Recent Progress on Copper‐Based Bimetallic Heterojunction Catalysts for CO2 Electrocatalysis: Unlocking the Mystery of Product Selectivity DOI
Jiabao Huang,

Xinping Zhang,

Yang Jiao

и другие.

Advanced Science, Год журнала: 2024, Номер 11(24)

Опубликована: Апрель 18, 2024

Abstract Copper‐based bimetallic heterojunction catalysts facilitate the deep electrochemical reduction of CO 2 (eCO RR) to produce high‐value‐added organic compounds, which hold significant promise. Understanding influence copper interactions with other metals on adsorption strength various intermediates is crucial as it directly impacts reaction selectivity. In this review, an overview formation mechanism catalytic products in eCO RR provided and highlight uniqueness copper‐based catalysts. By considering different metals' tendencies toward intermediates, are classified, including copper, into four categories. The significance advantages constructing then discussed delve research findings current development status types Finally, insights offered design strategies for future high‐performance electrocatalysts, aiming contribute multi‐carbon fuels high

Язык: Английский

Electrocatalytic C–N coupling for urea synthesis: a critical review DOI

Chuanju Yang,

Zhe Li, Junpeng Xu

и другие.

Green Chemistry, Год журнала: 2024, Номер 26(9), С. 4908 - 4933

Опубликована: Янв. 1, 2024

Strategies for building efficient electrocatalytic urea synthesis systems.

Язык: Английский

Процитировано

16
Pressure-Dependent CO2 Electroreduction to Methane over Asymmetric Cu–N2 Single-Atom Sites DOI
Haoyang Wu, Benqiang Tian, Wenhai Xu

и другие.

Journal of the American Chemical Society, Год журнала: 2024, Номер 146(32), С. 22266 - 22275

Опубликована: Июль 12, 2024

Single-atom catalysts (SACs) with unitary active sites hold great promise for realizing high selectivity toward a single product in the CO

Язык: Английский

Процитировано

16
Tailoring CO2 Adsorption Configuration with Spatial Confinement Switches Electroreduction Product from Formate to Acetate DOI

Hua‐Qin Wang,

Heyu Sui,

Ya-Long Ding

и другие.

Journal of the American Chemical Society, Год журнала: 2025, Номер unknown

Опубликована: Фев. 5, 2025

Multi-proton-coupled electron transfer, multitudinous intermediates, and unavoidable competing hydrogen evolution reaction during CO2 electroreduction make it tricky to control high selectivity for specific products. Here, we present spatial confinement of Fe single atoms (FeN2S2) by adjacent FeS clusters (Fe4S4) orientate the transition adsorption configuration from C,O-side O-end, which triggers a shift activated first-step protonation C–C coupling, thus switching target product HCOOH in Faraday efficiency (FE: 90.6%) on FeN2S2 CH3COOH 82.3%) Fe4S4/FeN2S2. The strength *OCHO upon solitary site is linearly related coordination number Fe–S, with predominantly produced over single-atom (ortho-substituted S atoms). Fe4S4 cluster functions as switch reduction product, can not only optimize electronic structure neighboring but also impel complete hydrocarbon intermediate *CH3, followed coupling CO2* *CH3 via synergistic catalysis This strategy provides new avenue modulate reactant model desirable pathways, potential applications diverse multistep electrochemical processes controlled selectivity.

Язык: Английский

Процитировано

4
Direct Electrochemical Reduction of CO2 to C2+ Chemicals: Catalysts, Microenvironments, and Mechanistic Understanding DOI
Shichen Guo, J. Wang, Haozhe Zhang

и другие.

ACS Energy Letters, Год журнала: 2025, Номер 10(1), С. 600 - 619

Опубликована: Янв. 2, 2025

The electrochemical reduction reaction of CO2 (eCO2RR) to chemicals presents a viable solution for addressing climate change and sustainable manufacturing. In this Review, we describe the recent advancements in eCO2RR multicarbon (C2+) production from aspects catalyst structure, microenvironments, mechanistic understanding. We draw experimental theoretical comparisons between systems containing bulk highly dispersed metals, alloys, metal compounds recount new results microenvironmental impacts as well catalytic mechanism. From our own studies, offer some viewpoints on electrocatalytic mechanism during complex multistep proton-coupled electron transfers propose several research directions unlocking full potential scalable industrial CO2-to-C2+ conversion.

Язык: Английский

Процитировано

2
Optimizing C─C Coupling on Cu0/Cu+/Ga Interfaces by Enhancing Active Hydrogen Absorption for Excellent CO2‐to‐C2+ Electrosynthesis DOI Open Access
Xiaoning Qi, Yikai Yang,

Y. C. Lan

и другие.

