UiO-67 MOF-Encapsulated NHC-Based Single-Site Copper Catalyst and Its Application in Regioselective Borylation of Terminal Alkynes DOI
Vijay Mandal,

Kumar Gaurav,

Sandeep H. Kaulage

и другие.

Inorganic Chemistry, Год журнала: 2024, Номер 63(43), С. 20510 - 20520

Опубликована: Окт. 19, 2024

N-Heterocyclic carbenes (NHCs) act as versatile ligand backbones due to their strong σ-donation and π-acceptance properties. However, the encapsulation of NHC-coinage metal complexes in a metal-organic framework (MOF) utilize them organic catalysis is rare. In this work, an NHC-coordinated CuBr (NHC = Bn

Язык: Английский

Biomimetic ZIF-8 Nanoparticles: A Novel Approach for Biomimetic Drug Delivery Systems DOI Creative Commons
Yao Wang,

Mingtang Zeng,

Tianfei Fan

и другие.

International Journal of Nanomedicine, Год журнала: 2024, Номер Volume 19, С. 5523 - 5544

Опубликована: Июнь 1, 2024

Metal-organic frameworks (MOFs) are porous materials resulting from the coordination of metal clusters or ions with organic ligands, merging macromolecular and chemistry features. Among these, zeolitic imidazolate framework-8 (ZIF-8) stands out as a widely utilized MOF known for its robust stability in aqueous environments owing to interaction between constituent zinc (Zn

Язык: Английский

Процитировано

28
Recent advances on biomedical applications of zirconium-based Nanozymes: A review DOI
Mostafa Ghafori-Gorab,

Amir Kashtiaray,

Mahdi Karimi

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 159464 - 159464

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

2
Cutting-edge research on mixed-metal MOFs: fabrication, characterization, properties, and uses DOI
Philips Chidubem Tagbo, Islam Ibrahim, Gehad G. Mohamed

и другие.

Journal of Organometallic Chemistry, Год журнала: 2025, Номер unknown, С. 123531 - 123531

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

2
The performance of MOFs and rich structure types of stable Zr-MOFs in storing clean energy: Hydrogen DOI
Kayhaneh Berijani, G. Reza Vakili-Nezhaad

Journal of Energy Storage, Год журнала: 2025, Номер 116, С. 115928 - 115928

Опубликована: Март 6, 2025

Язык: Английский

Процитировано

2
Advances in metal-organic framework-based drug delivery systems DOI

M T Khulood,

U. S. Jijith,

Punnoth Poonkuzhi Naseef

и другие.

International Journal of Pharmaceutics, Год журнала: 2025, Номер unknown, С. 125380 - 125380

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

1
Synthesis of MOFs and Characterization and Drug Loading Efficiency DOI Creative Commons

Chuang Wu,

Haithm Yahya Mohammed Almuaalemi

ChemEngineering, Год журнала: 2025, Номер 9(2), С. 24 - 24

Опубликована: Фев. 24, 2025

Asthma and allergic rhinitis (AR) stand as prevalent chronic ailments impacting children within the United States. It is approximated that many 40% of American exhibit symptoms indicative AR, a condition which, if inadequately managed, could potentially lead to onset additional illnesses such asthma, rhinosinusitis, conjunctivitis, otitis media. We have devised universal synthetic pathway encapsulate small molecules montelukast sodium Metal–Organic Frameworks (MOFs) for treatment asthma AR. Two distinct Cu-MOFs, namely single linker mixed MOFs, were synthesized through solvothermal method utilizing 1,4-benzenedioic acid (BDC) 4,4′-dipyridile linkers. The Cu-MOFs underwent thorough examination employing various analytical techniques including BET, SEM, FTIR, PXRD. These MOFs hold promise potential vehicles drug delivery applications. Various proportions Cu-MOF-1 Cu-MOF-2 dispersed alongside sodium. Notably, 1:1 ratio both exhibited enhanced absorption compared other ratios. Furthermore, demonstrated superior overall when contrasted with Cu-MOF-1. This investigation also delves into release dynamics from different ratios drug. analysis was conducted in phosphate-buffered saline (PBS) solution pH 7.4, absorbance values measured using UV-visible spectrometer at time intervals. Drug are effectively encapsulated demonstrate controlled establishment hydrogen bonding or π–π interactions between MOFs. Despite notable advancements utilization biomedical purposes, enhancements necessary before they can be considered viable therapeutic modalities.

