Royal Society of Chemistry eBooks, Journal Year: 2024, Volume and Issue: unknown, P. 117 - 149
Published: Dec. 6, 2024
This chapter provides a comprehensive overview of recent advancements in Mn(i)-catalysed hydrogenation and dehydrogenation reactions, with focus on their application hydrogen storage systems. It explores the reactivity Mn(i) complexes formate analogues, as well catalytic mechanisms, highlighting potential these catalysts to contribute circular carbon economy. The investigates use carbonate hydroxide salts amines environmentally friendly materials for storage, demonstrating substantial efficiency high evolution yield excellent reloading purity. systems’ operation below 100 °C suggests possibility waste heat management integration into process. also discusses challenges limitations encountered, such decreased subsequent cycles solubility issues certain CO2 absorbents. Overall, presents promising candidates renewable energy applications, offering insights current future perspectives development efficient, affordable, sustainable technologies.
Language: Английский