Advanced Materials,
Год журнала:
2024,
Номер
36(29)
Опубликована: Апрель 29, 2024
Abstract
The
development
of
high‐performance
electrocatalysts
for
energy
conversion
reactions
is
crucial
advancing
global
sustainability.
design
catalysts
based
on
their
electronic
properties
(e.g.,
work
function)
has
gained
significant
attention
recently.
Although
numerous
reviews
electrocatalysis
have
been
provided,
no
such
reports
function‐guided
electrocatalyst
are
available.
Herein,
a
comprehensive
summary
the
latest
advancements
in
diverse
electrochemical
applications
provided.
This
includes
function‐based
catalytic
activity
descriptors,
and
both
monolithic
heterostructural
catalysts.
measurement
function
first
discussed
descriptors
various
fully
analyzed.
Subsequently,
function‐regulated
material‐electrolyte
interfacial
electron
transfer
(IET)
employed
catalyst
design,
methods
regulating
optimizing
performance
discussed.
In
addition,
key
strategies
tuning
function‐governed
material‐material
IET
examined.
Finally,
perspectives
determination,
put
forward
to
guide
future
research.
paves
way
rational
efficient
sustainable
applications.
Advanced Energy Materials,
Год журнала:
2024,
Номер
14(30)
Опубликована: Май 27, 2024
Abstract
Electrochemical
water
splitting
is
a
promising
technique
for
the
production
of
high‐purity
hydrogen.
Substituting
slow
anodic
oxygen
evolution
reaction
with
an
oxidation
that
thermodynamically
more
favorable
enables
energy‐efficient
Moreover,
this
approach
facilitates
degradation
environmental
pollutants
and
synthesis
value‐added
chemicals
through
rational
selection
small
molecules
as
substrates.
Strategies
small‐molecule
electrocatalyst
design
are
critical
to
electrocatalytic
performance,
focus
on
achieving
high
current
density,
selectivity,
Faradaic
efficiency,
operational
durability.
This
perspective
discusses
key
factors
required
further
advancement,
including
technoeconomic
analysis,
new
reactor
system
design,
meeting
requirements
industrial
applications,
bridging
gap
between
fundamental
research
practical
product
detection
separation.
aims
advance
development
hybrid
electrolysis
applications.
EcoEnergy,
Год журнала:
2024,
Номер
2(1), С. 114 - 140
Опубликована: Март 1, 2024
Abstract
Developing
efficient
electrocatalysts
for
water
electrolysis
is
critical
sustainable
hydrogen
energy
development.
For
enhancing
the
catalytic
performance
of
metal
catalysts,
dual
doping
has
attracted
enormous
interest
its
high
effectiveness
and
facile
realization.
Dual
effective
tuning
electronic
properties,
electrical
conductivity,
populating
active
sites,
improving
stability
catalysts.
In
this
review,
recent
developments
in
cation–cation,
cation–anion,
anion–anion
dual‐doped
catalysts
splitting
are
comprehensively
summarized
discussed.
An
emphasis
put
on
illustrating
how
regulates
external
internal
properties
boosts
Additionally,
perspectives
pointed
out
to
guide
future
research
engineering
high‐performance
heteroatom‐doped
electrocatalysts.
Renewable and Sustainable Energy Reviews,
Год журнала:
2024,
Номер
195, С. 114333 - 114333
Опубликована: Фев. 27, 2024
The
abundant
plastic
wastes
become
an
imperative
global
issue,
and
how
to
handle
these
organic
gains
growing
scientific
industrial
interest.
Recently,
converting
into
hydrogen
fuel
has
been
investigated,
the
"waste-to-value"
practice
accelerates
circular
economy.
To
accelerate
development
of
plastic-to-hydrogen
conversion,
in
this
review,
recent
advances
conversion
via
thermochemical,
photocatalytic,
electrocatalytic
routes
are
analyzed.
All
thermo-,
photo-,
electrochemical
processes
can
transform
different
hydrogen,
production
efficiency
depends
heavily
on
selected
techniques,
operating
parameters,
applied
catalysts.
application
rational-designed
catalysts
promote
selective
from
feedstocks.
