Chemosphere,
Год журнала:
2024,
Номер
358, С. 142129 - 142129
Опубликована: Апрель 26, 2024
Per-
and
polyfluoroalkyl
substances
(PFAS)
are
a
unique
class
of
chemicals
synthesized
to
aid
in
industrial
processes,
fire-fighting
products,
benefit
consumer
products
such
as
clothing,
cosmetics,
textiles,
carpets,
coatings.
The
widespread
use
PFAS
their
strong
carbon-fluorine
bonds
has
led
ubiquitous
presence
throughout
the
world.
Airborne
transport
atmosphere
also
contributed
environmental
pollution.
Due
potential
human
exposure
concerns
some
PFAS,
research
extensively
focused
on
water,
soil,
organismal
detection,
but
air
become
an
area
growing
concern.
Methods
measure
polar
various
matrices
have
been
established,
while
investigation
nonpolar
is
still
its
early
development.
This
literature
review
aims
present
last
two
decades
characterizing
outdoor
indoor
air,
focusing
active
passive
sampling
analytical
methods.
classes
targeted
detected
samples
include
fluorotelomer
alcohols
(FTOHs),
perfluoroalkane
sulfonamides
(FASAs),
sulfonamido
ethanols
(FASEs),
perfluorinated
carboxylic
acids
(PFCAs),
sulfonic
(PFSAs).
Although
manufacturing
perfluorooctanoic
acid
(PFOA)
perfluorooctane
(PFOS)
largely
phased
out,
these
often
samples.
Additionally,
recent
estimates
indicate
that
there
thousands
likely
not
currently
monitored
Advances
methods
needed
fully
characterize
atmospheric
PFAS.
Reviews of Geophysics,
Год журнала:
2022,
Номер
60(3)
Опубликована: Авг. 7, 2022
Abstract
Per‐
and
polyfluoroalkyl
substances
(PFASs),
also
known
as
“forever
chemicals,”
are
manmade
chemicals
that
have
been
increasingly
detected
in
various
geological
settings
since
the
early
2000s.
The
soil
subsurface
environments
media
commonly
affected
by
PFAS.
We
conducted
a
comprehensive
review
of
peer‐reviewed
articles
published
from
2010
through
2022
concerning
fate
transport
PFAS
environments.
This
is
organized
into
different
subsections,
covering
basics
properties
how
they
affect
occurrence,
fate,
PFAS,
fundamental
processes
affecting
mathematical
models
for
describing
predicting
behaviors.
Mechanisms
governing
environment,
including
sorption
at
air‐water
interface,
solid‐water
nonaqueous
phase
liquids‐water
were
explored
detail.
Challenges
future
research
priorities
identified
to
better
mitigate
global
challenges
contamination.
Abstract
Per-
and
polyfluoroalkyl
substances
(PFASs),
commonly
known
as
‘‘forever
chemicals’’,
are
persistent
organic
pollutants
that
widely
distributed
in
the
environment.
Due
to
their
toxicity
resistance
degradation,
PFASs
classified
emerging
contaminants,
increasing
attention
is
being
paid
remediation.
Biochar,
an
environmentally
friendly
cost-effective
adsorbent,
shows
potential
for
remediating
contamination.
The
application
of
biochar
remediation
has
garnered
growing
interest.
Compared
other
adsorbents,
more
economical
raw
materials
its
preparation
readily
available.
However,
there
currently
no
comprehensive
review
summarizing
effects
on
environmental
behavior
PFASs.
This
aims
fill
gap
by
providing
in-depth
discussion
synthesis
existing
literature
this
area.
It
focuses
PFASs,
specifically
addressing
adsorption
mechanisms
factors
influencing
effectiveness
A
proposed
mechanism
which
photodegrades
through
generation
free
radicals,
addition
conventional
(such
pore
filling,
hydrogen
bonding,
hydrophobic
interactions,
electrostatic
interactions),
explored.
Furthermore,
discusses
ability
reduce
likelihood
entering
food
chain
water
soil
evaluates
feasibility
limitations
using
removal.
