Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy, Год журнала: 2024, Номер 330, С. 125664 - 125664
Опубликована: Дек. 25, 2024
Язык: Английский
Analytical Chemistry, Год журнала: 2024, Номер 96(20), С. 8036 - 8055
Опубликована: Май 10, 2024
ADVERTISEMENT RETURN TO ARTICLES ASAPPREVReviewNEXTRecent Developments in Single-Entity ElectrochemistryL. ZhangL. ZhangDepartment of Chemistry, Texas A&M University, College Station, 77845, United StatesMore by L. ZhangView Biography, O. J. WahabO. WahabDepartment WahabView Biographyhttps://orcid.org/0000-0003-4280-9089, A. JallowA. JallowDepartment JallowView Biographyhttps://orcid.org/0000-0003-2173-4137, Z. O'DellZ. O'DellDepartment Temple Philadelphia, Pennsylvania 19122, O'DellView Biographyhttps://orcid.org/0000-0002-7779-596X, T. PungsrisaiT. PungsrisaiDepartment PungsrisaiView S. SridharS. SridharDepartment SridharView Biographyhttps://orcid.org/0000-0003-3379-1630, K. VernonK. VernonDepartment VernonView Willets*K. WilletsDepartment States*Email: [email protected]More WilletsView Biographyhttps://orcid.org/0000-0002-1417-4656, and Baker*L. BakerDepartment BakerView Biographyhttps://orcid.org/0000-0001-5127-507XCite this: Anal. Chem. 2024, XXXX, XXX, XXX-XXXPublication Date (Web):May 10, 2024Publication History Published online10 May 2024https://doi.org/10.1021/acs.analchem.4c01406© 2024 The Authors. American Chemical Society. This publication is licensed under CC-BY 4.0. License Summary*You are free to share (copy redistribute) this article any medium or format adapt (remix, transform, build upon) the material for purpose, even commercially within parameters below:Creative Commons (CC): a Creative license.Attribution (BY): Credit must be given creator.View full license*DisclaimerThis summary highlights only some key features terms actual license. It not license has no legal value. Carefully review before using these materials. Open Access indicated. Learn MoreArticle Views-Altmetric-Citations-LEARN ABOUT THESE METRICSArticle Views COUNTER-compliant sum text downloads since November 2008 (both PDF HTML) across all institutions individuals. These metrics regularly updated reflect usage leading up last few days.Citations number other articles citing article, calculated Crossref daily. Find more information about citation counts.The Altmetric Attention Score quantitative measure attention that research received online. Clicking on donut icon will load page at altmetric.com with additional details score social media presence article. how calculated. Share Add toView InAdd Full Text ReferenceAdd Description ExportRISCitationCitation abstractCitation referencesMore Options onFacebookTwitterWechatLinked InRedditEmail (7 MB) Get e-AlertscloseSUBJECTS:Collisions,Electrodes,Metal nanoparticles,Nanoparticles,Nanopores e-Alerts
Язык: Английский
Процитировано
18
Chemical Society Reviews, Год журнала: 2024, Номер unknown
Опубликована: Дек. 23, 2024
This review comprehensively presents the fifty-year journey of surface-enhanced Raman spectroscopy (SERS), covering its discovery, pivotal phases, innovative methods, and key inspirations from pioneers trailblazers.
Язык: Английский
Процитировано
13
Journal of Solid State Electrochemistry, Год журнала: 2025, Номер unknown
Опубликована: Фев. 8, 2025
Язык: Английский
Процитировано
0
Small Methods, Год журнала: 2025, Номер unknown
Опубликована: Фев. 11, 2025
Abstract In situ monitoring of short‐lived transition states (TSs) is crucial for understanding electrochemical reaction mechanisms but remains challenging. Conventional surface‐enhanced Raman spectroscopy (EC‐SERS) primarily provides vibrational information, with limitations in hotspot reproducibility and often overlooking electronic information associated TSs. This study introduces a dual‐channel EC‐SERS strategy using nanolaminate nano‐optoelectrode (NLNOE) devices, integrating plasmon‐enhanced scattering (PE‐VRS) (PE‐ERS) to concurrently probe TS dynamics within electrically connected plasmonic nanocavities. Using the AgCl ( s ) + e − ⇌ Ag Cl aq redox system, this approach distinct PE‐VRS PE‐ERS signatures (AgCl) * TS. Notably, significant increase signals concurrent emergence, characterized by filled bonding unoccupied antibonding orbitals negligible energy gaps. enhanced signal correlates increased polarizability, leading amplified due electron cloud distortion. By modulating Cl⁻ ion concentrations via electrolyte composition (1× PBS 1× PBS‐equivalent KH₂PO₄) while maintaining constant total concentration, competition between Ag/AgCl Ag/AgH₂PO₄ reactions nanolayers influenced. These results demonstrate capability distinguish interfacial based on covalent ionic bond characteristics.
Язык: Английский
Процитировано
0
Current Opinion in Electrochemistry, Год журнала: 2025, Номер unknown, С. 101672 - 101672
Опубликована: Фев. 1, 2025
Язык: Английский
Процитировано
0
Journal of Energy Chemistry, Год журнала: 2025, Номер unknown
Опубликована: Март 1, 2025
Язык: Английский
Процитировано
0
Current Opinion in Electrochemistry, Год журнала: 2025, Номер unknown, С. 101692 - 101692
Опубликована: Апрель 1, 2025
Язык: Английский
Процитировано
0
The Journal of Physical Chemistry C, Год журнала: 2024, Номер unknown
Опубликована: Ноя. 25, 2024
Nonaqueous lithium-based batteries have become a dominating stream of modern energy storage systems. Understanding the physicochemical processes and mechanisms electrode evolution interfacial reactions in lithium is highly desired to further improve their capabilities. Compared with ex situ testing techniques, situ/operando spectroscopic techniques are significant importance battery research because they can provide more dynamic transient information under working conditions. Herein, this review we systematically introduce various for development nonaqueous Li batteries, including infrared (IR) spectroscopy, Raman scattering (Raman) nuclear magnetic resonance (NMR) sum frequency generation vibrational spectroscopy (SFG-VS) X-ray absorption (XAS). The recent advances these especially applications studying materials electrode–electrolyte interphases, been comprehensively summarized. Finally, propose future potential research.
Язык: Английский
Процитировано
3
The Journal of Physical Chemistry C, Год журнала: 2024, Номер 128(41), С. 17219 - 17239
Опубликована: Окт. 7, 2024
Proton exchange membrane water electrolysis (PEMWE) is a promising technology for sustainable hydrogen production. However, the anodic oxygen evolution reaction (OER) critical bottleneck restricting power-to-gas efficiency and widespread application of PEMWE devices because harsh acidic oxidative environment causes drastic catalyst structural thus severe dissolution/corrosion as well performance degradation. Currently, lack deep insight identifying real catalytic sites during distinctions mechanisms have hindered development highly active durable OER catalysts PEMWE. Therefore, elucidating OER-induced structure understanding underlying are recognized foundations technology. Against this backdrop, in situ spectroscopic characterization techniques serve powerful tools achieving goal by enabling real-time monitoring capture key intermediates. This Account summarizes recent advances cutting-edge spectroscopy probing process. The fundamentals device configurations these briefly introduced, advantages each technique intermediates to unveil also been discussed. Finally, challenges, trends, prospects field presented.
Язык: Английский
Процитировано
2
Microchimica Acta, Год журнала: 2024, Номер 191(11)
Опубликована: Окт. 7, 2024
Язык: Английский
Процитировано
2