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An extensive review on three dimension architectural Metal-Organic Frameworks towards supercapacitor application

Journal of Power Sources, Journal Year: 2021, Volume and Issue: 488, P. 229444 - 229444

Published: Jan. 18, 2021

Language: Английский

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Metal–Organic Frameworks for Photo/Electrocatalysis

Advanced Energy and Sustainability Research, Journal Year: 2021, Volume and Issue: 2(8)

Published: March 14, 2021

Metal–organic frameworks (MOFs), constructed from metal clusters/ions and organic ligands, are ideal materials for photo/electrocatalysis, mainly due to the advantages of large surface areas, high porosity, easily tunable optical electronic structures. Herein, recent important advances on MOF‐based photo/electrocatalysts including pristine MOFs, MOF composites, derivatives summarized. The novel strategies improve photo/electrocatalytic performances highlighted. Finally, current challenges future development MOFs photo/electrocatalysis discussed ad outlined.

Language: Английский

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Recent progress on pristine two-dimensional metal–organic frameworks as active components in supercapacitors

Dalton Transactions, Journal Year: 2021, Volume and Issue: 50(33), P. 11331 - 11346

Published: Jan. 1, 2021

Recent progress on 2D conductive MOFs and layered containing pillar-layered nanosheets as electrode materials in SCs is reviewed, including synthetic design strategies, electrochemical performances, working mechanisms.

Language: Английский

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Enhancing Photocatalytic Hydrogen Production via the Construction of Robust Multivariate Ti‐MOF/COF Composites

Angewandte Chemie International Edition, Journal Year: 2021, Volume and Issue: 61(3)

Published: Nov. 15, 2021

Titanium metal-organic frameworks (Ti-MOFs), as an appealing type of artificial photocatalyst, have shown great potential in the field solar energy conversion due to their well-studied photoredox activity (similar TiO2 ) and good optical responsiveness linkers, which serve antenna absorb visible-light. Although much effort has been dedicated developing Ti-MOFs with high photocatalytic activity, performances are still poor. Herein, we implemented a covalent-integration strategy construct series multivariate Ti-MOF/COF hybrid materials PdTCPP⊂PCN-415(NH2 )/TpPa (composites 1, 2, 3), featuring excellent visible-light utilization, suitable band gap, surface area for H2 production. Notably, resulting composites demonstrated remarkably enhanced visible-light-driven evolution performance, especially composite 2 maximum rate 13.98 mmol g-1 h-1 (turnover frequency (TOF)=227 ), is higher than that (0.21 TpPa (6.51 ). Our work thereby suggests new approach highly efficient photocatalysts beyond.

Language: Английский

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Heterostructured hybrids of metal–organic frameworks (MOFs) and covalent–organic frameworks (COFs)

Journal of Materials Chemistry A, Journal Year: 2021, Volume and Issue: 10(2), P. 475 - 507

Published: Dec. 15, 2021

MOF/COF-based hybrids show the properties of precisely tunable compositions and structures, provide a broad range potential applications in gas sorption separation, catalysis, energy transfer, biomedicine, etc.

Language: Английский

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Recent progress on porous carbon derived from Zn and Al based metal-organic frameworks as advanced materials for supercapacitor applications

Journal of Energy Storage, Journal Year: 2021, Volume and Issue: 44, P. 103263 - 103263

Published: Oct. 4, 2021

Language: Английский

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