Ligand modulated charge transfers in Z-scheme configured Ni-MOF/g-C3N4 nanocomposites for photocatalytic remediation of dye-polluted water DOI Creative Commons

Gayathri Karthik,

M. Sakar, R. Geetha Balakrishna

и другие.

Scientific Reports, Год журнала: 2024, Номер 14(1)

Опубликована: Окт. 30, 2024

The development of photocatalysts must be meticulous, especially when they are designed to degrade hazardous dyes that cause mutagenesis and carcinogenesis. In this meticulous approach, Ni-based metal-organic frameworks with different ligands, including terephthalic acid (NTP), 2-aminoterephthalic (NATP), their composite g-C

Язык: Английский

Highly efficient nitrogen fixation over S-scheme heterojunction photocatalysts with enhanced active hydrogen supply DOI Creative Commons

Tong Bao,

Yamin Xi,

Chaoqi Zhang

и другие.

National Science Review, Год журнала: 2024, Номер 11(5)

Опубликована: Март 8, 2024

ABSTRACT Photocatalytic N2 fixation is a promising strategy for ammonia (NH3) synthesis; however, it suffers from relatively low yield due to the difficulty in design of photocatalysts with both high charge transfer efficiency and desirable adsorption/activation capability. Herein, an S-scheme CoSx/ZnS heterojunction dual active sites designed as efficient photocatalyst. The exhibits unique pocket-like nanostructure small ZnS nanocrystals adhered on single-hole CoSx hollow dodecahedron. Within heterojunction, electronic interaction between creates electron-deficient Zn enhanced chemisorption electron-sufficient Co hydrogen supply hydrogenation, cooperatively reducing energy barrier activation. In combination promoted photogenerated electron-hole separation facilitated mass by nanostructure, excellent performance NH3 1175.37 μmol g−1 h−1 achieved. This study provides new insights into fixation.

Язык: Английский

Процитировано

27
Boosting Photocatalytic Upcycling of Liquid Biomass into Biodiesel via Microenvironment Modulation DOI Creative Commons

Lijuan He,

Lilong Zhang, Heng Zhou

и другие.

Advanced Energy Materials, Год журнала: 2024, Номер unknown

Опубликована: Авг. 13, 2024

Abstract The rational design of a photocatalyst and its microenvironmental modulation is crucial in the heterogeneous photocatalysis process, yet relevant research on photocatalytic biodiesel synthesis not explored. Herein, based prediction density functional theory (DFT) calculations, highly efficient ternary biocompatible montmorillonite (Mt) nanocomposites S‐scheme heterojunction photocatalysts (g‐C 3 N 4 ‐TiO 2 @Mt, CTM) are successfully rationally designed. By modulating microenvironment production, CTM‐2 demonstrates exceptional catalytic performance stability, achieving record‐breaking yield 98.5%. Through ex/in situ X‐ray photoelectron spectroscopy (XPS), absorption near‐edge (XANES), theoretical formation revealed, which can generate an interface electric field (IEF) that provides intrinsic driving force for carrier migration enhances surface positivity. This boosts enrichment effect electronegative oleic acid (OA) carboxyl molecules, thus greatly enriching substrate concentration improving reaction microenvironment. Moreover, fourier transform infrared spectrometer (FT‐IR)/Raman together with electron paramagnetic resonance (EPR) further confirm key intermediates CH O• ester carbonyl (C═O), DFT calculations provide reference pathway, determined to be capable significantly reducing energy barrier rate‐determining step.

Язык: Английский

Процитировано

21
Empowering wastewater treatment with step scheme heterojunction ternary nanocomposites for photocatalytic degradation of nitrophenol DOI Creative Commons
Zhu Liu, Mah Roosh, Ming Lü

и другие.

