Electrically driven phosphorus dissolution from iron-nickel phosphate surfaces exposing highly active sites for oxygen evolution reaction DOI

Ya Liu,

Jinghui Zhu, Liang Yu

и другие.

Journal of Colloid and Interface Science, Год журнала: 2024, Номер 683, С. 197 - 206

Опубликована: Дек. 9, 2024

Язык: Английский

Expanding the frontiers of electrocatalysis: advanced theoretical methods for water splitting DOI Creative Commons
Seong Chan Cho,

Jun Ho Seok,

Hung Ngo Manh

и другие.

Nano Convergence, Год журнала: 2025, Номер 12(1)

Опубликована: Янв. 24, 2025

Abstract Electrochemical water splitting, which encompasses the hydrogen evolution reaction (HER) and oxygen (OER), offers a promising route for sustainable production. The development of efficient cost-effective electrocatalysts is crucial advancing this technology, especially given reliance on expensive transition metals, such as Pt Ir, in traditional catalysts. This review highlights recent advances design optimization electrocatalysts, focusing density functional theory (DFT) key tool understanding improving catalytic performance HER OER. We begin by exploring DFT-based approaches evaluating activity under both acidic alkaline conditions. then shifts to material-oriented perspective, showcasing catalyst materials theoretical strategies employed enhance their performance. In addition, we discuss scaling relationships that exist between binding energies electronic structures through use charge-density analysis d -band theory. Advanced concepts, effects adsorbate coverage, solvation, applied potential behavior, are also discussed. finally focus integrating machine learning (ML) with DFT enable high-throughput screening accelerate discovery novel water-splitting comprehensive underscores pivotal role plays electrocatalyst its shaping future Graphical

Язык: Английский

Процитировано

4

Double‐Walled Tubular Heusler‐Type Platinum–Ruthenium Phosphide as All‐pH Hydrogen Evolution Reaction Catalyst Outperforming Platinum and Ruthenium DOI
Yongju Hong, Seong Chan Cho,

Soobean Kim

и другие.

Advanced Energy Materials, Год журнала: 2024, Номер 14(12)

Опубликована: Фев. 2, 2024

Abstract Nanostructured ionic compounds have driven major technological advancements in displays, photovoltaics, and catalysis. Current research focuses on refining the chemical composition of such compounds. In this study, a strategy for creating stoichiometrically well‐defined nanoscale multiple‐cation systems, where atomically precise structure maximizes synergistic cooperation between cations at atomic scale is reported. The unprecedented construction Heusler‐type PtRuP 2 double‐walled nanotubes through sequential anion/cation exchange reactions demonstrated. catalyst exhibits record‐high catalytic performance durability hydrogen evolution reaction (HER) alkaline electrolytes anion‐exchange membrane water electrolyzers. investigations highlight crucial role Pt/Ru dual centers, providing multiple active sites that accelerate HER kinetics within single phosphide material, operation H O activation/dissociation Ru production adjacent Pt sites. These findings open new avenues optimizing compound‐based electrocatalysts, offering platinum‐metal alternatives acidic media.

Язык: Английский

Процитировано

17

Scaling Up Stability: Navigating from Lab Insights to Robust Oxygen Evolution Electrocatalysts for Industrial Water Electrolysis DOI
Faiza Meharban, Chao Lin,

Xiaotong Wu

и другие.

Advanced Energy Materials, Год журнала: 2024, Номер unknown

Опубликована: Авг. 29, 2024

Abstract In the pursuit of sustainable hydrogen production via water electrolysis, paramount importance electrocatalyst stability emerges as a defining factor for long‐term industrial viability. A thorough understanding and enhancement not only ensure extended catalyst lifetimes but also pave way consistent efficient generation. This review focuses on pivotal role in determining practical viability oxygen evolution electrocatalysts (OECs) large‐scale applications electrolysis production. The paper explores over initial activity, citing examples hypothetical scenarios. First, figures merits evaluation are explained along with available benchmarking protocols evaluation. Further, text delves into various strategies that can enhance which include self‐healing/regeneration pathway, reaction (OER) mechanism optimization to achieve highly stable OER stabilization active metals atoms within inhibit dissolution forward application. interplay stability, cost is suit application electrocatalyst. Lastly, it outlines challenges, prospects, future directions, presenting guide advancing OECs generation landscape.

Язык: Английский

Процитировано

14

Crystalline Ru-Decorated MOF-Derived Amorphous CoMo-LDH Nanosheet Arrays as Bifunctional Catalysts for Overall Natural Seawater Electrolysis DOI

Thuy Tien Nguyen Tran,

Thi Anh Le, N. Dinh

и другие.

