Palladium‐Catalyzed 2‐Aminoacetophenone Oxime Directed β‐sp2 and γ‐sp3 C─H Bond Functionalization of Aryl Carboxamides DOI
Rathinam Sankar, Gnanasambandam Vasuki

ChemistrySelect, Год журнала: 2024, Номер 9(45)

Опубликована: Ноя. 26, 2024

Abstract Pd(II)‐catalyzed 2‐aminoacetophenone oxime‐assisted sp 2 and 3 C─H arylation of aryl carboxamides is disclosed. The oxime an N,N ‐bidentate auxiliary that proceeds activation through a six‐membered palladacycle intermediate, the activation/functionalization on C(sp )─H bond by ligand novel achieved. This facilitates subsequent in one step. optimized protocol enables access to various groups at β ‐sp ‐ γ ‐centers carboxamides. bidentate easy synthesize gram scale, we also described deoximination procedure after functionalization.

Язык: Английский

Cucurbit[6]uril supported β-Ni(OH)2 nanoparticles as a heterogeneous catalyst for the synthesis of quinazolines via acceptorless dehydrogenative coupling of alcohols with nitriles DOI

Shruti Verma,

Shelly Kujur,

Richa Sharma

и другие.

New Journal of Chemistry, Год журнала: 2022, Номер 46(44), С. 21356 - 21365

Опубликована: Янв. 1, 2022

Synthesis of a series quinazolines using β-Ni(OH) 2 -CB[6] as heterogeneous nanocatalyst.

Язык: Английский

Процитировано

7

Recent Advances in Nickel-Catalyzed C-C Cross-Coupling DOI
Yangyang Li, Jiao Long,

Guoyin Yin

и другие.

Topics in organometallic chemistry, Год журнала: 2023, Номер unknown, С. 181 - 231

Опубликована: Янв. 1, 2023

Язык: Английский

Процитировано

4

Visible light induced palladium catalyzed C H hydroxylation of nitrogen-containing heterocyclic aromatics in the presence of H2O2 DOI

Chaoyin He,

Xiaodong Fan,

Mengmeng Ji

и другие.

Tetrahedron Letters, Год журнала: 2022, Номер 112, С. 154225 - 154225

Опубликована: Ноя. 2, 2022

Язык: Английский

Процитировано

3

Palladium‐Catalyzed 2‐Aminoacetophenone Oxime Directed β‐sp2 and γ‐sp3 C─H Bond Functionalization of Aryl Carboxamides DOI
Rathinam Sankar, Gnanasambandam Vasuki

ChemistrySelect, Год журнала: 2024, Номер 9(45)

Опубликована: Ноя. 26, 2024

Abstract Pd(II)‐catalyzed 2‐aminoacetophenone oxime‐assisted sp 2 and 3 C─H arylation of aryl carboxamides is disclosed. The oxime an N,N ‐bidentate auxiliary that proceeds activation through a six‐membered palladacycle intermediate, the activation/functionalization on C(sp )─H bond by ligand novel achieved. This facilitates subsequent in one step. optimized protocol enables access to various groups at β ‐sp ‐ γ ‐centers carboxamides. bidentate easy synthesize gram scale, we also described deoximination procedure after functionalization.

Язык: Английский

Процитировано

0