A comprehensive review on the application of semiconductor nanometal oxides photocatalyst for the treatment of wastewater

Clean Technologies and Environmental Policy, Год журнала: 2024, Номер unknown

Опубликована: Июль 17, 2024

Язык: Английский

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Integration of CeO2 and Bi2O3 nanoparticles with TiO2-x to fabricate QDs-sized visible-light-triggered materials with efficient performances in the photodegradation of contaminants

Surfaces and Interfaces, Год журнала: 2024, Номер 51, С. 104614 - 104614

Опубликована: Июнь 13, 2024

Язык: Английский

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Synergetic Effect of Heterojunction and Sulfur Vacancy on ZnIn₂S₄/CeO₂ to Enhance the Photocatalytic Performance of 5‐Hydroxymethylfurfural into 2,5‐Diformylfuran

Advanced Functional Materials, Год журнала: 2024, Номер unknown

Опубликована: Окт. 18, 2024

Abstract The efficient separation of photocarriers and facile generation superoxide radicals are crucial for enhancing the performance photocatalysts in selectively photo‐oxidizing 5‐hydroxymethylfurfural (HMF) into 2,5‐diformylfuran (DFF). Herein, a ZnIn 2 S 4 /CeO composite with S‐scheme heterojunction sulfur vacancies (S V ) is successfully developed through one‐step hydrothermal method. optimal catalyst ‐ZnIn exhibits excellent catalytic activity 100% conversion HMF 96.1% selectivity DFF 80 min under ambient conditions, production rate up to 952.6 µmol g −1 h . Intriguingly, remains significant even when concentration increased from 8 100 mм. Experimental theoretical investigations discover that synergistic effect contribute activation oxygen, which facilitate radicals, thus boosting oxidation reactions.

Язык: Английский

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Nanocasting synthesis of mesoporous CeO2 particle abrasives from mesoporous SiO2 hard templates for enhanced chemical mechanical polishing performance

Ceramics International, Год журнала: 2024, Номер unknown

Опубликована: Окт. 1, 2024

Язык: Английский

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Cerium valence state conversion: fabrication and environmental remediation of modified CeO2 materials

Journal of Rare Earths, Год журнала: 2024, Номер unknown

Опубликована: Дек. 1, 2024

Язык: Английский

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Advanced activation of peroxymonosulfate by NiFe-LDH/CeO2 heterostructure photocatalysts toward medical wastewater remediation

Inorganic Chemistry Communications, Год журнала: 2024, Номер 169, С. 113028 - 113028

Опубликована: Авг. 25, 2024

Язык: Английский

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Nano-CeO2 for the Photocatalytic Degradation of the Complexing Agent Citric Acid in Cu Chemical Mechanical Polishing

Applied Sciences, Год журнала: 2024, Номер 14(18), С. 8285 - 8285

Опубликована: Сен. 14, 2024

Cu interconnect chemical mechanical polishing (CMP) technology has been continuously evolving, leading to increasingly stringent post-CMP cleaning requirements. To address the environmental pollution caused by traditional solutions, we have explored use of photocatalytic processes remove citric acid, which is a commonly used complexing agent for CMP. In this study, CeO2 abrasives, characterized hardness 5.5, are extensively employed in Importantly, also exhibits suitable band structure with gap 2.27 eV, enabling it photocatalytically Additionally, integration H2O2, an essential oxidant CMP, enhances degradation efficiency. The research indicates that removal rate single-phase was 1.78 mmol/g/h and efficiency increased 40% addition attributed hydroxyl radicals generated from Fenton-like reaction between H2O2 CeO2. These findings highlight potential improve organic contaminant cleaning, offering more sustainable alternative conventional practices.

Язык: Английский

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Synergetic Effect of Heterojunction and S-Vacancy on Znin2s4/Ceo2 to Enhance the Photocatalytic Performance of 5-Hydroxymethylfurfural into 2,5-Diformylfuran

Опубликована: Янв. 1, 2024

Язык: Английский

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Advanced Activation of Peroxymonosulfate by Nife-Ldh/Ceo2 Heterostructure Photocatalysts Toward Medical Wastewater Remediation

Опубликована: Янв. 1, 2024

Язык: Английский

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Photocatalytic CH₄ Upgrading to Multicarbon Products

ACS Catalysis, Год журнала: 2024, Номер 14(22), С. 16673 - 16686

Опубликована: Окт. 29, 2024

Methane is both a greenhouse gas and an abundant C1 fuel resource that exists in nature. The selective photocatalytic upgrading of methane into multicarbon (C2+) chemicals can mitigate the effect promote utilization value methane, which C–C coupling step key to production products. Achieving this targeted under ambient temperature pressure conditions requires efficient activation C–H bonds as well balancing adsorption desorption various free radicals intermediates facilitate coupling. In Review, we delve recent advances C2+ importance catalyst design, including active site assembly, crystal surface, valence reconstruction, first emphasized. Then, discuss how coreactants such carbon dioxide monoxide be introduced enhance chain growth pathways. Furthermore, also summarize developments looping systems photoelectrocatalysis. Finally, conclude with outlook for future advancement field. This Review aims provide general framework investigating reactions toward products, thereby suggesting research directions environmentally friendly strategies.

Язык: Английский

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