Analytical Methods,
Год журнала:
2024,
Номер
16(37), С. 6392 - 6402
Опубликована: Янв. 1, 2024
The
One
Health
perspective
highlights
the
balance
needed
between
antibiotic
use
and
preventing
environmental
contamination.
A
newly
synthesized
MIP
sensor
offers
a
revolutionary,
miniaturized
tool
for
detecting
ENR
residues
effectively.
Separations,
Год журнала:
2025,
Номер
12(4), С. 94 - 94
Опубликована: Апрель 10, 2025
Polyethyleneimine-based
porous
composites
have
been
prepared
by
ring-opening
polymerization
of
2,2-bishydroxymethylbutanol-tris[3-(1-aziridinyl)propionate]
(3AZ),
a
tri-aziridine
compound,
in
water,
the
presence
cyclodextrins
(CDs),
i.e.,
α-CD,
γ-CD,
methyl-β-cyclodextrin
(Me-β-CD),
monoacetyl-β-cyclodextrin
(Ac-β-CD),
and
hydroxypropyl-β-cyclodextrin
(HP-β-CD).
The
corresponding
3AZ-CD
polymer
were
successfully
obtained
most
cases
under
wide
range
CD
concentrations,
5–20
wt%,
reaction
temperatures,
20–60
°C.
system
Ac-β-CD
preferentially
yielded
gels.
composed
connected
particles
with
sizes
order
10−9
m.
particle
decreased
an
increase
concentration.
Young’s
moduli
tended
to
bulk
density.
Me-β-CD
HP-β-CD
effectively
adsorbed
phenolphthalein
solution.
adsorption
value
increased
increasing
content
rose
more
than
600
mg/g
composite.
Applied Sciences,
Год журнала:
2024,
Номер
14(8), С. 3320 - 3320
Опубликована: Апрель 15, 2024
In
this
paper,
we
report
the
synthesis
of
a
multi-template
molecularly
imprinted
polymer
(MIP)
to
target
and
extract
naproxen,
ibuprofen,
diclofenac,
emtricitabine,
tenofovir
disoproxil,
efavirenz
from
wastewater
bodies.
A
bulk
polymerization
procedure
was
used
synthesize
MIP
non-imprinted
(NIP).
The
specific
recognition
sites
for
each
were
obtained
through
removal
targeted
compounds.
interaction
antiretroviral
drugs
(ARVs)
non-steroidal
anti-inflammatory
(NSAIDs)
compounds
with
studied
under
various
conditions
such
as
pH,
mass,
concentration,
time
factors.
results
demonstrated
optimum
55
mg
MIP,
pH
7.0,
concentration
5
L−1,
contact
10
min.
For
every
compound
studied,
extraction
efficiencies
ARVs
NSAIDs
in
aqueous
solutions
>96%.
adsorption
capacity
>0.91
mg·g−1.
Adsorption
obeys
second-order
rate,
Freundlich
model
explains
isotherm
data.
This
study
that
synthesized
has
huge
potential
be
employed
environment
well
drug
purification
or
recovery
processes.
Polymer Chemistry,
Год журнала:
2024,
Номер
15(27), С. 2763 - 2772
Опубликована: Янв. 1, 2024
We
report
the
synthesis
of
thermoresponsive
poly(
N
-isopropylacrylamide)
coated
manganese
dioxide
nanoparticles
for
catalytic
decomposition
hydrogen
peroxide
(H
2
O
),
with
goal
developing
a
temperature-controlled
system.
ABSTRACT
The
ineffectiveness
of
traditional
wastewater
treatment
procedures
to
completely
remove
them
results
in
their
release
into
the
environment.
There
is
a
pressing
need
pharmaceuticals
effectively
using
different
methods.
Using
affordable
technologies
while
maintaining
standards
for
health
and
safety
one
main
problems
industry.
In
this
study,
cost
effective
highly
selective
molecularly
imprinted
polymers
(MIPs)
was
combined
with
silver
nanoparticles
(AgNPs)
capped
platanus
acerifolia
(PL)
moringa
oleifera
(MO)
removal
sulfamethoxazole,
nevirapine
ibuprofen
wastewater.
Moreover,
study
focused
on
adsorption
parameters,
including
temperature,
pH,
adsorbent
dosage,
adsorbate
concentration,
contact
time.
transmission
electron
microscopy
revealed
that
MO/PL‐AgNPs
MO/PL‐nanoMIPs
are
nanosized
spherical.
XRD
confirmed
formation
AgNPs
onto
surface.
Adsorption
isotherms
fitted
linear
Langmuir
model.
However,
high
Q
max
values
were
obtained
compared
MO/PL‐AgNPs.
pseudosecond
order
second‐order
kinetic
model
best
MO/PL‐nanoMIPs,
thermodynamics
process
spontaneous
endothermic.
findings
first
time
efficiency
selected
target