Selective Synthesis of 3-Selenoindoles via Selenation of Indoles under Catalyst-Free Condition
Chinese Journal of Organic Chemistry,
Год журнала:
2025,
Номер
45(1), С. 349 - 349
Опубликована: Янв. 1, 2025
Язык: Английский
A sustainable approach for the bis-selenylation of alkynes: Design, synthesis and mechanistic studies
Tetrahedron Letters,
Год журнала:
2025,
Номер
unknown, С. 155504 - 155504
Опубликована: Фев. 1, 2025
Язык: Английский
Direct C-H Selenylation of (Benz)Imidazole and related heterocycles via Cooperative Action of Palladium and Silver Catalyst
Tetrahedron,
Год журнала:
2025,
Номер
unknown, С. 134667 - 134667
Опубликована: Апрель 1, 2025
Язык: Английский
Selenium Modification of Natural Products and Its Research Progress
Foods,
Год журнала:
2023,
Номер
12(20), С. 3773 - 3773
Опубликована: Окт. 13, 2023
The
selenization
of
natural
products
refers
to
the
chemical
modification
method
artificially
introducing
selenium
atoms
into
interact
with
functional
groups
in
target
molecule
form
selenides.
Nowadays,
even
though
scientists
fields
involving
organic
compounds
have
achieved
numerous
results
due
their
continuous
investment,
few
comprehensive
and
systematic
summaries
relating
research
can
be
found.
present
paper
summarizes
methods
several
kinds
important
products,
such
as
polysaccharides,
proteins/polypeptides,
polyphenols,
lipids,
cyclic
compounds,
well
basic
principles
or
mechanisms
selenizing
methods.
On
this
basis,
explored
future
development
trend
field
selenized
it
is
hoped
provide
some
suggestions
for
directional
application
active
ingredients.
Язык: Английский
Iodine/Oxone® oxidative system for the Synthesis of Selenylindoles Bearing Benzenesulfonamide Moiety as Carbonic Anhydrase I, II, IX, and XII Inhibitors
Organic & Biomolecular Chemistry,
Год журнала:
2024,
Номер
22(32), С. 6532 - 6542
Опубликована: Янв. 1, 2024
A
wide
range
of
3-selenylindoles
were
synthesized
Язык: Английский
Synthesis of 3-chalcogenyl-indoles mediated by the safer reagent urea-hydrogen peroxide (UHP)
Tetrahedron Letters,
Год журнала:
2023,
Номер
120, С. 154446 - 154446
Опубликована: Март 16, 2023
Язык: Английский
Benzeneseleninic Acids (BSA) and Photocatalysis: An Alternative Duo for the Synthesis of 3‐Selanylindoles
Gabriela T. Quadros,
Savana P. de Medeiros,
Carolina A. de Oliveira
и другие.
Asian Journal of Organic Chemistry,
Год журнала:
2023,
Номер
12(12)
Опубликована: Ноя. 14, 2023
Abstract
A
novel
eco‐friendly
methodology
for
the
synthesis
of
3‐selanylindoles
has
been
established,
circumventing
requirement
transition
metal
catalysis,
strong
oxidants
and
elevated
reaction
temperatures.
In
present
protocol
a
photocatalytic
strategy
was
elegantly
developed
use
benzeneseleninic
acid
(BSA)
derivatives
as
selenium‐source
reagent,
reacting
with
indole
derivatives,
to
access
in
moderate
good
yields.
total
fourteen
were
selectively
prepared,
which
among
three
are
unprecedented.
addition
synthetic
advantages,
this
study
gives
significant
insights
into
BSA
reagent
construct
Se(II)‐decorated
products.
Язык: Английский
Selective Synthesis of 3‐Chalcogenylindoles via Silver‐Catalyzed Direct Chalcogenation of Indoles with Dichalcogenides
ChemistrySelect,
Год журнала:
2023,
Номер
8(29)
Опубликована: Авг. 2, 2023
Abstract
An
efficient
and
convenient
strategy
for
selective
synthesis
of
3‐selenyl
3‐sulfenyl
indoles
was
developed
using
silver(I)nitrate
as
catalyst
under
aerobic
mild
reaction
conditions.
This
approach
is
scalable,
economical
eco‐friendly
furnishing
the
corresponding
in
good
to
high
yields
a
short
time.
Язык: Английский
Bismuth(III)-Catalyzed Regioselective Selenation of Indoles with Diaryl Diselenides: Synthesis of 3-Selanylindoles
Molecules,
Год журнала:
2024,
Номер
29(13), С. 3227 - 3227
Опубликована: Июль 8, 2024
Heterocyclic
aryl
selenides
have
recently
attracted
considerable
research
interest
owing
to
their
applications
in
biological
and
pharmaceutical
fields.
Herein,
we
describe
a
simple
general
synthesis
of
3-selanylindoles
via
novel
regioselective
C–H
selenation
indoles
using
bismuth
reagent
as
catalyst.
The
reactions
with
diselenides
the
presence
10
mol%
BiI3
at
100
°C
DMF
afforded
corresponding
moderate-to-excellent
yields.
reaction
proceeded
efficiently
under
aerobic
conditions
by
adding
only
catalytic
amount
BiI3,
which
was
non-hygroscopic
less
toxic,
both
selanyl
groups
diselenide
were
transferred
desired
products.
Язык: Английский
Synthesis of Selenium-Decorated N-Oxide Isoquinolines: Arylseleninic Acids in Selenocyclization Reactions
The Journal of Organic Chemistry,
Год журнала:
2024,
Номер
89(16), С. 11272 - 11280
Опубликована: Авг. 1, 2024
Herein,
we
describe
the
use
of
benzeneseleninic
acid
derivatives
(BSA)
as
a
bench-stable
and
easy
to
handle
selenium
reagent
access
4-(selanyl)isoquinoline-
Язык: Английский