Photochemical N-Formylation of Amines and Cyclic Carbonate Synthesis from Epoxides by the Use of Light-Mediated Fixation of Carbon Dioxide Using Covalent Organic Framework/g-C3N4 Composites DOI

Bipasha Banerjee,

Pekham Chakrabortty,

Avik Chowdhury

и другие.

Industrial & Engineering Chemistry Research, Год журнала: 2024, Номер unknown

Опубликована: Дек. 2, 2024

A proficient heterogeneous catalytic system for the photocatalytic N-formylation reaction of amines and cyclic carbonate synthesis from epoxides using CO2 as a carbon source under ambient conditions has been documented. sophisticated approach established current process, aiming successful production formamides carbonates with high levels selectivity efficiency by adjusting several variables such solvent, time, well light involved in reaction. We have synthesized two distinct catalysts, T-COF N-COF, along g-C3N4 heterojunction, demonstrating outstanding performance. Compared to g-C3N4@N-COF, g-C3N4@T-COF photocatalyst showed significantly better light-driven formation other suitable at room temperature. The g-C3N4@COF photocatalysts can be recycled used multiple times without any noticeable decrease efficiency.

Язык: Английский

Metalated covalent organic frameworks: from synthetic strategies to diverse applications DOI
Qun Guan, Lele Zhou, Yu‐Bin Dong

и другие.

Chemical Society Reviews, Год журнала: 2022, Номер 51(15), С. 6307 - 6416

Опубликована: Янв. 1, 2022

This review highlights the recent advances of metalated covalent organic frameworks, including synthetic strategies and applications, discusses current challenges future directions.

Язык: Английский

Процитировано

221

A review on the advancements in covalent organic frameworks for photocatalytic reduction of carbon dioxide DOI Creative Commons
Chien Ing Yeo, Yee Seng Tan,

Hafiz Taimoor Ahmed Awan

и другие.

Coordination Chemistry Reviews, Год журнала: 2024, Номер 521, С. 216167 - 216167

Опубликована: Авг. 29, 2024

Язык: Английский

Процитировано

25

Experimental and kinetic evaluation on cobalt Salen conjugated organic polymers for CO2 cycloaddition reactions and iodine vapor adsorption DOI
Tingchun Zhu,

Shuangshuo Li,

Meiqi Sun

и другие.

Journal of Molecular Liquids, Год журнала: 2024, Номер 401, С. 124651 - 124651

Опубликована: Апрель 4, 2024

Язык: Английский

Процитировано

11

Polyoxometalates coupled covalent organic frameworks as highly active photothermal nanoreactor for CO2 cycloaddition DOI
Tian Wang, Yunqing Zhu, Wei Wang

и другие.

Nano Research, Год журнала: 2024, Номер 17(7), С. 5975 - 5984

Опубликована: Апрель 30, 2024

Язык: Английский

Процитировано

11

Recent trends in covalent organic frameworks (COFs) for carbon dioxide reduction DOI Creative Commons
Priyanka Sarkar, Ipsita Hazra Chowdhury,

Surya Shekhar Das

и другие.

Materials Advances, Год журнала: 2022, Номер 3(22), С. 8063 - 8080

Опубликована: Янв. 1, 2022

The review provides a concise report on various types of COFs, current trends, their application in CO 2 reduction via photochemical, electrochemical and photo coupled pathways.

Язык: Английский

Процитировано

33

Photothermal catalysis without solvent for fixing CO2 to cyclic carbonate DOI
Luping Zhang,

Xuewei Tu,

Yutong Chen

и другие.

Molecular Catalysis, Год журнала: 2023, Номер 538, С. 112971 - 112971

Опубликована: Фев. 10, 2023

Язык: Английский

Процитировано

19

Light-Mediated Sustainable Conversion of Carbon Dioxide to Valuable Methanol by Highly Efficient Covalent Organic Framework g-C3N4 Composites as a Reusable Photocatalyst DOI
Mainak Sarkar,

Pekham Chakrabortty,

Manideepa Sengupta

и другие.