Scientific Reports, Год журнала: 2025, Номер 15(1)

Опубликована: Янв. 26, 2025

The ongoing challenge of water pollution necessitates innovative approaches to remove organic contaminants from wastewater. In this work, new two-dimensional S-scheme heterojunction photocatalysts Bi2O3/CdS and MoS2/Bi2O3/CdS that are intended for the effective photocatalytic destruction 4-nitrophenol, a dangerous pollutant, synthesized characterized. Utilizing solvothermal method, successfully generated these ternary nanocomposites, which were characterized through various techniques including X-ray diffraction (XRD), scanning electron microscopy (SEM), photoelectron spectroscopy (XPS), high resolution transmission electronmicroscopy (HRTEM), Brunauer-Emmett-Telle (BET) diffuse reflectance (DRS). Our results demonstrated achieved an 86% degradation rate while composite exhibited exceptional performance, achieving nearly complete (99%) within 120 min under visible light irradiation. Most importantly improved activity originated release internal electric field in heterojunction. This enhanced is attributable synergistic effects heterojunctions facilitate more charge separation generation with OP RP confirmed synthesis using S-scheme. further by XPS, DRS, XPS-VB photocurrent response. These findings highlight promising application advanced real-world wastewater treatment processes, offering sustainable solution combat pollution.

Язык: Английский

Процитировано

2
Mofs-based S-scheme heterojunction photocatalysts: Challenges and prospects to break the selectivity limitation for intensified C1 products in CO2 photoreduction DOI

Monika Malhotra,

Vatika Soni,

Rohit Kumar

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 160238 - 160238

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

1
Cross‐Referencing Multifluid Metabolic Profiles on Hollow Dodecahedral Nanocages for Enhanced Disease Status Identification DOI Open Access

Fangying Shi,

Lingli Chen, Yiming Qiao

и другие.

Small, Год журнала: 2025, Номер 21(9)

Опубликована: Фев. 5, 2025

Abstract The development of matrices has shown great potential for fluid metabolic analysis in disease detection. However, single‐fluid metabolomic been recognized as insufficient to fully capture the complexities diseases such liver disease, which limits detection accuracy. To this end, hollow dodecahedral nanocages‐based analytical tool is developed, featuring four‐high characteristics speed, throughput, efficiency, and patient compliance, enhance extraction multifluid profiles. cross‐referencing these profiles among different diseases, including hepatocellular carcinoma (HCC), chronic (CLD), healthy controls, enhances diagnosis particularly achieving near‐perfect discrimination HCC with an AUC value 0.990, significantly outperforming any single analysis. Additionally, dynamic changes expression levels key biomarkers throughout progression are explored, providing insights into their temporal evolution, highlighting role monitoring status. This work highlights that can comprehensively sensitively reflect status, enabling precise identification complex facilitating personalized treatment.

Язык: Английский

Процитировано

1
Synthesis of the composites of carbon quantum dots and metal organic framework and their application in hydrogen evolution DOI

Chun-Yao Chang,

Chung‐Wei Kung,

Shanmuganathan Venkatesana

и другие.

International Journal of Hydrogen Energy, Год журнала: 2024, Номер 68, С. 321 - 330

Опубликована: Апрель 27, 2024

Язык: Английский

Процитировано

7
Metal-organic framework-based catalysts for solar-driven CO2 cycloaddition DOI

Jingyun Guo,

Simiao Guo,

P. Zhang

и другие.

Applied Materials Today, Год журнала: 2025, Номер 42, С. 102595 - 102595

Опубликована: Янв. 14, 2025

Язык: Английский

Процитировано

0
Principles, progress, and prospects of photo-rechargeable zinc-ion batteries DOI

Kejun Jin,

Yingjian Yu

Journal of Energy Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

0
Trending applications of layered triple hydroxide composites in adsorption and photocatalysis for highly effective wastewater treatment DOI

Angita Sarkar,

Bipul Das, Sanjay Basumatary

и другие.

Inorganic Chemistry Communications, Год журнала: 2025, Номер unknown, С. 114052 - 114052

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

0
1D-based nanostructures in photocatalytic CO2 reduction DOI

Farideh Kolahdouzan,

Nahal Goodarzi,

Mahboobeh Setayeshmehr

и другие.

CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Год журнала: 2025, Номер 70, С. 230 - 259

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0