Separation and Purification Technology, Год журнала: 2025, Номер 367, С. 132843 - 132843
Опубликована: Апрель 8, 2025
Язык: Английский
Separation and Purification Technology, Год журнала: 2025, Номер 367, С. 132843 - 132843
Опубликована: Апрель 8, 2025
Язык: Английский
Inorganic Chemistry Communications, Год журнала: 2025, Номер unknown, С. 114266 - 114266
Опубликована: Март 1, 2025
Язык: Английский
Процитировано
1Advanced Healthcare Materials, Год журнала: 2024, Номер unknown
Опубликована: Окт. 10, 2024
Over the past two decades, iron-based metal-organic frameworks (Fe-MOFs) have attracted significant research interest in biomedicine due to their low toxicity, tunable degradability, substantial drug loading capacity, versatile structures, and multimodal functionalities. Despite great potential, transition of Fe-MOFs-based composites from laboratory clinical products remains challenging. This review evaluates key properties that distinguish Fe-MOFs other MOFs highlights recent advances synthesis routes, surface engineering, shaping technologies. In particular, it focuses on applications biosensing, antimicrobial, anticancer therapies. addition, emphasizes need develop scalable, environmentally friendly, cost-effective production methods for additional meet specific requirements various biomedical applications. ability combine therapies, hurdles still remain, including a deeper understanding therapeutic mechanisms potential risks resistance overdose. Systematically addressing these challenges could significantly enhance prospects potentially facilitate integration into mainstream practice.
Язык: Английский
Процитировано
6Chemical Engineering Journal, Год журнала: 2024, Номер unknown, С. 156837 - 156837
Опубликована: Окт. 1, 2024
Язык: Английский
Процитировано
4Small Methods, Год журнала: 2024, Номер unknown
Опубликована: Ноя. 30, 2024
Abstract Metal–organic frameworks (MOFs) are highly studied for solar H 2 production from O due to their abundant active sites and open pore channels. Titanium (Ti) Zirconium (Zr) MOFs particularly noted stability optoelectronic properties, resembling conventional metal oxide semiconductors. These allow molecular‐level tuning alter creating opportunities enhance catalytic activity. Introducing defects in the MOF's structure is a versatile strategy modifying molecular topology, morphology, optical electronic properties. This review compiles essential methods synthesizing defect‐oriented MOFs, discussing characterization techniques structural modifications boost It also highlights connection between photocatalytic MOF exploring strategies address current limitations using defective Ti Zr‐based MOFs. Additionally, role of machine learning (ML) predicting properties faster material discovery optimization emphasized. aims identify challenges propose ideas designing future photocatalysts.
Язык: Английский
Процитировано
4Coordination Chemistry Reviews, Год журнала: 2024, Номер 526, С. 216356 - 216356
Опубликована: Дек. 9, 2024
Язык: Английский
Процитировано
4Accounts of Chemical Research, Год журнала: 2024, Номер unknown
Опубликована: Ноя. 28, 2024
ConspectusEnzymes are highly efficient and selective catalysts that operate under mild conditions, making them invaluable for various chemical transformations. However, their limitations, such as instability high cost, call advancements in enzyme immobilization the development of suitable host materials. Metal-organic frameworks (MOFs), characterized by porosity, crystallinity, tunability, promising candidates encapsulation. Among these, zirconium-based MOFs (Zr-MOFs) stand out due to exceptional structural diversity stability. The physical properties Zr-MOFs can be tuned with atomic precision, interactions enzymes analyzed through a range techniques spanning from chemistry materials science biochemistry. This tunable platform provides opportunities systematically investigate impact encapsulation on stability activity order develop design rules hosts.In this Account, we discuss experimentally validated concepts designing MOF hosts based mechanisms. We present methods enhance catalytic performance strategies creating multifunctional enzyme@MOF systems via modifications. start highlighting importance maximizes substrate diffusion availability, particular focus containing hierarchical mesoporous structures those
Язык: Английский
Процитировано
3Environmental Research, Год журнала: 2025, Номер 269, С. 120922 - 120922
Опубликована: Янв. 21, 2025
Язык: Английский
Процитировано
0Materials Science and Engineering B, Год журнала: 2025, Номер 314, С. 118045 - 118045
Опубликована: Янв. 27, 2025
Язык: Английский
Процитировано
0Inorganic Chemistry, Год журнала: 2025, Номер unknown
Опубликована: Фев. 11, 2025
Owing to the rapid development of nuclear industry, uranium has become a global environmental contaminant due its radiotoxicity and chemotoxicity, posing significant threats human health ecological safety. Although various instrumental chemical analytical methods have been developed for uranyl ion detection in aquatic environments, searching new sensors with high stability, sensitivity, selectivity remains challenge. In this study, luminescent Zr-based metal–organic framework (MOF), designated as Tb@UiO-66-(COOH)2, was successfully synthesized utilizing postsynthetic exchange (PSE) method along Tb3+ doping detection. Interestingly, presence UO22+ ions causes replacement guest (Tb3+) sensor via competitive host–guest interaction, leading luminescence quenching. The attenuation intensity Tb@UiO-66-(COOH)2 exhibits an excellent linear relationship concentrations within wide range 0–2.52 μM. Notably, demonstrates unprecedentedly sensitivity (Ksv = 2.16 × 105 M–1) extremely low limit (LOD) down 8.03 nM (1.91 ppb) deionized water. More importantly, can achieve efficient performance, even excesses competing ions. values Ksv were determined be 2.10 M–1 Xie'ao Lake water 3.05 seawater; LOD 8.26 (1.96 5.68 (1.35 seawater. To best our knowledge, is first instance introducing coordination strategy into MOF-based high-performance Hence, present work offers novel idea building functional MOFs aqueous solutions.
Язык: Английский
Процитировано
0Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 160680 - 160680
Опубликована: Фев. 1, 2025
Язык: Английский
Процитировано
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