Industrial & Engineering Chemistry Research, Год журнала: 2024, Номер 63(13), С. 5573 - 5590

Опубликована: Март 25, 2024

A novel triazine-based structured two-dimensional (2D) covalent organic framework (COF), known as TRITER-1, has been prepared through the Schiff-base condensation reaction between terephthalaldehyde and 1,3,5-tris(4-aminophenyl)triazine. Additionally, g-C3N4 incorporated within imine-based frameworks to produce composite TRITER-1@g-C3N4, which a relatively small band gap of 2.0 eV. This composite, called synthesized effectively used toward light-driven formation methanol from most greenhouse gas CO2. highly crystalline polymeric material demonstrated an outstanding photocatalytic activity. The active photocatalyst TRITER-1@g-C3N4 successfully reduces CO2 into under ambient conditions in presence NiO nanoparticles cocatalyst atmospheric pressure. visible-light-accelerated metal-free reduction by this COF accomplished 15 W white LED light illumination, with maximum turnover number (TON = 172, μmol 22 600). By varying intensity, it was clear that failed take place absence LED. We proved sunlight can also TON around 73 allow for sustainable reactions. catalyst retains its catalytic function after being regenerated multiple times is effective selective.

Язык: Английский

Процитировано

8

AgNPs supported over porous organic polymers for the fixation of CO2 on propargyl alcohols and amines under solvent-free conditions DOI
Amitesh Roy, Najirul Haque, R. Chatterjee

и другие.

New Journal of Chemistry, Год журнала: 2023, Номер 47(14), С. 6673 - 6684

Опубликована: Янв. 1, 2023

Silver nanoparticle embedded POP was synthesized and used as a heterogeneous catalyst for the synthesis of α-alkylidene cyclic carbonates acyclic carbamates via CO 2 fixation under mild conditions.

Язык: Английский

Процитировано

17

Covalent Immobilization of Quaternary Ammonium Salts on Covalent Organic Framework: Sustainable Intensification Strategy for the Synthesis of Cyclic Carbonates from CO2 DOI
Somnath Sarkar, Swarbhanu Ghosh,

Robius Sani

и другие.

ACS Sustainable Chemistry & Engineering, Год журнала: 2023, Номер 11(39), С. 14422 - 14434

Опубликована: Сен. 20, 2023

Sustainable metal-free catalytic conversion of carbon dioxide (CO2) via cycloaddition epoxides with CO2 has shown great promise but suffers from a lack recyclability because the homogeneous nature, limiting their use. Heterogeneous organocatalysts have gained immense attention in last decade superior application potential and important characteristics, they also play pivotal roles making environmentally friendly processes reality. Herein, we describe an unprecedented postsynthetic modification approach for efficient covalent immobilization quaternary ammonium salts to microporous organic framework (COF). More interestingly, no noticeable loss crystallinity occurred after (PSM) salt-decorated COF (MA-PDA IL@COF) consists only micropores (around 6–15 Å), which are smaller than most reported COF-based catalysts. Detailed investigations on chemical fixation reveal that ionic liquid-based is promising catalyst promote coupling under very mild conditions (metal-free/solvent-free/cocatalyst-free/additive-free 1 atm pressure). The displayed quantitative selectivity, more intriguingly, reaction high efficiency, broad scope, functional group tolerance without additives or cocatalysts. system can be recovered repeated use at least five times almost similar performance prerequisite industrial implementation.

Язык: Английский

Процитировано

15

Zinc incorporated covalent organic framework (Zn@DBPG): an efficient catalyst for the synthesis of carbamates through CO2 and non CO2 fixation pathways under sustainable condition DOI
Najirul Haque, Surajit Biswas, Malay Dolai

и другие.

Molecular Catalysis, Год журнала: 2023, Номер 536, С. 112900 - 112900

Опубликована: Янв. 3, 2023

Язык: Английский

Процитировано

12