Structure–property–performance relationship of vanadium- and manganese-based metal–organic frameworks and their derivatives for energy storage and conversion applications

Journal of Materials Chemistry A, Год журнала: 2024, Номер 12(19), С. 11149 - 11175

Опубликована: Янв. 1, 2024

The current review discusses on vanadium- and manganese-based metal–organic frameworks their derivatives for energy storage conversion applications along with the potential future advancements in these fields.

Язык: Английский

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Building robust metal-organic frameworks with premade ligands

Coordination Chemistry Reviews, Год журнала: 2024, Номер 505, С. 215690 - 215690

Опубликована: Фев. 1, 2024

Язык: Английский

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Metal-based nanomaterials with enzyme-like characteristics for bacterial rapid detection and control

Coordination Chemistry Reviews, Год журнала: 2024, Номер 510, С. 215799 - 215799

Опубликована: Апрель 1, 2024

Язык: Английский

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Harmonizing Enzyme‐like Cofactors to Boost Nanozyme Catalysis

Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(11)

Опубликована: Янв. 10, 2024

Engineering isolated metal sites resembling the primary coordination sphere of metallocofactors enables atomically dispersed materials as promising nanozymes. However, most existing nanozymes primarily focus on replicating specific while neglecting other supporting cofactors within active pockets, leading to reduced electron transfer (ET) efficiency and thus inferior catalytic performances. Herein, we report a metal-organic framework UiO-67 nanozyme with iron sites, which involves multiple tailored enzyme-like nanocofactors that synergistically drive ET process for enhanced peroxidase-like catalysis. Among them, linker-coupled atomic site plays critical role in substrate activation, bare linkers zirconia nodes facilitate intermediates. The synergy three results 4.29-fold enhancement compared single effort site-based nanocofactor, holding promise immunoassay sensitive detection chlorpyrifos. This finding opens new way designing high-performance by harmonizing various at molecular scale.

Язык: Английский

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Introducing Hydrogen-Bonding Microenvironment in Close Proximity to Single-Atom Sites for Boosting Photocatalytic Hydrogen Production

Journal of the American Chemical Society, Год журнала: 2024, Номер 146(29), С. 20391 - 20400

Опубликована: Июль 10, 2024

Inspired by enzymatic catalysis, it is crucial to construct hydrogen-bonding-rich microenvironment around catalytic sites; unfortunately, its precise construction and understanding how the distance between such sites affects catalysis remain significantly challenging. In this work, a series of metal-organic framework (MOF)-based single-atom Ru

Язык: Английский

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Smart Nano-Hybrid Metal-Organic Frameworks: Revolutionizing Advancements, Applications, and Challenges in Biomedical Therapeutics and Diagnostics

Hybrid Advances, Год журнала: 2025, Номер unknown, С. 100406 - 100406

Опубликована: Фев. 1, 2025

Язык: Английский

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Multi-Enzyme Cascade Nanoreactors for High-Throughput Immunoassay: Transitioning Concept in Lab to Application in Community

Analytical Chemistry, Год журнала: 2024, Номер 96(28), С. 11463 - 11471

Опубликована: Июль 4, 2024

In this work, we reported a cholesterol oxidase (Chox)-loaded platinum (Pt) nanozyme with the collaborative cascade nanoreactor for construction of nanozyme-enzyme-linked immunosorbent assay (N-ELSA) models to realize high-throughput rapid evaluation cancer markers. Considering high specific surface area and manipulable sites, ZIF-8 was used as substrate natural enzyme loading. The constructed ZIF-8-Pt platform exhibited efficient enzyme-like catalytic efficiency standard corrected activity 60.59 U mg

Язык: Английский

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Metal-organic framework-based biosensing platforms for diagnosis of bacteria-induced infectious diseases

TrAC Trends in Analytical Chemistry, Год журнала: 2024, Номер 175, С. 117707 - 117707

Опубликована: Апрель 15, 2024

Язык: Английский

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Photoluminescent organic crystals and co-crystals

Journal of Materials Chemistry C, Год журнала: 2024, Номер 12(27), С. 9888 - 9913

Опубликована: Янв. 1, 2024

This perspective highlights the significance of crystal engineering intervention in design and development applied optical materials.

Язык: Английский

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The promise of chiral electrocatalysis for efficient and sustainable energy conversion and storage: a comprehensive review of the CISS effect and future directions

Chemical Society Reviews, Год журнала: 2024, Номер 53(18), С. 9029 - 9058

Опубликована: Янв. 1, 2024

The integration of chirality, specifically through the chirality-induced spin selectivity (CISS) effect, into electrocatalytic processes represents a pioneering approach for enhancing efficiency energy conversion and storage systems. This review delves burgeoning field chiral electrocatalysis, elucidating fundamental principles, historical development, theoretical underpinnings, practical applications CISS effect across spectrum reactions, including oxygen evolution reaction (OER), reduction (ORR), hydrogen (HER). We explore methodological advancements in inducing structural surface engineering discuss various techniques its measurement, from magnetic conductive atomic force microscopy (mc-AFM) to peroxide titration. Furthermore, this highlights transformative potential addressing key challenges NRR CO

Язык: Английский

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