ACS Applied Materials & Interfaces, Год журнала: 2024, Номер unknown

Опубликована: Сен. 24, 2024

The construction of an amorphous/crystalline heterostructure MOF-derived electrocatalysts offers intriguing pathway to improve hydrogen production efficiency, but it has received little attention. Here, we report crystalline Ru-decorated amorphous CoMo-LDH nanosheet arrays as highly active and robust bifunctional for natural seawater electrolysis. Benefiting from the abundant interfaces, Ru-CoMo-LDH catalyst exhibits excellent activity toward OER under fresh seawater, in particular; requires only 257 406 mV overpotential at 10 500 mA cm

Язык: Английский

Процитировано

13

Heterostructure of Fe-Doped CoMoOx/CoMoOx as an Efficient Electrocatalyst for Oxygen Evolution Reaction DOI
Cu Dang Van, Samiran Garain, Joel W. Ager

и другие.

ACS Applied Materials & Interfaces, Год журнала: 2024, Номер 16(8), С. 9989 - 9998

Опубликована: Фев. 15, 2024

Oxygen evolution reaction (OER) plays a crucial role as counter half-reaction for both electrochemical hydrogen production through water splitting and the generation of valuable carbon compounds via CO

Язык: Английский

Процитировано

9

Engineering Amorphous CoNiRuOx Nanoparticles Grown on Nickel Foam for Boosted Electrocatalytic Hydrogen Evolution DOI Open Access

Xiahui Shi,

Qitong Ye, Qing Huang

и другие.

Catalysts, Год журнала: 2025, Номер 15(3), С. 211 - 211

Опубликована: Фев. 22, 2025

Designing efficient and cost-effective electrocatalysts is crucial for the large-scale development of sustainable hydrogen energy. Amorphous catalysts hold great promise application due to their structural flexibility high exposure active sites. We report a novel method in situ growth amorphous CoNiRuOx nanoparticle structures (CoNiRuOx/NF) on nickel foam substrate. In 1 m KOH, CoNiRuOx/NF achieves current density 10 mA/cm2 with evolution reaction (HER) overpotential only 43 mV remains stable over 100 h at mA/cm2. An alkaline electrolyzer assembled as cathode delivers 2.97 times higher than that an IrO2||Pt/C electrode pair potential 2 V exhibits excellent long-term durability exceeding h. Experimental results reveal combined replacement corrosion reactions facilitate formation structure. This work provides valuable insights developing scalable catalysts.

Язык: Английский

Процитировано

1

A crystalline/amorphous FeCo alloy/FeCoNi-Pi bifunctional electrocatalyst for efficient overall water splitting DOI
Haoyu Li, Yawei Xiao,

Xu Tian

и другие.

Inorganic Chemistry Frontiers, Год журнала: 2024, Номер 11(12), С. 3585 - 3595

Опубликована: Янв. 1, 2024

The crystalline/amorphous composite strategy proposed in this work presents a new concept for the rational design of FeCo alloy-based bifunctional electrocatalysts efficient overall water splitting.

Язык: Английский

Процитировано

5

Tailored nanocomposite FeNiB/MnO2/rGO@NF electrocatalyst for highly efficient and stable oxygen evolution reaction in freshwater and seawater environments DOI
Min Song, Xue Yang, W. F. Mader

и другие.

Materials Today Chemistry, Год журнала: 2024, Номер 36, С. 101957 - 101957

Опубликована: Фев. 6, 2024

Язык: Английский

Процитировано

4

Construction of core-shell NiFe LDH/Co(OH)F amorphous/crystalline heterostructure for synergistically enhanced electrocatalytic water oxidation DOI

Yanhu Jiang,

Kaiwen Cheng, Jiale Xie

и другие.

Journal of Alloys and Compounds, Год журнала: 2024, Номер unknown, С. 177889 - 177889

Опубликована: Дек. 1, 2024

Язык: Английский

Процитировано

4

Design strategy of encapsulated nanoplates and nanorods (ID-CoMo): enhanced catalytic activity and sustainability for overall & solar cell water splitting DOI

Muthukumaran Sangamithirai,

Murugan Vijayarangan,

Arunagiri Gayathri

и другие.

Sustainable Energy & Fuels, Год журнала: 2024, Номер 8(14), С. 3124 - 3135

Опубликована: Янв. 1, 2024

The encapsulated morphology of ID-CoMo/NF is driven by the ID method. It exhibits a higher catalytic activity, conductivity and lower resistance which enhance bifunctional activity (1.55 V) in overall solar cell water splitting.

Язык: Английский

Процитировано

3