Further
studies
process
optimization,
cost-effective
catalyst
design,
mechanism
investigation
needed.
Progress in Materials Science,
Год журнала:
2024,
Номер
145, С. 101299 - 101299
Опубликована: Апрель 16, 2024
Electrochemistry-driven
techniques
for
advanced
energy
storage/conversion
and
environmental
protection
play
a
crucial
role
in
achieving
sustainable
development
goals.
As
an
indispensable
component
diverse
electrochemical
systems,
electroactive
materials
gain
soaring
interest
terms
of
rational
design
synthesis.
Notably,
mechanochemistry-based
green
powerful
synthesis
has
been
widely
employed
to
fabricate
materials,
given
their
scalability
tunability.
Recently,
mechanochemically
synthesized
have
applied
various
fields,
leading
significant
progress.
However,
systematic
analysis
these
advancements
is
still
missing.
Herein,
we
comprehensively
discuss
recent
achievements
mechanosynthesized
applications.
The
mechanochemical
introduced,
along
with
different
types
materials.
Subsequently,
the
review
delves
into
applications
conversion/storage
systems
remediation.
structure-performance
correlation
are
illustrated
by
discussing
effects
process
on
internal
external
properties
performance.
Lastly,
key
perspectives
this
field
discussed,
including
monitoring,
field-assisted
synthesis,
material
performance
optimization,
practical
applications,
mechanochemistry-driven
fuels/chemicals
By
illustrating
current
advances
related
aims
shed
some
light
upcoming
research
synthesis-driven
sustainability.
Transition
metal
hydroxides
have
attracted
significant
research
interest
for
their
energy
storage
and
conversion
technique
applications.
In
particular,
nickel
hydroxide
(Ni(OH)
Abstract
With
large
quantities
and
natural
resistance
to
degradation,
plastic
waste
raises
growing
environmental
concerns
in
the
world.
To
achieve
upcycling
of
into
value‐added
products,
electrocatalytic‐driven
process
is
emerging
as
an
attractive
option
due
mild
operation
conditions,
high
reaction
selectivity,
low
carbon
emission.
Herein,
this
review
provides
a
comprehensive
overview
upgrading
via
electrocatalysis.
Specifically,
key
electrooxidation
processes
including
target
intermediates
pathways
electro‐reforming
are
discussed.
Subsequently,
advanced
electrochemical
systems,
integration
anodic
monomer
oxidation
cathodic
reduction
photo‐involved
electrolysis
processes,
summarized.
The
design
strategies
electrocatalysts
with
enhanced
activity
highlighted
catalytic
mechanisms
electrocatalytic
elucidated.
promote
electrochemistry‐driven
sustainable
waste,
challenges
opportunities
further
put
forward.
Chemical Communications,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
The
urea
oxidation
reaction
(UOR)
presents
a
more
favorable
alternative
to
the
conventional
oxygen
evolution
(OER)
for
hydrogen
production
due
its
lower
thermodynamic
potential.
This
method
offers
advantages
over
traditional
approaches
operating
conditions
and
potentially
costs.
However,
complex
6-electron
transfer
process
in
UOR
limits
performance.
Researchers
are
tackling
this
challenge
by
designing
advanced
electrocatalysts
with
optimized
properties,
such
as
porosity,
heterostructures,
controlled
defects,
surface
functionalization,
fine-tuned
electronic
structures.
significant
progress
catalyst
design
holds
promise
future
of
clean
energy
technologies.
In
view
this,
layered
double
hydroxides
(LDHs)
attracting
interest
their
potential
role
electrolysis
synergistic
cooperation
metals,
flexible
configuration,
tunable
composition
unique
structure.
review
examines
recent
advancements
synthesis
LDH-based
catalysts.
Beyond
highlighting
breakthroughs
catalysts,
critically
stresses
strategies
challenges
towards
conversion.
Moreover,
comprehensive
approach
provides
valuable
forward-looking
perspective
on
research
directions.
