iScience,
Год журнала:
2024,
Номер
27(5), С. 109715 - 109715
Опубликована: Апрель 10, 2024
Hydrogen
generation
from
boron
hydride
is
important
for
the
development
of
hydrogen
economy.
Cobalt
(Co)
element
has
been
widely
used
in
hydrolysis
hydride.
Pyrolysis
a
common
method
materials
synthesis
catalytic
fields.
Herein,
Co-based
nanocomposites
derived
pyrolysis
organic
metal
precursors
and
are
summarized
discussed.
The
different
consisting
MOF,
supported,
metal,
phosphide
summarized.
mechanism
dissociation
based
on
oxidative
addition-reduction
elimination,
pre-activation
mechanism,
SN2
four-membered
ring
acid-base
intensively
Finally,
conclusions
outlooks
conveyed
design
high-efficiency
catalysts,
characterization
catalyst
structure,
enhancement
activities,
investigation
stability
active
structure.
This
review
can
provide
guidance
designing
catalysts
boosting
ACS Catalysis,
Год журнала:
2024,
Номер
14(5), С. 3298 - 3307
Опубликована: Фев. 15, 2024
The
discovery
of
acid-stable
and
highly
active
electrocatalysts
for
the
oxygen
evolution
reaction
(OER)
is
crucial
in
quest
high-performance
water-splitting
technologies.
Herein,
a
heterostructured
RuO2–CeO2
electrocatalyst
was
constructed
by
using
lattice-matching
strategy.
interfacial
Ru–O–Ce
bridge
structure
provided
channel
electron
transfer
between
Ru
Ce,
creating
lattice
stress
that
distorts
local
RuO2.
resulting
catalyst
exhibited
attractive
stability
with
negligible
decay
after
1000
h
OER
0.5
M
H2SO4,
along
high
activity
an
overpotential
only
180
mV
at
10
mA
cm–2.
In
situ
attenuated
total
reflectance
surface-enhanced
infrared
absorption
spectroscopy
(ATR-SEIRAS),
differential
electrochemical
mass
spectrometry
(DEMS),
density
functional
theory
(DFT)
calculations
were
used
to
reveal
interface
noninterface
RuO2
sites
enabled
oxide
path
mechanism
(OPM)
enhanced
adsorbate
(AEM-plus),
respectively,
during
OER.
simultaneous
independent
pathways
accessible
matching
guides
improved
design
acidic
media.
Angewandte Chemie International Edition,
Год журнала:
2023,
Номер
62(52)
Опубликована: Ноя. 9, 2023
The
active-site
density,
intrinsic
activity,
and
durability
of
Pd-based
materials
for
oxygen
reduction
reaction
(ORR)
are
critical
to
their
application
in
industrial
energy
devices.
This
work
constructs
a
series
carbon-based
rare-earth
(RE)
oxides
(Gd2
O3
,
Sm2
Eu2
CeO2
)
by
using
RE
metal-organic
frameworks
tune
the
ORR
performance
Pd
sites
through
Pd-REx
Oy
interface
interaction.
Taking
Pd-Gd2
/C
as
representative,
it
is
identified
that
strong
coupling
between
Gd2
induces
formation
Pd-O-Gd
bridge,
which
triggers
charge
redistribution
.
screened
exhibits
impressive
with
high
onset
potential
(0.986
VRHE
),
half-wave
(0.877
excellent
stability.
Similar
results
also
found
Pd-Sm2
/C,
Pd-Eu2
Pd-CeO2
catalysts.
Theoretical
analyses
reveal
promotes
electron
transfer
antibonding-orbital
occupancy
Pd-*OH
optimization
*OH
adsorption
rate-determining
step
ORR.
pH-dependent
microkinetic
modeling
shows
close
theoretical
optimal
activity
ORR,
outperforming
Pt
under
same
conditions.
By
its
ascendancy
superior
Zn-air
battery
an
air
cathode,
implying
practicability.