Small, Год журнала: 2025, Номер unknown

Опубликована: Март 5, 2025

The electrocatalytic reduction of CO2 (CO2RR) to high-value chemicals and fuels offers a promising route for clean carbon cycle. However, it often suffers from low catalytic activity poor selectivity. Heterostructure construction has been shown be an effective strategy producing multi-carbon products, but the synergistic mechanisms between multiple active sites resulting reconstruction process remain unclear. In this study, Ga2O3/CuO heterostructure is established via simple sol-gel method produce C2+ products. Experimental results demonstrate that Ga2O3 stabilizes Cu+ form Cu0/Cu+/Ga centers enhances water-splitting ability during reaction. improved hydrogen absorption on Ga site shifts C─C coupling reaction pathway *OCCO asymmetric *OCCHO path with lower energy barrier. As result, catalysts exhibit superior CO2RR performance, achieving 70.1% Faradaic efficiency at -1.2 VRHE in flow cell, ethylene reaching 58.3% remaining stable 10 h.

Язык: Английский

Процитировано

2
Atomic Dispersed Hetero-Pairs for Enhanced Electrocatalytic CO2 Reduction DOI Creative Commons

Zhaoyong Jin,

Meiqi Yang,

Yilong Dong

и другие.

Nano-Micro Letters, Год журнала: 2023, Номер 16(1)

Опубликована: Ноя. 6, 2023

Abstract Electrochemical carbon dioxide reduction reaction (CO 2 RR) involves a variety of intermediates with highly correlated and ad-desorption energies, hindering optimization the catalytic activity. For example, increasing binding *COOH to active site will generally increase *CO desorption energy. Breaking this relationship may be expected dramatically improve intrinsic activity CO RR, but remains an unsolved challenge. Herein, we addressed conundrum by constructing unique atomic dispersed hetero-pair consisting Mo-Fe di-atoms anchored on N-doped carrier. This system shows unprecedented RR TOF 3336 h −1 , high selectivity toward production, Faradaic efficiency 95.96% at − 0.60 V excellent stability. Theoretical calculations show that diatomic sites increased intermediate adsorption energy bridging intermediates. At same time, d-d orbital coupling in di-atom results electron delocalization facilitates Thus, undesirable correlation between these steps is broken. work provides promising approach, specifically use di-atoms, for breaking unfavorable relationships based understanding mechanisms scale.

Язык: Английский

Процитировано

26
Carbothermal shock enabled functional nanomaterials for energy-related applications DOI
Wei Zhang, Xiang Wei, Tong Wu

и другие.

Nano Energy, Год журнала: 2023, Номер 118, С. 108994 - 108994

Опубликована: Окт. 13, 2023

Язык: Английский

Процитировано

24
Strategies to achieve effective nitrogen activation DOI Creative Commons
Bin Chang, Huabin Zhang, Shuhui Sun

и другие.

Carbon Energy, Год журнала: 2024, Номер 6(5)

Опубликована: Фев. 23, 2024

Abstract Ammonia serves as a crucial chemical raw material and hydrogen energy carrier. Aqueous electrocatalytic nitrogen reduction reaction (NRR), powered by renewable energy, has attracted tremendous interest during the past few years. Although some achievements have been revealed in aqueous NRR, significant challenges also identified. The activity selectivity are fundamentally limited activation competitive evolution. This review focuses on hurdles of delves into complementary strategies, including materials design system optimization (reactor, electrolyte, mediator). Then, it introduces advanced interdisciplinary technologies that recently emerged for using high‐energy physics such plasma triboelectrification. With better understanding corresponding mechanisms coming years, these potential to be extended further applications. provides insight stability different systems. We then recommend rigorous detailed protocol investigating NRR performance highlight several research directions this exciting field, coupling with applications, situ/operando characterizations, theoretical calculations.

Язык: Английский

Процитировано

15
Unlocking solar energy: Photocatalysts design for tuning the CO2 conversion into high-value (C2+) solar fuels DOI
Chaitanya B. Hiragond, Niket S. Powar, Hwapyong Kim

и другие.

EnergyChem, Год журнала: 2024, Номер 6(5), С. 100130 - 100130

Опубликована: Июль 16, 2024

Язык: Английский

Процитировано

15
Electrochemical CO2 reduction integrated with membrane/adsorption‐based CO2 capture in gas‐diffusion electrodes and electrolytes DOI Creative Commons
Hesamoddin Rabiee, Penghui Yan, Hao Wang

и другие.

EcoEnergy, Год журнала: 2024, Номер 2(1), С. 3 - 21

Опубликована: Янв. 26, 2024

Abstract Electrochemical CO 2 reduction reaction (CO RR) has attracted much attention in the last decade, owing to its unique advantages such as operation at ambient conditions, coupling with renewable electricity, and producing a wide range of products commodities. The majority RR studies are focused on pure feed, while real waste streams, flue gas or biogas, concentration does not exceed 40%. Therefore, economic feasibility carbon footprint greatly limited by purification steps before electrolysis ($70–100 per ton for /N separation). In recent years, have exhibited importance this matter integrating capture electroreduction single unit. Mostly, solutions electrolytes been under attention, promising results achieved significantly improve overall economy RR. focus capture‐electroreduction integration can go beyond solution/electrolyte‐based (e.g., amine ionic liquids) other processes solid adsorption membrane‐based processes, more efficient options, be potentially integrated gas‐diffusion electrode design. This article aims review efforts provides new perspectives material selection design membrane‐ adsorption‐based capture‐reduction integration, addition analysis integration.

Язык: Английский

Процитировано

12