Recent strategies to improve the photoactivity of metal–organic frameworks DOI
Yu Yan,

Reza Abazari,

Juming Yao

и другие.

Dalton Transactions, Год журнала: 2021, Номер 50(7), С. 2342 - 2349

Опубликована: Янв. 1, 2021

The current state-of-the-art strategies to improve the photoactivity of metal–organic frameworks are summarized.

Язык: Английский

Recent progress on porous carbon derived from Zn and Al based metal-organic frameworks as advanced materials for supercapacitor applications DOI
Raja Arumugam Senthil, Sedahmed Osman, Junqing Pan

и другие.

Journal of Energy Storage, Год журнала: 2021, Номер 44, С. 103263 - 103263

Опубликована: Окт. 4, 2021

Язык: Английский

Процитировано

110

Principles of Design and Synthesis of Metal Derivatives from MOFs DOI Creative Commons
Thibault De Villenoisy, Xiaoran Zheng, Vienna Wong

и другие.

Advanced Materials, Год журнала: 2023, Номер 35(24)

Опубликована: Янв. 10, 2023

Abstract Materials derived from metal–organic frameworks (MOFs) have demonstrated exceptional structural variety and complexity can be synthesized using low‐cost scalable methods. Although the inherent instability low electrical conductivity of MOFs are largely responsible for their uptake catalysis energy storage, a superior alternative is MOF‐derived metal‐based derivatives (MDs) as these retain complex nanostructures while exhibiting stability conductivities several orders magnitude higher. The present work comprehensively reviews MDs in terms synthesis nanostructural design, including oxides, sulfides, phosphides, nitrides, carbides, transition metals, other minor species. focal point approach identification rationalization design parameters that lead to generation optimal compositions, structures, nanostructures, resultant performance parameters. aim this provide an inclusive platform strategies process materials specific applications. This complemented by detailed figures both summarize processing approaches been reported indicate potential trajectories development. also supported comprehensive up‐to‐date tabular coverage studies.

Язык: Английский

Процитировано

94

Nanosheet-Engineered NH2-MIL-125 with Highly Active Facets for Enhanced Solar CO2 Reduction DOI
Fan Guo,

Mei Yang,

Ruixia Li

и другие.

ACS Catalysis, Год журнала: 2022, Номер 12(15), С. 9486 - 9493

Опубликована: Июль 20, 2022

Rational engineering of metal–organic frameworks (MOFs) with maximum exposed highly active facets for photocatalytic CO2 reduction is desirable yet remains greatly challenging. Herein, ultrathin Ti-MOF NH2-MIL-125 nanosheets are successfully fabricated through a facile and efficient approach relying on the precursors directly. Importantly, surfaces dominated by {110} facet, which has more sites than {001} {111}. In contrast conventional catalysts {001}, {110}, {111} facets, nanosheet material reported here exhibits remarkably high photoreduction performance affording abundant augmented photoinduced electrons. The enhanced solar conversion activity attributed to favorable distribution photoexcited electrons over all Ti in outer surface nanosheet, as revealed density functional theory simulations.

Язык: Английский

Процитировано

83

Metal–organic frameworks for organic transformations by photocatalysis and photothermal catalysis DOI
Hong‐Guang Jin, Pengcheng Zhao, Yunyang Qian

и другие.

Chemical Society Reviews, Год журнала: 2024, Номер 53(18), С. 9378 - 9418

Опубликована: Янв. 1, 2024

Organic transformation by light-driven catalysis, especially, photocatalysis and photothermal denoted as photo(thermal) is an efficient, green, economical route to produce value-added compounds. In recent years, owing their diverse structure types, tunable pore sizes, abundant active sites, metal-organic framework (MOF)-based catalysis has attracted broad interest in organic transformations. this review, we provide a comprehensive systematic overview of MOF-based for First, the general mechanisms, unique advantages, strategies improve performance MOFs are discussed. Then, outstanding examples transformations over introduced according reaction type. addition, several representative advanced characterization techniques used revealing charge kinetics intermediates presented. Finally, prospects challenges field proposed. This review aims inspire rational design development materials with improved catalysis.