Язык: Английский

Процитировано

1
Cyborg microbe biohybrids with metal–organic coating layers: strategies, functionalisation and potential applications DOI Creative Commons
Zichen Wu, Ke Xu,

Regina Huang

и другие.

Materials Today Bio, Год журнала: 2025, Номер 31, С. 101642 - 101642

Опубликована: Март 7, 2025

The integration of living microbes, specifically bacteria and fungi, with metal-organic nanocoatings has led to the recent development cyborg microbe biohybrids, which show excellent adaptability functionality for a wide range potential applications in biotechnology medicine. This review discusses strategies, functionalisation, these are categorised into two types coatings: frameworks (MOFs) metal-phenolic networks (MPNs). Key advances their synthetic approaches via in-situ pre-synthesised coatings crucially addressed, yet methodology details specific advantages highlighted. Despite notable advancements, there various limitations challenges, such as determination long-term viability stability insufficient work on theranostic essentially scaling-up difficulties industrial clinical translation. latest advancements biohybrids related technology have established critical foundation enhancing innovative studies through strong interdisciplinary teamwork.

Язык: Английский

Процитировано

1
Synergistic cancer treatment using porphyrin-based metal-organic Frameworks for photodynamic and photothermal therapy DOI
Mahsa Akbari Oryani, Mojtaba Tarin,

Leila Rahnama Araghi

и другие.

Journal of drug targeting, Год журнала: 2024, Номер unknown, С. 1 - 19

Опубликована: Дек. 2, 2024

Recent advancements in multifunctional nanomaterials for cancer therapy have highlighted porphyrin-based metal-organic frameworks (MOFs) as promising candidates due to their unique properties and versatile applications. This overview focuses on the use of MOFs combined photodynamic (PDT) photothermal (PTT) treatment. Porphyrin-based offer high porosity, tuneable structures, excellent stability, making them ideal drug delivery therapeutic The incorporation porphyrin molecules into MOF framework enhances light absorption energy transfer, leading improved effects. Additionally, porosity allows encapsulation agents, further enhancing efficacy. In PDT, generate reactive oxygen species (ROS) upon activation, destroying cells. enable conversion heat, resulting localised hyperthermia tumour ablation. combination PDT PTT a single platform offers synergistic effects, better outcomes, reduced side selectivity. dual-modal treatment strategy provides precise spatiotemporal control over process, paving way next-generation therapeutics with enhanced efficacy Further research optimisation are needed clinical

Язык: Английский

Процитировано

6
Efficient internalization of nano architectured 177Lu-hyaluronic acid@ zirconium-based metal-organic framework for the treatment of neuroblastoma: Unravelling toxicity, stability, radiolabelling and bio-distribution DOI Creative Commons
Sanjay Kulkarni, Abhijeet Pandey, Soji Soman

и другие.

International Journal of Biological Macromolecules, Год журнала: 2024, Номер 278, С. 134381 - 134381

Опубликована: Авг. 8, 2024

Zirconium-based metal-organic frameworks (UiO-66) have gained considerable attention owing to their versatile application. In the present research, UiO-66 was synthesized via a defect engineering approach, and its toxicity profile explored. The nanomaterial extensively characterized spectroscopic methods such as FTIR Raman spectroscopy, which confirmed formation of framework. X-ray diffraction (XRD) transmission electron microscopy (TEM) were used determine crystallinity, shape size nanoformulations. Thermal gravimetric analysis,

Язык: Английский

Процитировано

5
The fabrication of Ce-MOFs with the effective electromagnetic wave absorption performance DOI

Yuce Yang,

Peng Jin, Yujie Li

и другие.

Inorganic Chemistry Communications, Год журнала: 2024, Номер 168, С. 112950 - 112950

Опубликована: Авг. 6, 2024

Язык: Английский

Процитировано

4