Finally,
we
identify
future
research
directions
support
safe
effective
use
remediation,
so
promote
advancement
green
technologies.
Graphic
Environmental Science & Technology,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 21, 2025
Per-
and
polyfluoroalkyl
substances
(PFAS)─so-called
"forever
chemicals"─contaminate
the
drinking
water
of
about
100
million
people
in
U.S.
alone
are
inefficiently
removed
by
standard
treatment
techniques.
A
key
property
these
compounds
that
underlies
their
fate
transport
efficacy
several
promising
remediation
approaches
is
they
accumulate
at
water–air
interface.
This
phenomenon
remains
incompletely
understood,
particularly
under
conditions
relevant
to
natural
systems
where
interfaces
often
carry
significant
loads
other
organic
contaminants
or
matter.
To
understand
impact
loading
on
PFAS
adsorption,
we
carried
out
molecular
dynamics
simulations
varying
interfacial
densities.
We
find
adsorbed
form
strong
mutual
interactions
(attraction
between
perfluoroalkyl
chains
electrostatic
among
charged
head
groups)
give
rise
ordered
coatings.
These
involve
near-cancellation
hydrophobic
attraction
Coulomb
repulsion.
Our
findings
explain
an
apparent
paradox
whereby
adsorption
isotherms
suggest
minimal
while
simultaneously
displaying
a
high
sensitivity
composition
density
Consideration
present
with
interface
has
potential
allow
for
more
accurate
predictions
design
efficient
approaches.
Environmental Science Advances,
Год журнала:
2023,
Номер
2(8), С. 1019 - 1041
Опубликована: Янв. 1, 2023
Biotransformation
of
per-
and
polyfluoroalkyl
substances
(PFAS)
has
received
growing
attention
as
more
research
becomes
available
indicating
that
bioremediation
may
have
a
future
role
to
play
in
addressing
PFAS
contamination.
Environmental Pollution,
Год журнала:
2024,
Номер
346, С. 123575 - 123575
Опубликована: Фев. 14, 2024
We
have
investigated
the
occurrence,
distribution,
and
biomagnification
of
per-
polyfluoroalkyl
substances
(PFAS)
in
two
tropical
lakes
(Asejire
Eleyele)
Southwestern
Nigeria,
with
contrasting
urban
intensities.
Over
an
8-month
period,
we
sampled
sediment
fish
species
(Clarias
gariepinus:
CIG;
Oreochromis
niloticus:
ON;
Coptodon
guineensis:
CG;
Sarotherodon
melanotheron:
SM)
across
trophic
levels,
analyzed
various
PFAS
congeners,
addition
to
a
select
group
toxicological
responses.
While
herbivores
(SM)
benthic
omnivores
(CIG)
at
Asejire
exhibited
elevated
levels
PFBS
PFOS,
pelagic
(ON)
showed
dominance
PFDA,
PFHxDA
EtFOSE
muscle.
At
Eleyele
lake,
patterns
was
dominated
by
PFBS,
EtFOSE,
PFPeS,
PFOcDA
PFOS
(SM,
CG),
omnivore
(ClG).
The
estimated
factor
(BMF)
analysis
for
both
indicated
level
increase
PFUnA
PFDA
suburban
while
biomagnified
lake.
detected
occurrence
diSAMPAP
9CL-PF3ONS,
novel
compounds
not
commonly
reported,
studies
lakes.
studied
responses
varied
groups
probable
modulations
environmental
conditions,
structure,
relative
exposures
present
study
documents,
first
time
or
any
other
African
country,
role
urbanization
on
contaminant
load
into
environment
their
implications
dynamics
within
ecosystem
aquatic
food
safety.
Applied and Environmental Microbiology,
Год журнала:
2024,
Номер
90(4)
Опубликована: Март 17, 2024
ABSTRACT
Per-
and
polyfluoroalkyl
substances
(PFAS)
are
highly
fluorinated
synthetic
organic
compounds
that
have
been
used
extensively
in
various
industries
owing
to
their
unique
properties.