Angewandte Chemie International Edition,
Год журнала:
2023,
Номер
63(3)
Опубликована: Дек. 8, 2023
Simultaneous
optimization
of
the
energy
level
water
dissociation,
hydrogen
and
hydroxide
desorption
is
key
to
achieving
fast
kinetics
for
alkaline
evolution
reaction
(HER).
Herein,
well-dispersed
Ru
clusters
on
surface
amorphous/crystalline
CeO
Advanced Materials,
Год журнала:
2024,
Номер
36(16)
Опубликована: Янв. 10, 2024
Abstract
Single‐atom
catalysts
(SACs)
are
demonstrated
to
show
exceptional
reactivity
and
selectivity
in
catalytic
reactions
by
effectively
utilizing
metal
species,
making
them
a
favorable
choice
among
the
different
active
materials
for
energy
conversion.
However,
SACs
still
early
stages
of
conversion,
problems
like
agglomeration
low
conversion
efficiency
hampering
their
practical
applications.
Substantial
research
focus
on
support
modifications,
which
vital
SAC
stability
due
intimate
relationship
between
atoms
support.
In
this
review,
category
supports
variety
surface
engineering
strategies
employed
SA
systems
summarized,
including
site
(heteroatom
doping,
vacancy
introducing,
groups
grafting,
coordination
tunning)
structure
(size/morphology
control,
cocatalyst
deposition,
facet
engineering,
crystallinity
control).
Also,
merits
single‐atom
systematically
introduced.
Highlights
comprehensive
summary
discussions
utilization
surface‐engineered
diversified
applications
photocatalysis,
electrocatalysis,
thermocatalysis,
devices.
At
end
potential
obstacles
using
field
discussed.
This
review
aims
guide
rational
design
manipulation
target‐specific
capitalizing
characteristic
benefits
engineering.
Science,
Год журнала:
2024,
Номер
386(6724), С. 915 - 920
Опубликована: Ноя. 21, 2024
The
metal-support
interaction
is
one
of
the
most
important
pillars
in
heterogeneous
catalysis,
but
developing
a
fundamental
theory
has
been
challenging
because
intricate
interfaces.
Based
on
experimental
data,
interpretable
machine
learning,
theoretical
derivation,
and
first-principles
simulations,
we
established
general
metal-oxide
interactions
grounded
metal-metal
metal-oxygen
interactions.
applies
to
metal
nanoparticles
atoms
oxide
supports
films
supports.
We
found
that
for
late-transition
catalysts,
metal-metal
dominated
support
effects
suboxide
encapsulation
over
nanoparticles.
A
principle
strong
occurrence
formulated
substantiated
by
extensive
experiments
including
10
metals
16
oxides.
valuable
insights
revealed
(strong)
advance
interfacial
design
supported
catalysts.
Angewandte Chemie International Edition,
Год журнала:
2024,
Номер
63(10)
Опубликована: Янв. 10, 2024
The
size
of
support
in
heterogeneous
catalysts
can
strongly
affect
the
catalytic
property
but
is
rarely
explored
light-driven
catalysis.
Herein,
we
demonstrate
TiO
Catalysts,
Год журнала:
2024,
Номер
14(3), С. 176 - 176
Опубликована: Март 1, 2024
The
dry
reforming
of
methane
(DRM)
is
a
promising
method
for
controlling
greenhouse
gas
emissions
by
converting
CO2
and
CH4
into
syngas,
mixture
CO
H2.
Ni-based
catalysts
have
been
intensively
investigated
their
use
in
the
DRM.
However,
they
are
limited
formation
carbonaceous
materials
on
surfaces.
In
this
review,
we
explore
carbon-induced
catalyst
deactivation
mechanisms
summarize
recent
research
progress
mitigating
carbon
deposition
developing
coke-resistant
catalysts.
This
review
emphasizes
significance
support,
alloy,
structural
strategies,
importance
comprehending
interactions
between
components
to
achieve
improved
catalytic
performance
stability.
