Green Chemistry,
Год журнала:
2024,
Номер
26(13), С. 7552 - 7578
Опубликована: Янв. 1, 2024
In
this
review,
we
present
a
comprehensive
strategies
for
overcoming
hurdles
to
store
hydrogen
and
natural
gas
in
the
clathrate
hydrate
media
under
static
system.
ACS Nano,
Год журнала:
2024,
Номер
18(31), С. 20201 - 20212
Опубликована: Июль 30, 2024
Assembly
of
different
metal-organic
frameworks
(MOFs)
into
hybrid
MOF-on-MOF
heterostructures
has
been
established
as
a
promising
approach
to
develop
synergistic
performances
for
variety
applications.
Here,
we
explore
the
performance
heterostructure
by
epitaxial
growth
MIL-88B(Fe)
onto
UiO-66(Zr)-NH2
nanoparticles.
The
face-selective
design
and
appropriate
energy
band
structure
alignment
selected
MOF
constituents
have
permitted
its
application
an
active
heterogeneous
photocatalyst
solar-driven
water
splitting.
composite
achieves
apparent
quantum
yields
photocatalytic
overall
splitting
at
400
450
nm
about
0.9%,
values
that
compare
much
favorably
with
previous
analogous
reports.
Understanding
this
high
activity
gained
spectroscopic
electrochemical
characterization
together
scanning
transmission
electron
microscopy
(STEM,
TEM)
measurements.
This
study
exemplifies
possibility
developing
operates
under
Z-scheme
mechanism
exhibits
outstanding
toward
solar
light.
Applied Physics Reviews,
Год журнала:
2025,
Номер
12(1)
Опубликована: Янв. 10, 2025
Scaling
up
photocatalytic
systems
for
large-scale
hydrogen
generation
holds
transformative
potential
sustainable
energy
but
faces
significant
technical
and
economic
challenges
in
transitioning
from
lab-scale
experiments
to
industrial
applications.
This
review
delves
into
recent
innovations
that
drive
progress
this
field,
including
advanced
materials
developed
improved
efficiency
stability,
as
well
innovative
reactor
designs
optimize
light
capture
reactant
flow.
It
also
examines
practical
strategies
the
integration
of
these
with
renewable
sources,
focusing
on
their
scalability
cost-effectiveness.
Key
addressed
include
mass
transport
limitations,
utilization,
catalyst
longevity,
accompanied
by
emerging
solutions
aim
overcome
hurdles.
The
comprehensively
explores
intersection
technological
advancements
feasibility,
emphasizing
environmental
considerations
necessary
implementation
production.
Emphasizing
most
developments
strategic
approaches,
outlines
a
pathway
advancing
technologies.
Advanced Energy Materials,
Год журнала:
2024,
Номер
14(11)
Опубликована: Янв. 28, 2024
Abstract
Bias‐free
solar
water‐splitting
technology
is
considered
an
ideal
solution
to
address
the
energy
crisis,
as
it
can
efficiently
convert
hydrogen
and
has
made
groundbreaking
progress.
Particularly,
photovoltaic
(PV)‐driven
electrolysis
systems
exhibit
promising
potential
for
enhanced
conversion
efficiency.
Nonetheless,
majority
of
research
on
PV‐driven
remains
confined
laboratory
scale,
with
industrial‐scale
application
still
in
nascent
stages.
This
review
comprehensively
explores
pivotal
factors
required
practically
apply
bias‐free
electrochemical
water
splitting
current
research.
It
delves
into
fundamental
principles
involved
components,
configuration
structure
varied
integration
degree
systems,
differences
composition
level
devices,
system
reaction
environment
electrolytic
system,
strategy
development
refinement
electrocatalysts.
Furthermore,
offers
a
perspective
analysis
future
trajectories
each
component.
work
aims
shed
light
scientific
hurdles
exploration
prospects
faced
by
field
process
becoming
practical.