The
PFAS
family
encompasses
diverse
classes,
with
only
a
fraction
being
commercially
relevant.
These
found
the
environment,
including
water
sources,
soil,
wildlife,
leading
human
exposure
fueling
concerns
about
potential
health
impacts.
Although
degradation
is
challenging,
biodegradation
offers
promising,
eco-friendly
solution.
Biodegradation
has
effective
for
variety
of
contaminants
but
yet
be
successful
due
paucity
identified
microbial
species
capable
transforming
these
compounds.
Recent
studies
investigated
biotransformation
fluoride
release;
however,
number
specific
microorganisms
enzymes
demonstrable
activity
remains
limited.
This
review
discusses
could
metabolism,
haloacid
dehalogenases,
reductive
cytochromes
P450,
alkane
butane
monooxygenases,
peroxidases,
laccases,
desulfonases,
mechanisms
resistance
intracellular
fluoride.
Finally,
we
emphasize
enzyme
engineering
advance
strategies
provide
insights
future
research
this
field.
Environmental Science & Technology,
Год журнала:
2024,
Номер
58(21), С. 9303 - 9313
Опубликована: Май 16, 2024
As
part
of
the
Integrated
Atmospheric
Deposition
Network,
precipitation
(n
=
207)
and
air
60)
from
five
sites
water
samples
87)
all
Great
Lakes
were
collected
in
2021–2023
analyzed
for
41
per-
polyfluoroalkyl
substances
(PFAS).
These
measurements
combined
with
other
available
data
to
estimate
mass
budget
four
representative
compounds,
PFBA,
PFBS,
PFOS,
PFOA
basin.
The
median
Σ41PFAS
concentrations
across
ranged
between
2.4
4.5
ng/L.
concentration
lake
was
highest
Lake
Ontario
(11
ng/L)
lowest
Superior
(1.3
ng/L).
Cleveland
at
410
pg/m3
Sleeping
Bear
Dunes
146
pg/m3.
net
transfer
flows
generally
negative
Superior,
Michigan,
Huron
positive
Erie
Ontario,
indicating
that
three
most
northern
lakes
are
accumulating
PFAS
two
eliminating
PFAS.
deposition
is
an
important
source
PFAS,
particularly
Superior.
Chemical Engineering Journal,
Год журнала:
2024,
Номер
493, С. 152537 - 152537
Опубликована: Май 24, 2024
Biosolids
(stabilised
sewage
sludge)
are
the
final
solid
residues
of
wastewater
treatment
process
and
generally
applied
on
agricultural
land
in
many
countries,
including
Australia.
Per-
polyfluoroalkyl
substances
(PFAS)
a
group
synthetic
fluorinated
chemicals
with
ubiquitous
applications
consumer
products
persist
environment.
Globally,
PFAS
have
been
detected
biosolids
considered
source
discharge
to
The
thermal
is
gaining
increasing
interest
water
sector.
Therefore,
viability
techniques
for
safe
destruction
has
received
substantial
research
attention
last
few
years.
Recent
studies
suggest
that
can
be
removed
potentially
destroyed
during
combustive
(such
as
incineration)
non-combustive
treatment,
such
pyrolysis,
gasification,
hydrothermal
carbonisation/liquefaction.
However,
there
limited
understanding
fate
transformation
degradation
across
overall
from
feed
pre-treatment
gas
cleaning
(post-thermal
treatment)
stage.
This
review
consolidates
current
knowledge
transformation,
destruction,
before,
during,
after
biosolids,
covering
lab,
pilot
scale,
industrial
studies.
It
suggested
mechanisms
may
differ
established
pathways
pure
salts,
given
complex
organic
inorganic
matrix
typically
low
concentrations.
Among
all
techniques,
pyrolysis
extensive
investigations
at
different
scales
operation.
temperatures
residence
time
need
sufficiently
optimised
designing
realistic
large-scale
systems
relevant
biosolids'
compositional
peculiarities
destruction.