Food Chemistry, Год журнала: 2023, Номер 439, С. 138147 - 138147
Опубликована: Дек. 6, 2023
Язык: Английский
Materials Horizons, Год журнала: 2023, Номер 10(10), С. 4083 - 4138
Опубликована: Янв. 1, 2023
Porous organic polymers show great potential for addressing environmental pollution challenges, including chemical sensing, wastewater treatment, toxic gas sorption, heterogeneous catalysis, and further promoting sustainable remediation strategies.
Язык: Английский
Процитировано
100
Bioactive Materials, Год журнала: 2022, Номер 21, С. 358 - 380
Опубликована: Сен. 14, 2022
Nanomedicines for drug delivery and imaging-guided cancer therapy is a rapidly growing research area. The unique properties of nanomedicines have massive potential in solving longstanding challenges existing drugs, such as poor localization at the tumor site, high doses toxicity, recurrence, immune response. However, inadequate biocompatibility restricts their clinical translation. Therefore, advanced nanomaterials with enhanced therapeutic efficiency are highly desired to fast-track translation nanomedicines. Intrinsic nanoscale covalent organic frameworks (nCOFs), suitable size, modular pore geometry porosity, straightforward post-synthetic modification via simple transformations, make them incredibly attractive future ability COFs disintegrate slightly acidic microenvironment also gives competitive advantage targeted delivery. This review summarizes recently published applications delivery, photo-immuno therapy, sonodynamic photothermal chemotherapy, pyroptosis, combination therapy. Herein we mainly focused on modifications enhance biocompatibility, efficacy will provide fundamental knowledge designing biocompatible nCOFs-based help rapid development carriers theranostics.
Язык: Английский
Процитировано
82
Journal of the American Chemical Society, Год журнала: 2023, Номер 145(13), С. 7408 - 7415
Опубликована: Март 17, 2023
Excited-state intramolecular proton transfer (ESIPT) has been widely employed for the design of a variety functionality-led molecular systems. However, precise manipulation excited-state reaction is challenging. Herein, we report new tactic tuning ESIPT via incorporating an charge (ESICT) process. Specifically, three o-carborane derivatives, NaCBO, PaCBO, and PyCBO, were designed, where 2-(2'-hydroxyphenyl)-benzothiazole typical unit functioning as electron acceptor, electron-donating units are naphthyl-(Na), phenanthrenyl-(Pa), pyrenyl-(Py), respectively. The architectures molecules featured with face-to-face alignment two units. Spectroscopy theoretical calculation studies revealed that capacity donors solvent polarity continuously modulate ESIPT/ESICT energetics dynamics, resulting in distinct emissions. Moreover, depicted not only highly porous structures but also very different fluorescent colors solid state, enabling selective film-based fluorescence sensing mustard gas simulant, 2-chloroethyl ethyl sulfide, detection limit 50 ppb response time 5 s. This work thus provides reliable strategy creation high-performance fluorophores manipulation.
Язык: Английский
Процитировано
73
Chemosphere, Год журнала: 2023, Номер 336, С. 139203 - 139203
Опубликована: Июнь 12, 2023
Язык: Английский
Процитировано
59
Chemical Society Reviews, Год журнала: 2024, Номер 53(5), С. 2530 - 2577
Опубликована: Янв. 1, 2024
This review emphasizes the crucial role of chemiresistive gas sensors (CGS) in detection. It underscores porous materials as alternatives, showcasing their exceptional attributes. The explores CGS-based real-life applications.
Язык: Английский
Процитировано
57
Journal of Polymer Science, Год журнала: 2023, Номер 62(8), С. 1517 - 1535
Опубликована: Авг. 2, 2023
Abstract Hyper‐crosslinked polymers (HCPs) are a family of that possess several desirable characteristics, including high specific surface area, excellent stability, tunable porous structures, and low‐cost reagents. As result, HCPs have gained significant attention in the areas gas storage, adsorption, catalysis, separation, carbon precursors, exhibiting advanced performances catalytic energy‐related applications. Recently, researchers explored potential biomedical engineering. In this review, we discuss classical synthesis strategies morphological assembly methods used to create with unique biological properties. We also highlight latest advances emerging HCPs, such as drug delivery, antimicrobial, bioimaging, biosensing. By providing various examples, further correlations between morphologies, enhanced properties HCPs. Finally, summarize key applications provide an outlook on research direction encourage development biomedically available Overall, offer promising new class materials for use applications, continued field will lead exciting discoveries breakthroughs.
Язык: Английский
Процитировано
56
European Polymer Journal, Год журнала: 2023, Номер 189, С. 111980 - 111980
Опубликована: Март 9, 2023
Язык: Английский
Процитировано
53
Chemical Society Reviews, Год журнала: 2023, Номер 52(19), С. 6644 - 6663
Опубликована: Янв. 1, 2023
A succinct and illustrative summary of the recent progress supramolecular smart organic materials based on macrocycle hosts is provided spanning aspects design principles, functioning mechanisms, relative applications.
Язык: Английский
Процитировано
53
ACS Catalysis, Год журнала: 2024, Номер 14(4), С. 2631 - 2641
Опубликована: Фев. 6, 2024
The direct application of low-energy red light for photochemical transformations is synthetically appealing but practically challenging. Covalent organic frameworks (COFs) exhibit significant potential within this domain, owing to their broad spectrum absorption and prevalence in reactions, despite the fact that these photocatalysts are now mainly focused on using ultraviolet (UV) blue light. In study, an imidazole-linked porphyrin-based COF, PyPor-COF, which exhibits a wide band ranging from 200 700 nm, especially strong 630 expected be applied photocatalytic reactions. PyPor-COF possesses capacity selectively generate singlet oxygen (1O2) with high efficiency, renders it efficient photosensitizer reactions olefin cleavages thioanisole photooxidation under present study demonstrates intriguing prospect photoactive COFs as type II utilization photocatalyses.
Язык: Английский
Процитировано
32
Coordination Chemistry Reviews, Год журнала: 2024, Номер 511, С. 215860 - 215860
Опубликована: Апрель 17, 2024
Язык: Английский
Процитировано
32