Development of Mn(i)-based catalysts for CO2 hydrogenation/dehydrogenation in the context of hydrogen storage/release systems DOI
Mohammed Cassiem Joseph, Andrew J. Swarts

Royal Society of Chemistry eBooks, Год журнала: 2024, Номер unknown, С. 117 - 149

Опубликована: Дек. 6, 2024

This chapter provides a comprehensive overview of recent advancements in Mn(i)-catalysed hydrogenation and dehydrogenation reactions, with focus on their application hydrogen storage systems. It explores the reactivity Mn(i) complexes formate analogues, as well catalytic mechanisms, highlighting potential these catalysts to contribute circular carbon economy. The investigates use carbonate hydroxide salts amines environmentally friendly materials for storage, demonstrating substantial efficiency high evolution yield excellent reloading purity. systems’ operation below 100 °C suggests possibility waste heat management integration into process. also discusses challenges limitations encountered, such decreased subsequent cycles solubility issues certain CO2 absorbents. Overall, presents promising candidates renewable energy applications, offering insights current future perspectives development efficient, affordable, sustainable technologies.

Язык: Английский

Phthalimidine Synthesis via Iridium-Catalyzed Reductive Lactamization DOI
Jingyu Zhang, Chen Yang, Jiaxi Xu

и другие.

The Journal of Organic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Дек. 24, 2024

Herein, we report a sustainable and efficient method for the synthesis of structurally diverse phthalimidines from 2-formylbenzoic acid primary amines using an iridium-catalyzed reductive lactamization strategy. The advantages this method, such as use water–ethanol solvent, broad substrate scope, high catalyst efficiency (S/C up to 10000), good scalability, easy purification, enable it be practical approach phthalimidines. It is suggested that iridium hydride formation involved in rate-limiting step. Synthetic applications late-stage functionalization medicinally relevant molecules are also demonstrated.

Язык: Английский

Процитировано

0
Hydrogen Storage DOI
Peter Ozaveshe Oviroh, Sunday Temitope Oyinbo, Sina Karimzadeh

и другие.

Springer series in materials science, Год журнала: 2024, Номер unknown, С. 139 - 212

Опубликована: Дек. 30, 2024

Процитировано

0
Development of Mn(i)-based catalysts for CO2 hydrogenation/dehydrogenation in the context of hydrogen storage/release systems DOI
Mohammed Cassiem Joseph, Andrew J. Swarts

Royal Society of Chemistry eBooks, Год журнала: 2024, Номер unknown, С. 117 - 149

Опубликована: Дек. 6, 2024

This chapter provides a comprehensive overview of recent advancements in Mn(i)-catalysed hydrogenation and dehydrogenation reactions, with focus on their application hydrogen storage systems. It explores the reactivity Mn(i) complexes formate analogues, as well catalytic mechanisms, highlighting potential these catalysts to contribute circular carbon economy. The investigates use carbonate hydroxide salts amines environmentally friendly materials for storage, demonstrating substantial efficiency high evolution yield excellent reloading purity. systems’ operation below 100 °C suggests possibility waste heat management integration into process. also discusses challenges limitations encountered, such decreased subsequent cycles solubility issues certain CO2 absorbents. Overall, presents promising candidates renewable energy applications, offering insights current future perspectives development efficient, affordable, sustainable technologies.

Язык: Английский

Процитировано

0