Язык: Английский

Процитировано

54

Band gap engineering of metal-organic frameworks for solar fuel productions DOI
Xiangyang Guo, Lifang Liu, Yu Xiao

и другие.

Coordination Chemistry Reviews, Год журнала: 2021, Номер 435, С. 213785 - 213785

Опубликована: Фев. 24, 2021

Язык: Английский

Процитировано

103

Aptamer-functionalized Fe3O4@MOF nanocarrier for targeted drug delivery and fluorescence imaging of the triple-negative MDA-MB-231 breast cancer cells DOI

Hamed Alijani,

Abolhassan Noori, Nassim Faridi

и другие.

Journal of Solid State Chemistry, Год журнала: 2020, Номер 292, С. 121680 - 121680

Опубликована: Авг. 16, 2020

Язык: Английский

Процитировано

101

Biomimetic assembly to superplastic metal–organic framework aerogels for hydrogen evolution from seawater electrolysis DOI Creative Commons
Yuntong Sun,

Shuaishuai Xu,

César A. Ortíz‐Ledón

и другие.

Exploration, Год журнала: 2021, Номер 1(2)

Опубликована: Сен. 23, 2021

Applications for metal-organic frameworks (MOFs) demand their assembly into three-dimensional (3D) macroscopic architectures. The capability of sustaining structural integrity with considerable deformation is important to allow a monolithic material work reliably. Nevertheless, it remains significant challenge introduce superplasticity in 3D MOF networks. Here, we report general procedure synthesizing superplastic aerogels inspired by the hierarchical architecture natural corks. resultant MOFs exhibited excellent that can recover fully and rapidly its original dimension after 50% strain compression unloading >2000 cycles. achieved successively assembling one-dimensional (1D) two-dimensional (2D) then 3D, variety different transition metal active sites (Co-, NiMn-, NiCo-, NiCoMn-) organic ligands (2-thiophenecarboxylic acid glutaric acid). Latent applications have been demonstrated NiMn-MOF serve as new generation flexible electrocatalysts hydrogen evolution reaction (HER) from seawater splitting, which requires low overpotential 243 mV achieve current density 10 mA·cm

Язык: Английский

Процитировано

98

Materials Institute Lavoisier (MIL) based materials for photocatalytic applications DOI

Suzhao Yang,

Xin Li, Guangming Zeng

и другие.

Coordination Chemistry Reviews, Год журнала: 2021, Номер 438, С. 213874 - 213874

Опубликована: Март 23, 2021

Язык: Английский

Процитировано

88

A 3D Anionic Metal Covalent Organic Framework with soc Topology Built from an Octahedral TiIV Complex for Photocatalytic Reactions DOI

Hui‐Shu Lu,

Wang‐Kang Han,

Xiaodong Yan

и другие.

Angewandte Chemie International Edition, Год журнала: 2021, Номер 60(33), С. 17881 - 17886

Опубликована: Май 19, 2021

Abstract The construction of three‐dimensional (3D) covalent organic frameworks (COFs) remains challenging due to the limited types building blocks. With octahedral Ti IV complex as unit, this study reports on first 3D anionic titanium‐based COF ( Ti‐COF‐1 ) with an edge‐transitive (6, 4)‐connected soc topology. exhibits high crystallinity, superior stability, and large specific surface area (1000.4 m 2 g −1 ). Moreover, has a broad absorption band in UV spectrum optical energy gap 1.86 eV, photocatalytic activity toward Meerwein addition reactions. This research demonstrates attractive strategy for design functional COFs.

Язык: Английский

Процитировано

88

Mono-coordinated metallocene ligands endow metal-organic frameworks with highly efficient oxygen evolution and urea electrolysis DOI
Meng Li,

Huachuan Sun,

Jueming Yang

и другие.

Chemical Engineering Journal, Год журнала: 2021, Номер 430, С. 132733 - 132733

Опубликована: Сен. 30, 2021

Язык: Английский

Процитировано

88