Organic Letters,
Год журнала:
2022,
Номер
24(12), С. 2431 - 2435
Опубликована: Март 21, 2022
The
Ce(III)-photocatalyzed
synthesis
of
amides
from
carboxylic
acids
and
aryl
isocyanates
was
developed.
reaction
includes
the
formation
alkyl
radicals
followed
by
radical
addition
to
electron-deficient
carbon
isocyanate.
Green Chemistry,
Год журнала:
2022,
Номер
24(18), С. 7122 - 7130
Опубликована: Янв. 1, 2022
Syntheses
of
β-keto
sulfones
have
been
reported
using
g-C
3
N
4
as
a
recyclable
photocatalyst
along
with
green
chemistry
metrics
and
eco-scale
evaluation.
The Journal of Organic Chemistry,
Год журнала:
2022,
Номер
87(12), С. 8248 - 8255
Опубликована: Май 26, 2022
Ultrasound
has
been
successfully
employed
to
promote
the
thiocyanation
of
C═C
bond
in
enaminones
for
synthesis
α-thiocyanoketones
and
2-aminothiazoles.
The
reactions
with
ammonium
thiocyanate
provide
ultrasound
irradiation
at
room
temperature.
More
interestingly,
simply
further
heating
vessel
after
ultrasonic
leads
selective
2-aminothiazoles
an
unconventional
4-aryl
substructure.
The Journal of Organic Chemistry,
Год журнала:
2022,
Номер
87(19), С. 13195 - 13203
Опубликована: Сен. 15, 2022
Visible
light
photocatalytic
reactions
of
NH2-enaminones
and
ammonium
thiocyanate
for
chemoselective
α-C-H
thiocyanation
have
been
realized
the
first
time,
providing
a
sustainable
route
synthesis
thiocyanated
NH2-enaminones.
In
addition,
enaminone
products
can
be
flexibly
transformed
into
2-aminothiazoles
2-thiazolinones
via
simple
operation.
Organic Letters,
Год журнала:
2022,
Номер
24(12), С. 2431 - 2435
Опубликована: Март 21, 2022
The
Ce(III)-photocatalyzed
synthesis
of
amides
from
carboxylic
acids
and
aryl
isocyanates
was
developed.
reaction
includes
the
formation
alkyl
radicals
followed
by
radical
addition
to
electron-deficient
carbon
isocyanate.